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Solid-solid interface bonding of cathode active material and solid electrolyte by water vapor heating

Research Project

Project/Area Number 20H02451
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26030:Composite materials and interfaces-related
Research InstitutionOsaka University

Principal Investigator

Kozawa Takahiro  大阪大学, 接合科学研究所, 助教 (40734158)

Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2023: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2022: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2021: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Fiscal Year 2020: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Keywords水蒸気 / 固体電解質 / ナノ粒子 / 結晶化 / 多孔質粒子 / 微構造制御 / 粒成長 / 全固体電池 / 電極活物質 / 界面接合 / 正極活物質
Outline of Research at the Start

本研究では,電極活物質と固体電解質の微粒子が混合,積層されたバルク型全固体電池において,その微粒子間での良好な固固界面接合を水蒸気焼成で実現する。酸化物表面での水酸基形成と脱水縮合反応を誘起させる水蒸気に着目し,界面での酸素を介した結合形成を狙う。本研究では正極に焦点を当て,活物質-固体電解質が均質に分散して造粒されたコンポジット電極粒子や電極・電解質層内における接合界面評価,ならびに電極特性評価を行い,バルク型全固体電池の実用化の加速に貢献する。

Outline of Final Research Achievements

Focusing on the water vapor reaction on oxide surfaces, we aimed to realize solid-solid interface bonding between electrode active material and oxide-based solid electrolyte for lithium-ion batteries by water vapor heating. As a result, we succeeded in synthesizing a maze-like porous oxide with high-capacity anode performance by accelerating particle bonding and inserting conductive carbon nanoparticles into it to improve the cycle performance. We also found that structural changes occur on the surface of the cathode active material during heating in water vapor. Furthermore, the ultrafine particles of the oxide-based solid electrolyte were prepared, and its recrystallization was accelerated by water vapor heating. Composite electrodes were prepared by compositing the electrode active material with oxide-based solid electrolyte nanoparticles and were confirmed to work in an all-solid-state half-cell.

Academic Significance and Societal Importance of the Research Achievements

固体微粒子どうしの低温接合が水蒸気加熱プロセスで実現したことは、無機材料科学分野における新たな接合手法として期待され、その適用範囲の拡張が想定される。また、コンポジット電極の作製において、電極活物質と固体電解質との低温接合から界面での異相形成は抑制されると考えられる。水蒸気加熱プロセスは汎用的な技術であるため、バルク型全固体電池の実用化の加速に寄与できると考えられる。

Report

(5 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (28 results)

All 2024 2023 2022 2021 2020 Other

All Journal Article (11 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Open Access: 6 results) Presentation (15 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Development of nanostructured Ge/C anodes with a multistacking layer fabricated via Ar high-pressure sputtering for high-capacity Li<sup>+</sup>-ion batteries2024

    • Author(s)
      Omae Tomoki、Yamada Teruya、Fujikake Daiki、Kozawa Takahiro、Uchida Giichiro
    • Journal Title

      Applied Physics Express

      Volume: 17 Issue: 2 Pages: 026001-026001

    • DOI

      10.35848/1882-0786/ad2785

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Mechano-chemical hydrothermal synthesis of NH4NiPO4・H2O and its transformation to LiNiPO42024

    • Author(s)
      Huebner Jan、Kozawa Takahiro、Kondo Akira、Fukuyama Kayo、Naito Makio
    • Journal Title

      Advanced Powder Technology

      Volume: 35 Issue: 3 Pages: 104375-104375

    • DOI

      10.1016/j.apt.2024.104375

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Mechanical Synthesis of Lithium Titanate Hydrate in Liquid Phase Using a High Centrifugal Bead Mill2023

    • Author(s)
      Kondo Akira、Ishii Toshihiro、Kozawa Takahiro、Naito Makio
    • Journal Title

      Journal of the Society of Powder Technology, Japan

      Volume: 60 Issue: 9 Pages: 536-541

    • DOI

      10.4164/sptj.60.536

    • ISSN
      0386-6157, 1883-7239
    • Year and Date
      2023-09-10
    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanochemical Synthesis of Shape-Anisotropic Particles through Wet Milling Using High-Energy Mills2023

    • Author(s)
      Kozawa Takahiro、Fukuyama Kayo、Kondo Akira、Naito Makio
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 70 Issue: 2 Pages: 100-105

    • DOI

      10.2497/jjspm.70.100

    • ISSN
      0532-8799, 1880-9014
    • Year and Date
      2023-02-15
    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Single-step fabrication of fibrous Si/Sn composite nanowire anodes by high-pressure He plasma sputtering for high-capacity Li-ion batteries2023

    • Author(s)
      Uchida Giichiro、Masumoto Kodai、Sakakibara Mikito、Ikebe Yumiko、Ono Shinjiro、Koga Kazunori、Kozawa Takahiro
    • Journal Title

      Scientific Reports

      Volume: 13 Issue: 1 Pages: 14280-14280

    • DOI

      10.1038/s41598-023-41452-3

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Carbon nanoparticle-entrapped macroporous Mn3O4 microsphere anodes with improved cycling stability for Li-ion batteries2022

    • Author(s)
      Kozawa Takahiro, Kitabayashi Fumiya, Fukuyama Kayo, Naito Makio
    • Journal Title

      Scientific Reports

      Volume: 12 Issue: 1 Pages: 11992-11992

    • DOI

      10.1038/s41598-022-16383-0

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Formation mechanism of maze-like open macropores in Mn3O4 microspheres by heating in water vapor and their single-particle compressive behavior2022

    • Author(s)
      Kozawa Takahiro, Li Yuexuan, Hirahara Kaori
    • Journal Title

      Advanced Powder Technology

      Volume: 33 Issue: 12 Pages: 103844-103844

    • DOI

      10.1016/j.apt.2022.103844

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Combined wet milling and heat treatment in water vapor for producing amorphous to crystalline ultrafine Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte particles2021

    • Author(s)
      Takahiro Kozawa
    • Journal Title

      RSC Advances

      Volume: 11 Issue: 24 Pages: 14796-14804

    • DOI

      10.1039/d1ra02039k

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 水蒸気固相反応プロセスによる粒子合成2021

    • Author(s)
      小澤隆弘
    • Journal Title

      セラミックス

      Volume: 56 Pages: 526-530

    • Related Report
      2021 Annual Research Report
  • [Journal Article] 特異反応場を駆使した機能性微粒子の作製とその応用2021

    • Author(s)
      小澤隆弘,近藤光,内藤牧男
    • Journal Title

      生産と技術

      Volume: 73 Pages: 22-24

    • Related Report
      2021 Annual Research Report
  • [Journal Article] Macroporous Mn3O4 microspheres as a conversion-type anode material morphology for Li-ion batteries2020

    • Author(s)
      Kozawa Takahiro, Nishikawa Kei
    • Journal Title

      Journal of Solid State Electrochemistry

      Volume: 24 Issue: 6 Pages: 1283-1290

    • DOI

      10.1007/s10008-020-04625-y

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] 資源循環ナノ粒子回収に適用可能なマクロ多孔体の開発2023

    • Author(s)
      小澤隆弘
    • Organizer
      実装フェスタ関西2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] 多孔質球を用いた炭酸リチウムナノ粒子の捕集とリチウムイオン電池用正極合成への応用2023

    • Author(s)
      小澤隆弘
    • Organizer
      日本セラミックス協会第36回秋季シンポジウム
    • Related Report
      2023 Annual Research Report
  • [Presentation] 微構造制御された機能性粒子の開発とエネルギー分野への応用2023

    • Author(s)
      小澤隆弘
    • Organizer
      第141回マイクロ接合研究委員会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 水蒸気熱分解法による多孔質酸化マンガン球の形成機構とその単粒子解析2022

    • Author(s)
      小澤隆弘,Li Yuexuan,平原佳織
    • Organizer
      日本セラミックス協会第35回秋季シンポジウム
    • Related Report
      2022 Annual Research Report
  • [Presentation] Template-free preparation of macroporous Mn3O4 and its application as anodes for Li-ion batteries2022

    • Author(s)
      Kozawa Takahiro, Kitabayashi Fumiya, Fukuyama Kayo, Naito Makio
    • Organizer
      The 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水蒸気固相反応プロセスによる粒子合成への展開2022

    • Author(s)
      小澤隆弘
    • Organizer
      電子セラミック・プロセス研究会 第188回研究会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 多孔質Mn3O4/C複合粒子によるコンバージョン型リチウムイオン二次電池負極のサイクル性能向上2022

    • Author(s)
      小澤隆弘,北林史弥,福山香代,内藤牧男
    • Organizer
      日本セラミックス協会2022年年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 特異反応場を駆使した機能性微粒子の作製とその応用2021

    • Author(s)
      小澤隆弘,近藤光,内藤牧男
    • Organizer
      第18回産学連携シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] 微構造制御された正極活物質粒子の合成と全固体電池用コンポジット正極の作製2021

    • Author(s)
      小澤隆弘
    • Organizer
      全固体リチウムイオン電池技術の研究開発動向
    • Related Report
      2021 Annual Research Report
  • [Presentation] 高エネルギー粉砕による酸化物固体電解質の超微粒子作製と表面特性2021

    • Author(s)
      小澤隆弘
    • Organizer
      日本セラミックス協会第34回秋季シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] 水蒸気焼成による非晶質固体電解質の低温結晶化2021

    • Author(s)
      小澤隆弘
    • Organizer
      日本セラミックス協会第34回秋季シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] Preparation of conversion-type porous Mn3O4/C composite anode for lithium-ion batteries2021

    • Author(s)
      Fumiya Kitabayashi, Takahiro Kozawa, Makio Naito
    • Organizer
      The 8th Asian Particle Technology Symposium
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] LATP被覆LiNi1/2Mn3/2O4の電気化学インピーダンス法による評価2021

    • Author(s)
      今﨑充康,今泉純一,菊池剛,福山香代,小澤隆弘,内藤牧男
    • Organizer
      第62回電池討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 表面コーティングLNMO/LTOリチウムイオン電池のガス抑制効果2020

    • Author(s)
      今泉純一,今崎充康,菊池剛,福山香代,小澤隆弘,内藤牧男
    • Organizer
      第61回電池討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 湿式メカニカル法による異方性ナノ粒子の合成と高電位正極材料への展開2020

    • Author(s)
      樽美良紀,小澤隆弘,内藤牧男
    • Organizer
      粉体工学会2020年度秋期研究発表会
    • Related Report
      2020 Annual Research Report
  • [Remarks] 大阪大学接合科学研究所

    • URL

      http://www.jwri.osaka-u.ac.jp/

    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属オキシ水酸化物の凝集体および金属オキシ水酸化物の製造方法2023

    • Inventor(s)
      小澤隆弘
    • Industrial Property Rights Holder
      小澤隆弘
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2023-166399
    • Filing Date
      2023
    • Related Report
      2023 Annual Research Report

URL: 

Published: 2020-04-28   Modified: 2025-01-30  

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