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Development of photo-switching transistors using functional organic molecules

Research Project

Project/Area Number 20860090
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Electronic materials/Electric materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

HAYAKAWA Ryoma  National Institute for Materials Science, 半導体材料センター, NIMSポスドク研究員 (90469768)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,211,000 (Direct Cost: ¥2,470,000、Indirect Cost: ¥741,000)
Fiscal Year 2009: ¥1,495,000 (Direct Cost: ¥1,150,000、Indirect Cost: ¥345,000)
Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
Keywords有機トランジスタ / 有機ヘテロ界面 / 光 / ヘテロ構造 / 光スイッチング
Research Abstract

The objective of our study is to control the charge-transfer at organic hetero-interface by photo-irradiation, leading to development of photo-switching organic transistor. Firstly, we successfully improved electrical properties of quaterrylene (QT) thin film transistors by interface-engineering. As a result, even 2ML-thick QT thin films worked as p-typed transistors. Then, we formed organic hetero-layer transistors, where charge-transfer complex molecules with high electron acceptability were deposited on the top of QT transistors. Threshold voltage in the hetero-layer transistors was drastically changed by charge-transfer complex molecules, demonstrating that transistor properties can be controlled through organic hetero-interface.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (18 results)

All 2010 2009 2008 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (11 results)

  • [Journal Article] Impact of Surface Modification by Self-assembled Monolayer for Carrier Transport of Quaterrylene Thin Films2009

    • Author(s)
      R. Hayakawa, N. Hiroshiba, T. Chikyow, Y. Wakayama
    • Journal Title

      Thin Solid Films vol.518

      Pages: 437-440

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stress Release Drives Growth Transition of Quaterrylene Thin Films on SiO2 surfaces2009

    • Author(s)
      R. Hayakawa, Z.N. Zhang, M. Petit, H. Dosch, T. Chikyow, Y. Wakayama
    • Journal Title

      J. Phys. Chem. C vol.113

      Pages: 2197-2199

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impact of Surface Modification by Self-assembled Monolayer for Carrier Transport of Quaterrylene Thin Films2009

    • Author(s)
      Ryoma Hayakawa
    • Journal Title

      Thin Solid Films 518

      Pages: 437-440

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stress Release Drives Growth Transition of Quaterrylene Thin Films on SiO_2 surfaces2009

    • Author(s)
      Ryoma Hayakawa
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 2197-2199

    • Related Report
      2009 Annual Research Report 2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface Engineering for Molecular Alignment and Device Performance of Quaterrylene Thin Films2009

    • Author(s)
      Ryoma Hayakawa
    • Journal Title

      Applied Physics Letters 93

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface Engineering for Molecular Alignment and Device Performance of Quaterrylene Thin Films2008

    • Author(s)
      R. Hayakawa, M. Petit, T. Chikyow, Y. Wakayama
    • Journal Title

      Appl. Phys. Lett. vol.93

      Pages: 153301-153301

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impact of Surface Modification by Self-assembled Monolayer for Carrier Transport of Quaterrylene Thin Films

    • Author(s)
      Ryoma Hayakawa
    • Journal Title

      Thin Solid Films

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Quaterrylene有機薄膜における格子歪みの制御と成長過程に及ぼす影響2010

    • Author(s)
      早川竜馬, Ayse Turak, XueNa Zhang, Helmut Dosch, 廣芝伸哉, 知京豊裕, 若山裕
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-20
    • Related Report
      2009 Final Research Report
  • [Presentation] Quaterrylene有機薄膜における格子歪みの制御と成長過程に及ぼす影響2010

    • Author(s)
      早川竜馬
    • Organizer
      日本物理学会 第65回年次大会
    • Place of Presentation
      岡山大学 津島キャンパス(岡山市)
    • Year and Date
      2010-03-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] Strain-engineering for controlled growth mode of quaterrylene Thin Films2009

    • Author(s)
      R. Hayakawa, A. Turak, X.N. Zhang, H. Dosch, N. Hiroshiba, T. Chikyow, Y. Wakayama
    • Organizer
      ACSIN-10
    • Place of Presentation
      Granada conference center, Granada, Spain
    • Year and Date
      2009-09-21
    • Related Report
      2009 Final Research Report
  • [Presentation] Strain-engineering for Controlled Growth Process of Quaterrylene Thin Films2009

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      ACSIN-10
    • Place of Presentation
      Granada conference centre, Granada, Spain
    • Year and Date
      2009-09-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Quaterrylene有機薄膜における格子歪みの評価と成長過程に及ぼす影響2009

    • Author(s)
      早川竜馬, Ayse Turak, XueNa Zhang, Helmut Dosch, 廣芝伸哉, 知京豊裕, 若山裕
    • Organizer
      2009年春季第56回応用物理学関係連合講演会
    • Place of Presentation
      筑波大学
    • Year and Date
      2009-03-31
    • Related Report
      2009 Final Research Report
  • [Presentation] Quaterrylene 有機薄膜における格子歪みの評価と成長過程に及ぼす影響2009

    • Author(s)
      早川竜馬
    • Organizer
      2009年春季 第56回応用物理学関係連合講演会
    • Place of Presentation
      筑波大学,茨城,日本
    • Year and Date
      2009-03-31
    • Related Report
      2008 Annual Research Report
  • [Presentation] Impact of interface modification by self-assembled monolayer on growth and electrical property of quaterrylene thin films2008

    • Author(s)
      R. Hayakawa, N. Hiroshiba, T. Chikyow, Y. Wakayama
    • Organizer
      ICNME2008
    • Place of Presentation
      神戸ポートピアホテル, 神戸市
    • Year and Date
      2008-12-16
    • Related Report
      2009 Final Research Report
  • [Presentation] Impact of Interface Modification by Self-assembled Monolayer on Growth electrical Property of Quaterrylene Thin Films2008

    • Author(s)
      Ryoma Hayakawa
    • Organizer
      ICNME2008
    • Place of Presentation
      神戸ポートピアホテル,神戸,日本
    • Year and Date
      2008-12-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Quaterrylene有機薄膜の成長とトランジスタ特性-自己組織化膜によるシリコン酸化膜表面修飾効果-2008

    • Author(s)
      早川竜馬、XueNa Zang, Ayse Turak, Helmut Dosch, 廣芝伸哉, 知京豊裕, 若山裕
    • Organizer
      2008年秋季第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学、愛知県
    • Year and Date
      2008-09-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Quaterrylene 有機薄膜の成長とトランジスタ特性-自己組織化膜によるシリコン酸化膜表面修飾効果-2008

    • Author(s)
      早川竜馬
    • Organizer
      2008年秋季 第69回応用物理学会学術講演会
    • Place of Presentation
      中部大学,愛知県,日本
    • Year and Date
      2008-09-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] Quaterrylene Single Monolayer Transistors Formed Using Ultra-slow Vacuum Deposition Technique2008

    • Author(s)
      R. Hayakawa, M. Petit, Y. Wakayama, T. Chikyow
    • Organizer
      E-MRS 2008 Spring meeting
    • Place of Presentation
      Congress Center, Strasbourg, France
    • Year and Date
      2008-05-26
    • Related Report
      2009 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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