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Creation of Novel N-Confused Metallo-porphyrinoid System

Research Project

Project/Area Number 20H00406
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 37:Biomolecular chemistry and related fields
Research InstitutionRitsumeikan University (2022-2023)
Kyushu University (2020-2021)

Principal Investigator

FURUTA HIROYUKI  立命館大学, 総合科学技術研究機構, 教授 (40244157)

Co-Investigator(Kenkyū-buntansha) 石田 真敏  東京都立大学, 理学研究科, 准教授 (60706951)
井川 善也  富山大学, 学術研究部理学系, 教授 (70281087)
清水 宗治  九州大学, 工学研究院, 准教授 (70431492)
Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥45,240,000 (Direct Cost: ¥34,800,000、Indirect Cost: ¥10,440,000)
Fiscal Year 2023: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2022: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2021: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2020: ¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Keywordsポルフィリン異性体 / Nー混乱ポルフィリン / 金属錯体 / 近赤外色素 / ポルフィリン / 光触媒 / 近赤外光 / π共役 / 触媒 / 磁性
Outline of Research at the Start

本研究課題に対して、金属d電子と配位子のπ電子の共同的な相互作用を利用した分子軌道の精密制御に基づく新規N-混乱ポルフィリノイド金属錯体の設計・合成を行う。特異な光・電子物性、触媒反応性の検討を通じて、新たなポルフィリノイド化学の礎を築くと共に、次世代分子触媒・バイオイメージング・磁気材料に資する材料化学へ展開する。

Outline of Final Research Achievements

Based on the N-confused porphyrinoid chemistry containing a confused(inverted) pyrrole ring, developed independently by us, we have synthesized various molecules capable of metal coordination and investigated their optical, electronic, and magnetic properties, aiming to create molecular materials that can exhibit a variety of functionalities (multi-electron transfer ability, catalytic ability, photothermal conversion ability, etc.). Among N-confused ring-contracted and ring-expanded porphyrinoids, we discovered many molecules that function in the low-energy optical window called the second near-infrared (NIR-II).

Academic Significance and Societal Importance of the Research Achievements

異種ポルフィリノイドとして新たなクラスを形成するN―混乱ポルフィリノイドの未知なる基本物性や反応性等を発見すると共に、深部固形がんの治療において注目されている「近赤外光免疫治療法」には欠かす事のできない近赤外光感受性薬剤分子への応用展開可能な、第二近赤外(NIR-II)低エネルギー光学窓で機能する化合物を多数見出すことに成功した。

Report

(5 results)
  • 2023 Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Comments on the Screening Results   Annual Research Report
  • Research Products

    (79 results)

All 2023 2022 2021 2020 Other

All Int'l Joint Research (11 results) Journal Article (30 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 30 results,  Open Access: 5 results) Presentation (38 results) (of which Int'l Joint Research: 6 results,  Invited: 4 results)

  • [Int'l Joint Research] University of Wroclaw(ポーランド)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] ECUST(中国)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] Uppsala University(スウェーデン)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] National Taiwan University(その他の国・地域)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] Yonsei University(韓国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] ECUST(中国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] GITAM(インド)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] University of Southern Denmark(デンマーク)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] ECUST(中国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] Yonsei University(韓国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] IIT Gandhinagar(インド)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Conformation-dependent photophysical properties of butadiyne-linked π-extended BODIPY dimers2023

    • Author(s)
      Sato Yuma、Shimada Takahide、Mori Shigeki、Yasutake Yuhsuke、Fukatsu Susumu、Furuta Hiroyuki、Ishida Masatoshi
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 27 Issue: 01n04 Pages: 486-492

    • DOI

      10.1142/s1088424623500232

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ring-opening of 5,15-dioxaporphyrin into 1,9-diaryldipyrrin by a reaction with Grignard reagents2023

    • Author(s)
      Hao Jiping、Nishiyama Akihide、Mori Shigeki、Furuta Hiroyuki、Shimizu Soji
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 27 Issue: 07n10 Pages: 1083-1088

    • DOI

      10.1142/s1088424623500293

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Redox properties of bis-cobalt(III) complex of 3,3′-linked N-confused porphyrin dimer with axial pyridine ligands2023

    • Author(s)
      Iwanaga Osamu、Yoshida Naoya、Miyazaki Takaaki、Tani Fumito、Mori Shigeki、Shimizu Soji、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 27 Issue: 07n10 Pages: 1074-1082

    • DOI

      10.1142/s1088424623500281

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Panchromatic small-molecule organic solar cells based on a pyrrolopyrrole aza-BODIPY with a small energy loss2023

    • Author(s)
      Feng Ru、Mori Tatsuya、Yasuda Takuma、Furuta Hiroyuki、Shimizu Soji
    • Journal Title

      Dyes and Pigments

      Volume: 210 Pages: 111020-111020

    • DOI

      10.1016/j.dyepig.2022.111020

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Organometallic chemistry confined within a porphyrin-like framework2023

    • Author(s)
      Bialek Michal J.、Hurej Karolina、Furuta Hiroyuki、Latos-Grazynski Lechoslaw
    • Journal Title

      Chemical Society Reviews

      Volume: 52 Issue: 6 Pages: 2082-2144

    • DOI

      10.1039/d2cs00784c

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Conformation Governed Reactivity of Fused Thia-Sapphyrin Dimers Bearing Multiply Fused Heteroaromatic Rings2023

    • Author(s)
      Li Qizhao、Ishida Masatoshi、Li Chengjie、Baryshnikov Glib、Sha Feng、Zhu Bin、Wu Xinyan、Agren Hans、Furuta Hiroyuki、Xie Yongshu
    • Journal Title

      CCS Chemistry

      Volume: 5 Issue: 6 Pages: 1-11

    • DOI

      10.31635/ccschem.023.202202690

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Creation from Confusion and Fusion in the Porphyrin World─The Last Three Decades of N-Confused Porphyrinoid Chemistry2022

    • Author(s)
      Toganoh Motoki、Furuta Hiroyuki
    • Journal Title

      Chemical Reviews

      Volume: 122 Issue: 9 Pages: 8313-8437

    • DOI

      10.1021/acs.chemrev.1c00065

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spontaneous Assembly and Three‐Dimensional Stacking of Antiaromatic 5,15‐Dioxaporphyrin on HOPG2022

    • Author(s)
      Chen Tsang‐Wei Matt、Tanaka Yuki、Kametani Yohei、Cheng Kum‐Yi、Lin Chih‐Hsun、Lin Yi Rick、Hsu Ting‐Rong、Chen Zuqian、Hao Jiping、Mori Shigeki、Shiota Yoshihito、Yoshizawa Kazunari、Furuta Hiroyuki、Shimizu Soji、Chen Chun‐hsien
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 61 Issue: 48

    • DOI

      10.1002/anie.202212726

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Selective hetero-bis-metalation of a cisoid isomer of doubly N-confused dioxohexaphyrin2022

    • Author(s)
      Shimomura Keito、Nakamura Yuma、Kai Hiroto、Saito Kyosuke、Furukawa Ko、Mori Shigeki、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 26 Issue: 12 Pages: 807-814

    • DOI

      10.1142/s1088424622500456

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Computational Study on the Mechanism of Catalytic Cyclopropanation Reaction with Cobalt N-Confused Porphyrin: The Effects of Inner Carbon and Intramolecular Axial Ligand2022

    • Author(s)
      Iwanaga Osamu、Miyanishi Mayuko、Tachibana Toshihiro、Miyazaki Takaaki、Shiota Yoshihito、Yoshizawa Kazunari、Furuta Hiroyuki
    • Journal Title

      Molecules

      Volume: 27 Issue: 21 Pages: 7266-7266

    • DOI

      10.3390/molecules27217266

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Antiaromatic Sapphyrin Isomer: Transformation into Contracted Porphyrinoids with Variable Aromaticity2022

    • Author(s)
      Li Qizhao、Ishida Masatoshi、Wang Yunyun、Li Chengjie、Baryshnikov Glib、Zhu Bin、Sha Feng、Wu Xinyan、Agren Hans、Furuta Hiroyuki、Xie Yongshu
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 62 Issue: 1

    • DOI

      10.1002/anie.202212174

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Metal complexes of 5,10,15-tris(pentafluorophenyl)-20-pyrrolyl N-confused porphyrin and its meso-pyrrolyl-bridged dimers: Synthesis and optical properties2021

    • Author(s)
      Yamasumi Kazuhisa、Mori Shigeki、Tanaka Takayuki、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 25 Issue: 05n06 Pages: 447-455

    • DOI

      10.1142/s1088424621500255

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvent-Controlled Self-Assembled Oligopyrrolic Receptor2021

    • Author(s)
      Wang Fei、Liang Kejiang、Larsen Mads Christian、Bahring Steffen、Ishida Masatoshi、Furuta Hiroyuki、Jana Atanu
    • Journal Title

      Molecules

      Volume: 26 Issue: 6 Pages: 1771-1771

    • DOI

      10.3390/molecules26061771

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Iridium Complex of N‐Fused Bilatrienone: Oxidative Cleavage of N‐Fused Porphyrin Induced by Iridium‐Cyclooctadiene Complexation2021

    • Author(s)
      Abraham Jibin Alex、Mori Shigeki、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Chemistry A European Journal

      Volume: 27 Issue: 32 Pages: 8268-8272

    • DOI

      10.1002/chem.202100789

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Heptacene and Its Hole‐Transfer Property of Stable Thin Films2021

    • Author(s)
      Miyazaki Takaaki、Watanabe Motonori、Matsushima Toshinori、Chien Ching-Ting、Adachi Chihaya、Sun Shih-Sheng、Furuta Hiroyuki、Chow Tahsin J.
    • Journal Title

      Chemistry - A European Journal

      Volume: - Issue: 41 Pages: 10677-10684

    • DOI

      10.1002/chem.202100936

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Janus Pyrrolopyrrole Aza‐dipyrrin: Hydrogen‐Bonded Assemblies and Slow Magnetic Relaxation of the Cobalt(II) Complex in the Solid State2021

    • Author(s)
      Ishizaki Toshiharu、Karasaki Hideaki、Kage Yuto、Kamioka Misaki、Wang Yitong、Mori Shigeki、Ishikawa Naoto、Fukuda Takamitsu、Furuta Hiroyuki、Shimizu Soji
    • Journal Title

      Chemistry - A European Journal

      Volume: 27 Issue: 49 Pages: 12686-12692

    • DOI

      10.1002/chem.202101755

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of N-Fused Porphyrin Rhodium Complex with an Isomerized Cyclooctadiene Ligand2021

    • Author(s)
      Abraham Jibin Alex、Mori Shigeki、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Chemistry Letters

      Volume: 50 Issue: 9 Pages: 1707-1709

    • DOI

      10.1246/cl.210381

    • NAID

      130008088227

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruthenium(IV) N-confused porphyrin μ-oxo-bridged dimers: acid-responsive molecular rotors2021

    • Author(s)
      Iwanaga Osamu、Fukuyama Kazuki、Mori Shigeki、Song Jun Tae、Ishihara Tatsumi、Miyazaki Takaaki、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      RSC Advances

      Volume: 11 Issue: 40 Pages: 24575-24579

    • DOI

      10.1039/d1ra05063j

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Benzo‐Tetrathiafulvalene‐ (BTTF‐) Annulated Expanded Porphyrins: Potential Next‐Generation Multielectron Reservoirs2021

    • Author(s)
      Jana Atanu、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Chemistry A European Journal

      Volume: 27 Issue: 13 Pages: 4466-4472

    • DOI

      10.1002/chem.202005021

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An Electron‐Accepting aza‐BODIPY‐Based Donor?Acceptor?Donor Architecture for Bright NIR Emission2021

    • Author(s)
      Kage Yuto、Kang Seongsoo、Mori Shigeki、Mamada Masashi、Adachi Chihaya、Kim Dongho、Furuta Hiroyuki、Shimizu Soji
    • Journal Title

      Chemistry - A European Journal

      Volume: 27 Issue: 16 Pages: 5259-5267

    • DOI

      10.1002/chem.202005360

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chiral Interlocked Corrole Dimers Directly Linked at Inner Carbon Atoms of Confused Pyrrole Rings2021

    • Author(s)
      Kumar Maurya Yogesh、Wei Pingchun、Shimada Takahide、Yamasumi Kazuhisa、Mori Shigeki、Furukawa Ko、Kusaba Hajime、Ishihara Tatsumi、Xie Yongshu、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Chemistry An Asian Journal

      Volume: 16 Issue: 7 Pages: 743-747

    • DOI

      10.1002/asia.202100083

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis, Photophysical Properties and Computational Studies of beta‐Substituted Porphyrin Dyads2020

    • Author(s)
      Kesavan Praseetha E.、Pandey Vijayalakshmi、Ishida Masatoshi、Furuta Hiroyuki、Mori Shigeki、Gupta Iti
    • Journal Title

      Chemistry An Asian Journal

      Volume: 15 Issue: 13 Pages: 2015-2028

    • DOI

      10.1002/asia.202000463

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Copper 1,19‐Diaza‐21,24‐dicarbacorrole: A Corrole Analogue with an N-N Linkage Stabilizes a Ground‐State Singlet Organocopper Species2020

    • Author(s)
      Basumatary Biju、Hashiguchi Ikuho、Mori Shigeki、Shimizu Soji、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 37 Pages: 15897-15901

    • DOI

      10.1002/anie.202005167

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near‐Infrared‐III‐Absorbing and ‐Emitting Dyes: Energy‐Gap Engineering of Expanded Porphyrinoids via Metallation2020

    • Author(s)
      Wang Yue、Ogasahara Koki、Tomihama Daisuke、Mysliborski Radomir、Ishida Masatoshi、Hong Yongseok、Notsuka Yusuke、Yamaoka Yoshihisa、Murayama Tomotaka、Muranaka Atsuya、Uchiyama Masanobu、Mori Shigeki、Yasutake Yuhsuke、Fukatsu Susumu、Kim Dongho、Furuta Hiroyuki
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 37 Pages: 16161-16166

    • DOI

      10.1002/anie.202006026

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fundamental Study on Arsenic(III) Halides (AsX3; X = Br, I) toward the Construction of C3-Symmetrical Monodentate Arsenic Ligands2020

    • Author(s)
      Tanaka Susumu、Konishi Masafumi、Imoto Hiroaki、Nakamura Yuma、Ishida Masatoshi、Furuta Hiroyuki、Naka Kensuke
    • Journal Title

      Inorganic Chemistry

      Volume: 59 Issue: 14 Pages: 9587-9593

    • DOI

      10.1021/acs.inorgchem.0c00598

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near-infrared absorbing pyrrolopyrrole aza-BODIPY-based donor-acceptor polymers with reasonable photoresponse2020

    • Author(s)
      Feng Ru、Sato Narumi、Nomura Mayuka、Saeki Akinori、Nakanotani Hajime、Adachi Chihaya、Yasuda Takuma、Furuta Hiroyuki、Shimizu Soji
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 8 Issue: 26 Pages: 8770-8776

    • DOI

      10.1039/d0tc01487g

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NH Tautomerism of N-Confused Porphyrin: Solvent/Substituent Effects and Isomerization Mechanism2020

    • Author(s)
      Tomoya Ishizuka, Ryuichi Sakashita, Osamu Iwanaga, Tatsuki Morimoto, Shigeki Mori, Masatoshi Ishida, Motoki Toganoh, Kiyonori Takegoshi, Atsuhiro Osuka, Hiroyuki Furuta
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 124 Issue: 28 Pages: 5756-5769

    • DOI

      10.1021/acs.jpca.0c04779

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Helically π‐Extended N‐Confused Porphyrin Dimer via meso‐Bipyrrole‐Bridge with Near‐Infrared‐II Absorption Capability2020

    • Author(s)
      Yamasumi Kazuhisa、Notsuka Yusuke、Yamaoka Yoshihisa、Mori Shigeki、Ishida Masatoshi、Furuta Hiroyuki
    • Journal Title

      Chemistry A European Journal

      Volume: 26 Issue: 60 Pages: 13590-13594

    • DOI

      10.1002/chem.202002406

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] TTF-Annulated Silicon Phthalocyanine Oligomers and Their External-Stimuli-Responsive Orientational Ordering2020

    • Author(s)
      Y. Shiina, Y. Kage, K. Furukawa, H. Wang, H. Yoshikawa, H. Furuta, N. Kobayashi, and S. Shimizu
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 59 Issue: 50 Pages: 22721-22730

    • DOI

      10.1002/anie.202011025

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Expanded N-Confused Phlorin: A Platform for a Multiply Fused Polycyclic Ring System via Oxidation within the Macrocycle2020

    • Author(s)
      Li Chengjie、Li Qizhao、Shao Jiewei、Tong Zhangfa、Ishida Masatoshi、Baryshnikov Glib、Agren Hans、Furuta Hiroyuki、Xie Yongshu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 142 Issue: 40 Pages: 17195-17205

    • DOI

      10.1021/jacs.0c09572

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Modulation of Aromatic Circuits in the Triply Fused N-Confused Porphyrin Dimer System2022

    • Author(s)
      Furuta Hiroyuki
    • Organizer
      12th International Conference of Porphyrins and Phthalocyanines (ICPP-12)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] N-Confused Porphyrinoids: Directional Evolution from Porphyrin Isomer to Functional NIR Dyes2022

    • Author(s)
      Furuta Hiroyuki
    • Organizer
      XX Brazilian Meeting on Inorganic Chemistry (XXBMIC)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 「混乱から創造へ」; 混乱型ポルフィリノイドの創製と展開2022

    • Author(s)
      古田弘幸
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 三重縮環N-混乱ポルフィリン二量体の合成と物性2022

    • Author(s)
      岩永 修、石田 真敏、古田 弘幸
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 二光子励起光音響イメージング応用を目指した近赤外吸収BODIPY誘導体の合成と光物性2022

    • Author(s)
      嶋田 隆秀、石田 真敏、古田 弘幸
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis and Optical Properties of Donor-Acceptor-Donor Pyrrolopyrrole aza-BODIPYs2022

    • Author(s)
      Yitong Wang, Shigeki Mori, Hiroyuki Furuta, Soji Shimizu
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis of tetraaryl-substituted 5,15-dioxaporphyrin and its oxidation to the aromatic dication2022

    • Author(s)
      Jiping Hao, Shigeki Mori, Hiroyuki Furuta, Soji Shimizu
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ケイ素テトラアザポルフィリンμ-oxo二量体の合成と分光・電気化学特性2022

    • Author(s)
      井口 まり、森 重樹、古田 弘幸、清水 宗治
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] BO縮環構造を有するピロロピロールaza-BODIPYの合成とキラル光学特性2022

    • Author(s)
      深水 柊兵、森 重樹、古田 弘幸、清水 宗治
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Push-Pull 置換基を有するケイ素テトラアザポルフィリンの合成とμ-oxo 二量化2022

    • Author(s)
      金森 隆太郎、森 重樹、古田 弘幸、清水 宗治
    • Organizer
      日本化学会 第102春季年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Synthesis and Ring Rotation of Ruthenium μ-Oxo N-Confused Porphyrin Dimer2021

    • Author(s)
      Osamu Iwanaga, Kazuki Fukuyama, Takaaki Miyazaki, Masatoshi Ishida, Hiroyuki Furuta
    • Organizer
      第31回万有福岡シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] Copper 1,19-Diazadibenzonorrole: Rational Synthesis of a Porphyrin Analogue Containing N-N Direct Linkage2021

    • Author(s)
      Biju Basumatary, Masatoshi Ishida, Hiroyuki Furuta
    • Organizer
      International Conference on Porphyrins and Phthalocyanines -11
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ring Rotation Behavior of Ruthenium N-Confused Porphyrin [mu]-Oxo Dimers2021

    • Author(s)
      Osamu Iwanaga, Kazuki Fukuyama, Takaaki Miyazaki, Masatoshi Ishida, Hiroyuki Furuta
    • Organizer
      International Conference on Porphyrins and Phthalocyanines -11
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of α- and β-Alkynylated BODIPYs via Gold(I)-catalyzed Direct C-H Functionalization and Their Photophysical Properties2021

    • Author(s)
      Takahide Shimada, Masatoshi Ishida, Hiroyuki Furuta
    • Organizer
      International Conference on Porphyrins and Phthalocyanines -11
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Azabora[6]helicene誘導体の合成および光学特性2021

    • Author(s)
      水口波暉, 古田弘幸, 清水宗治
    • Organizer
      第58回 化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] N-混乱金属ポルフィリン修飾KTaO3;系光触媒による完全水分解2021

    • Author(s)
      吉田直也, 石田真敏, 古田弘幸
    • Organizer
      第58回 化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 近赤外光吸収色素の分子構造と光熱変換特性の相関関係2021

    • Author(s)
      鶴田英寿, BijuBasumatary, 石田真敏, 古田弘幸
    • Organizer
      第58回 化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 外部配位能を有する四置換ジオキサポルフィリンの合成2021

    • Author(s)
      池本彪流, 古田弘幸, 清水宗治
    • Organizer
      第58回 化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 二重N-混乱ジオキソヘキサフィリンを基盤とした光音響イメージング造影剤の開発2021

    • Author(s)
      甲斐浩太郎, 甲斐寛人, 石田真敏, 古田弘幸
    • Organizer
      第58回 化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] N-混乱ポルフィリンルテニウムμ-オキソ二量体の環回転制御2021

    • Author(s)
      岩永修、福山和希、宮﨑隆聡、石田真敏、古田弘幸
    • Organizer
      九州錯体化学懇談会第261回例会
    • Related Report
      2021 Annual Research Report
  • [Presentation] N-混乱金属ポルフィリン修飾Pt/KTa(Zr)O3 光触媒による水分解反応2021

    • Author(s)
      吉田直也、石田真敏、古田弘幸
    • Organizer
      第33回 若手研究者のためのセミナー
    • Related Report
      2021 Annual Research Report
  • [Presentation] Ring Rotation and Restriction of Ruthenium μ-Oxo N-Confused Porphyrin Dimer2021

    • Author(s)
      Osamu Iwanaga, Kazuki Fukuyama, Takaaki Miyazaki, Masatoshi Ishida, Hiroyuki Furuta
    • Organizer
      錯体化学会第71回討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 混乱アプローチ法による新規ポルフィリノイドの創製と機能化2021

    • Author(s)
      古田弘幸
    • Organizer
      第31回基礎有機化学討論
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] ブタジイン架橋π共役 BODIPY 二量体の合成と物性2021

    • Author(s)
      佐藤優真・石田真敏・古田弘幸
    • Organizer
      第31回基礎有機化学討論
    • Related Report
      2021 Annual Research Report
  • [Presentation] ケイ素テトラアザポルフィリンu-oxo 二量体の合成と分光特性の解明2021

    • Author(s)
      井口まり・森重樹・古田弘幸・清水宗治
    • Organizer
      第31回基礎有機化学討論
    • Related Report
      2021 Annual Research Report
  • [Presentation] α-アリールエチニル BODIPY 誘導体の合成と光物性2021

    • Author(s)
      佐藤優真・石田真敏・古田弘幸
    • Organizer
      2021ハロゲン利用ミニシンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] コバルトベンゾノロール錯体の電子構造と電気化学的水素発生2021

    • Author(s)
      橋口育歩、石田真敏、古田弘幸
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] アルキニル置換π拡張ボロンジピリン誘導体の合成2021

    • Author(s)
      佐藤優真、石田真敏、古田弘幸
    • Organizer
      日本化学会第101春季大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] N-混乱ポルフィリンルテニウム μ-オキソ二量体の合成と環回転2021

    • Author(s)
      岩永修、福山和毅、宮﨑隆聡、石田真敏、古田弘幸
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Synthesis and Characterization of N-Fused Porphyrin Iridium Complexes2021

    • Author(s)
      Jibin Alex Abraham, Masatoshi Ishida, and Hiroyuki Furuta
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] TTF縮環ケイ素テトラアザポルフィリンの合成2021

    • Author(s)
      井口まり、清水宗治、古田弘幸
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] β- 4置換5,15-ジオキサポルフィリンおよびジカチオン種の合成と構造2021

    • Author(s)
      長野純・古田弘幸・清水宗治
    • Organizer
      日本化学会第101回春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Synthesis and Characterization of N-fused porphyrin iridium complexes towards catalysis2020

    • Author(s)
      Jibin Alex Abraham, Masatoshi Ishida, Hiroyuki Furuta
    • Organizer
      Virtual Conference on Recent Advances in Bis and Tetra-Pyrrolic Molecular Materials
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Redox Property of N-Confused Porphyrin Dimer Complexes2020

    • Author(s)
      Osamu IWANAGA, Ritesh NANDY, Takaaki MIYAZAKI, Masatoshi ISHIDA, Hiroyuki FURUTA
    • Organizer
      第70回錯体化学会討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 異種拡張ポルフィリノイドの異核金属錯形成に基づく黒色色素の設計と合成2020

    • Author(s)
      王越、石田真敏、古田弘幸
    • Organizer
      第30回記念万有福岡シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] N-混乱ポルフィリン二量体二核金属錯体の酸化還元特性2020

    • Author(s)
      岩永 修,宮﨑 隆聡,石田 真敏,古田 弘幸
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] 芳香族C-H部位の直接アルキニル化反応を用いたエチニル置換BODIPY色素の位置選択的合成および光物性2020

    • Author(s)
      嶋田隆秀, 石田真敏、古田弘幸
    • Organizer
      第117回有機合成シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 芳香族 C-H 部位の直接アルキニル化反応 による BODIPY 誘導体の合成および光物性2020

    • Author(s)
      嶋田隆秀, 石田真敏、古田弘幸
    • Organizer
      基礎有機化学会第0回若手オンラインシンポジウム
    • Related Report
      2020 Annual Research Report

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Published: 2020-04-28   Modified: 2025-01-30  

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