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Allotropic phase transformation by point-defect clustering

Research Project

Project/Area Number 20H00309
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionShimane University

Principal Investigator

Arakawa Kazuto  島根大学, 学術研究院理工学系, 教授 (30294367)

Co-Investigator(Kenkyū-buntansha) 武藤 哲也  島根大学, 学術研究院理工学系, 准教授 (50312244)
大島 義文  北陸先端科学技術大学院大学, 先端科学技術研究科, 教授 (80272699)
Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥44,980,000 (Direct Cost: ¥34,600,000、Indirect Cost: ¥10,380,000)
Fiscal Year 2023: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2022: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2021: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Fiscal Year 2020: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Keywords点欠陥 / 転位 / 鉄 / 透過電子顕微鏡 / 欠陥 / 透過電子顕微鏡法 / 相転移
Outline of Research at the Start

本申請者らは最近、アルファ鉄中において、点欠陥によって、第四の同素体の安定なナノ・クラスター(欠陥同素体)を創り得ることを、透過電子顕微鏡法を駆使して、世界に先駆けて明らかにした。本研究では、透過電子顕微鏡法を駆使して、鉄における欠陥同素体の形成機構および材料の機械的性質へもたらす効果を明らかにする。これらの知見は、点欠陥が導入される幅広い過程における微細組織発達を理解する上での新たな基盤となる。

Outline of Final Research Achievements

The purpose of this study was to clarify fundamental issues regarding small point defect clusters, particularly "defect allotropes," using in-situ transmission electron microscopy. The main achievements are as follows: (1) We succeeded in directly observing the formation process of defect allotropes in high-purity iron and a few iron alloys. It was made clear that the formation of defect allotropes is not due to solute or impurity atoms, but is an intrinsic property of iron. (2) We succeeded in directly observing the interactions between dislocation loops and gliding dislocations in iron at room temperature and at high temperatures.

Academic Significance and Societal Importance of the Research Achievements

本研究成果は、点欠陥が導入される多くの過程(原子炉・核融合炉材料における高エネルギー粒子照射、幅広い種類の構造材料における塑性変形 等)における鉄および鉄鋼材料の微細組織変化を理解する上で極めて重要である。「欠陥同素体」を新たな強化因子として生かした新たな鉄鋼材料設計に繋がり得るものと期待される。

Report

(6 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Comments on the Screening Results   Annual Research Report
  • Research Products

    (35 results)

All 2024 2023 2022 2021 2020 Other

All Int'l Joint Research (5 results) Journal Article (8 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 8 results,  Open Access: 6 results) Presentation (21 results) (of which Int'l Joint Research: 4 results,  Invited: 17 results) Remarks (1 results)

  • [Int'l Joint Research] UKAEA(英国)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] CEA-Saclay(フランス)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] CEA-Saclay(フランス)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] UKAEA(英国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] CEA-Saclay(フランス)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] X-ray free electron laser observation of ultrafast lattice behaviour under femtosecond laser-driven shock compression in iron2023

    • Author(s)
      T.Sano, T. Matsuda, T. Sato, K.Miyanishi, M. Yabashi, T. Togashi, K. Tono, O. Sakata, Y.Tange, K. Arakawa, Y.Ito, T.Okuchi, T. Sato, T.Sekine, T.Mashimo, N. Nakanii, Y. Seto, M.Shigeta, T.Shobu, Y.Sano, T. Hosokai, T.Matsuoka, T.Yabuuchi, K. A. Tanaka, N.Ozaki , R,Kodama
    • Journal Title

      Scientific Reports

      Volume: 13 Issue: 1 Pages: 13789-13796

    • DOI

      10.1038/s41598-023-40283-6

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 水素脆化における潜伏期から破壊までの実態解明における新展開2023

    • Author(s)
      高井健一, 松本龍介, 松永久生, 小山元道, 小川祐平, 柴田暁伸, 荒河一渡, 武富紳也, 藤浪眞紀
    • Journal Title

      ふぇらむ

      Volume: 28 Pages: 28-36

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Influence of pulse duration on mechanical properties and dislocation density of dry laser peened aluminum alloy using ultrashort pulsed laser-driven shock wave2022

    • Author(s)
      M. Yoshida, I. Nishibata, T. Matsuda, Y. Ito, N. Sugita, A. Shiro, T. Shobu, K. Arakawa, A. Hirose, T. Sano
    • Journal Title

      Journal of Applied Physics

      Volume: 132 Issue: 7 Pages: 075101-075101

    • DOI

      10.1063/5.0083511

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ TEM Observation of Quantum Diffusion of Defects in Metal2021

    • Author(s)
      荒河一渡
    • Journal Title

      KENBIKYO

      Volume: 56 Issue: 3 Pages: 143-146

    • DOI

      10.11410/kenbikyo.56.3_143

    • NAID

      130008137909

    • ISSN
      1349-0958, 2434-2386
    • Year and Date
      2021-12-30
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hydrogen Effects on the Migration of Nanoscale Cavities in Iron2021

    • Author(s)
      K. Arakawa, A. Kageyama, H. Hiroshima, H. Yasuda, S. Ogata
    • Journal Title

      ISIJ International

      Volume: 61 Issue: 8 Pages: 2305-2307

    • DOI

      10.2355/isijinternational.ISIJINT-2021-140

    • NAID

      130008075168

    • ISSN
      0915-1559, 1347-5460
    • Year and Date
      2021-08-15
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Perspectives on multiscale modelling and experiments to accelerate materials development for fusion2021

    • Author(s)
      Gilbert M.R.、Arakawa K.、Suzudo T.、Trelewicz J.R.、Tsuru T.、et al.
    • Journal Title

      Journal of Nuclear Materials

      Volume: 554 Pages: 153113-153113

    • DOI

      10.1016/j.jnucmat.2021.153113

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrogen-Enhanced Vacancy Diffusion in Metals2020

    • Author(s)
      Du Jun-Ping、Geng W. T.、Arakawa Kazuto、Li Ju、Ogata Shigenobu
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 11 Issue: 17 Pages: 7015-7020

    • DOI

      10.1021/acs.jpclett.0c01798

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] In-situ WB-STEM observation of dislocation loop behavior in reactor pressure vessel steel during post-irradiation annealing2020

    • Author(s)
      Du Yufeng、Yoshida Kenta、Shimada Yusuke、Toyama Takeshi、Inoue Koji、Arakawa Kazuto、Suzudo Tomoaki、Milan Konstantinovic J.、Gerard Robert、Ohnuki Somei、Nagai Yasuyoshi
    • Journal Title

      Materialia

      Volume: 12 Pages: 100778-100778

    • DOI

      10.1016/j.mtla.2020.100778

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 鉄におけるらせん転位とプリズマティック転位ループ間相互作用のTEMその場観察2024

    • Author(s)
      井上喬仁, 杉本有隆, 荒河一渡
    • Organizer
      日本鉄鋼協会第187回春季講演大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 鉄の引張変形下でのキャビティ形成に対する水素効果のTEM観察2024

    • Author(s)
      水谷琢朗, 井上喬仁, 西村飛翔, 福田英, 植田靖子, 荒河一渡
    • Organizer
      日本鉄鋼協会第187回春季講演大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] In-situ TEM of Dynamics of Lattice Defects in Metals2023

    • Author(s)
      Kazuto Arakawa
    • Organizer
      The 11th Pacific Rim International Conference on Advanced Materials and Processing (PRICM11)
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-situ TEM of Dynamics of Lattice Defects in Metals2023

    • Author(s)
      Kazuto Arakawa
    • Organizer
      International Workshop on Advanced and In-situ Microscopies of Functional Nanomaterials and Devices (IAMNano) 2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 材料の先端電子顕微鏡による原子~ナノ分析技術2023

    • Author(s)
      荒河一渡
    • Organizer
      プラズマ材料工学研究会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 金属の変形をナノレベルで観る2023

    • Author(s)
      荒河一渡
    • Organizer
      応用物理・物理系学会 中国四国支部 学術合同講演会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 鉄におけるらせん転位の高温挙動の透過電子顕微鏡その場観察2023

    • Author(s)
      井上喬仁, 植田大地, 木村崇, 小宅雄真, 荒河一渡
    • Organizer
      日本顕微鏡学会第79回学術講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 原子分解能磁場フリー電子顕微鏡のTEM光学系の開発2023

    • Author(s)
      前川達洋, 河野祐二, 森下茂幸, 荒河一渡
    • Organizer
      日本顕微鏡学会第79回学術講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 金属における格子欠陥の動的挙動のその場観察2023

    • Author(s)
      荒河一渡
    • Organizer
      日本顕微鏡学会 超高分解能顕微鏡法分科会 研究討論会 「様々な環境下での超高分解能」
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 金属における欠陥挙動のTEMその場観察2023

    • Author(s)
      荒河一渡
    • Organizer
      日本電子第15回TEMユーザーズミーティング
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] タングステンにおける照射欠陥挙動のTEMその場観測2022

    • Author(s)
      荒河一渡
    • Organizer
      日本金属学会シンポジウム「タングステン材料科学」
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 原子分解能磁場フリー電子顕微鏡 MARS の汎用化へ向けた展開2022

    • Author(s)
      荒河一渡
    • Organizer
      日本表面真空学会 関東支部 実用顕微鏡評価技術セミナー 2022
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 金属における格子欠陥挙動の透過電子顕微鏡その場観察法による研究2022

    • Author(s)
      荒河一渡
    • Organizer
      2022 年度 日本顕微鏡学会 学術講演会 瀬藤賞授賞講演
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] In-situ TEM of Quantum De-trapping and Transport of Heavy Defects in Tungsten2022

    • Author(s)
      Kazuto Arakawa, Mihai-Cosmin Marinica, Steven Fitzgerald, Laurent Proville, Duc Nguyen-Manh, Sergei L. Dudarev, Pui-Wai Ma, Thomas D. Swinburne, Alexandra M. Goryaeva, Tetsuya Yamada, Shigeo Arai, Tetsuya Yasuda, Hirotaro Mori
    • Organizer
      TMS 2022 Annual Meeting
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-situ TEM of the Interaction between Screw Dislocations and Dislocation Loops in Iron2021

    • Author(s)
      Kazuto Arakawa, Takahito Inoue, Yutaka Sugimoto
    • Organizer
      International Conference on Fusion Reactor Materials (ICFRM-20)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属の変形素過程の透過電子顕微鏡その場観察2021

    • Author(s)
      荒河一渡
    • Organizer
      日本熱処理技術協会第 92 回 (2021 年秋季) 講演大会 田村・川嵜記念講演
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] TEMその場観察による金属における格子欠陥挙動の研究2021

    • Author(s)
      荒河一渡
    • Organizer
      日本セラミックス協会 第34回秋季シンポジウム 先進的な構造科学と分析技術
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 透過電子顕微鏡による金属における格子欠陥のダイナミクスの研究2021

    • Author(s)
      荒河一渡
    • Organizer
      日本セラミックス協会 第3回資源・環境関連材料部会討論会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] TEM その場観察による金属における格子欠陥挙動の研究2021

    • Author(s)
      荒河一渡
    • Organizer
      日本材料学会 マルチスケール材料力学部門 第69期第 5 回部門委員会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 金属における格子欠陥の動的挙動のTEMその場観察2020

    • Author(s)
      1.荒河一渡
    • Organizer
      東京大学 次世代電子顕微鏡法 社会連携講座 第1回「次世代電子顕微鏡法」講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 超高圧電子顕微鏡による金属における重い欠陥の量子移動の観測2020

    • Author(s)
      2.荒河一渡, M. C. Marinica, S. Fitzgerald, L. Proville, D. Nguyen-Manh, S.L. Dudarev, P.W. Ma, T.D. Swinburne, A.M. Goryaeva, 山田哲也, 網野岳文, 荒井重勇, 山本悠太, 樋口公孝, 田中信夫, 保田英洋, 安田哲也, 森博太郎
    • Organizer
      日本顕微鏡学会 第63回シンポジウム 顕微鏡オンラインフォーラム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Remarks] 透過型電子顕微鏡法による固体内局所構造の研究

    • URL

      http://tem-defect.jp/index.html

    • Related Report
      2021 Annual Research Report

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Published: 2020-04-28   Modified: 2025-01-30  

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