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Development of innovative catalytic systems based on the construction of multifunctional active sites and deepening of their science

Research Project

Project/Area Number 20H02517
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27030:Catalyst and resource chemical process-related
Research InstitutionHokkaido University

Principal Investigator

Furukawa Shinya  北海道大学, 触媒科学研究所, 准教授 (10634983)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2022: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2021: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2020: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Keywords擬二元系合金 / 金属間化合物 / ハイエントロピー / 触媒 / 合金触媒 / 脱水素 / 多元素合金 / プロパン脱水素 / CO2有効利用 / 合金 / 反応場設計 / 多元機能
Outline of Research at the Start

本研究では合金触媒化学の知見、設計指針、研究手法、触媒調製ノウハウを一層発展させ、新規三元系合金を基盤材料とした、革新的触媒設計技法を確立する。特に、既存材料の問題点を克服するため、柔軟性と拡張性を併せ持つ活性点構造「多元機能活性サイト」を構築し、さらにそれらを応用することで従来材料では成しえない、革新的に高効率な触媒系の構築を目指す。またそれだけでなく、詳細なキャラクタリゼーションと計算化学を融合したメカニズム研究を進めることで、三元系合金の触媒化学の学理構築を促進するとともに、新規設計指針の妥当性を検証する。

Outline of Final Research Achievements

In this study, we have demonstrated that partial substitution of either or both of the A and B sites of the binary intermetallic compound AmBn by a close element in the periodic table can be extended to a quasi-binary alloy represented by (A1-xA'x)mBn or (A1-x-yA'xA''y)m(B1-p-qB'pB''q)n, thereby dramatically improving catalytic performance. Specifically, they succeeded in developing a group of catalysts that exhibit extremely high performance, including the world's highest, in reaction systems such as methylcyclohexane and propane dehydrogenation, NOx reduction, and propane oxidation dehydrogenation using CO2. In particular, those with multi-element substitutions on both sites are called high-entropy intermetallic compounds, and have shown extremely high novelty in terms of materials.

Academic Significance and Societal Importance of the Research Achievements

最近、ハイエントロピー合金(high-entropy alloy: HEA, 5元素以上からなる固溶体合金)が構造材料分野を中心に、触媒も含めた様々な分野で注目されてきている。一方でHEAは固溶体合金であるため原子の配列はランダムであり、触媒反応場の精密設計に不可欠な秩序構造を基本的に持たない。この点において我々が切り拓いたHEIの触媒化学は、現在の先進研究のさらに先を行く最新鋭の研究分野であり、なおかつ産学に対する影響力も極めて大きい。特にCO2を用いたプロパン酸化脱水素は化石資源によるプロピレン製造をカーボンニュートラル化できるため、Net Zero 2050に対する貢献も計り知れない。

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (34 results)

All 2023 2022 2021 2020 Other

All Int'l Joint Research (1 results) Journal Article (17 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 17 results,  Open Access: 2 results) Presentation (9 results) (of which Int'l Joint Research: 3 results,  Invited: 9 results) Patent(Industrial Property Rights) (7 results) (of which Overseas: 4 results)

  • [Int'l Joint Research] National University of Singapore(シンガポール)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Development of a Highly Stable Ternary Alloy Catalyst for Dry Reforming of Methane2023

    • Author(s)
      Liu Ke、Xing Feilong、Xiao Yiying、Yan Ning、Shimizu Ken-ichi、Furukawa Shinya
    • Journal Title

      ACS Catalysis

      Volume: 13 Issue: 6 Pages: 3541-3548

    • DOI

      10.1021/acscatal.2c05488

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nickel‐Based High‐Entropy Intermetallic as a Highly Active and Selective Catalyst for Acetylene Semihydrogenation2022

    • Author(s)
      Ma Jiamin、Xing Feilong、Nakaya Yuki、Shimizu Ken‐ichi、Furukawa Shinya
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 61 Issue: 27

    • DOI

      10.1002/anie.202200889

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Entropy Intermetallics Serve Ultrastable Single-Atom Pt for Propane Dehydrogenation2022

    • Author(s)
      Nakaya Yuki、Hayashida Eigo、Asakura Hiroyuki、Takakusagi Satoru、Yasumura Shunsaku、Shimizu Ken-ichi、Furukawa Shinya
    • Journal Title

      Journal of the American Chemical Society

      Volume: 144 Issue: 35 Pages: 15944-15953

    • DOI

      10.1021/jacs.2c01200

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tailoring Single‐Atom Platinum for Selective and Stable Catalysts in Propane Dehydrogenation2022

    • Author(s)
      Nakaya Yuki、Furukawa Shinya
    • Journal Title

      ChemPlusChem

      Volume: 87 Issue: 4

    • DOI

      10.1002/cplu.202100560

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metallic Catalysts for Oxidative Dehydrogenation of Propane Using CO <sub>2</sub>2022

    • Author(s)
      Xing Feilong、Furukawa Shinya
    • Journal Title

      Chemistry ? A European Journal

      Volume: 29 Issue: 3

    • DOI

      10.1002/chem.202202173

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ternary platinum-cobalt-indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO22022

    • Author(s)
      Feilong Xing, Yuki Nakaya, Shunsaku Yasumura, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      Nature Catalysis

      Volume: 5 Issue: 1 Pages: 55-65

    • DOI

      10.1038/s41929-021-00730-x

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Doubly Decorated Platinum-Gallium Intermetallics as Stable Catalysts for Propane Dehydrogenation2021

    • Author(s)
      Yuki Nakaya, Feilong Xing, Hyungwon Ham, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 36 Pages: 19715-19719

    • DOI

      10.1002/anie.202107210

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electroassisted Propane Dehydrogenation at Low Temperatures: Far beyond the Equilibrium Limitation2021

    • Author(s)
      Jianshuo Zhang, Ruoyun Ma, Hyungwon Ham, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      JACS Au

      Volume: 1 Issue: 10 Pages: 1688-1693

    • DOI

      10.1021/jacsau.1c00287

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Silica-decorated Ni-Zn alloy as a highly active and selective catalyst for acetylene semihydrogenation2021

    • Author(s)
      Wiyanti F. Simanulang, Jiamin Ma, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      Catalysis Science & Technology

      Volume: 11 Issue: 12 Pages: 4016-4020

    • DOI

      10.1039/d1cy00709b

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Towards the Circular Economy: Converting Aromatic Plastic Waste Back to Arenes over a Ru/Nb2O5 Catalyst2021

    • Author(s)
      Jing Yaxuan、Wang Yanqin、Furukawa Shinya、Xia Jie、Sun Chengyang、Hulsey Max J.、Wang Haifeng、Guo Yong、Liu Xiaohui、Yan Ning
    • Journal Title

      Angewandte Chemie

      Volume: 133 Issue: 10 Pages: 5587-5595

    • DOI

      10.1002/ange.202011063

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Silica‐Decoration Boosts Ni Catalysis for (De)hydrogenation: Step‐Abundant Nanostructures Stabilized by Silica2021

    • Author(s)
      Ham Hyungwon、Simanullang Wiyanti F.、Kanda Yasuharu、Wen Yu、Hashimoto Ayako、Abe Hideki、Shimizu Ken‐ichi、Furukawa Shinya
    • Journal Title

      ChemCatChem

      Volume: 13 Issue: 5 Pages: 1306-1310

    • DOI

      10.1002/cctc.202001946

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrosilylation of carbonyls over electron-enriched Ni sites of intermetallic compound Ni3Ga heterogeneous catalyst2021

    • Author(s)
      Takayama Tomoaki、Kariya Rio、Nakaya Yuki、Furukawa Shinya、Yamazoe Seiji、Komatsu Takayuki
    • Journal Title

      Chemical Communications

      Volume: - Issue: 35 Pages: 4239-4242

    • DOI

      10.1039/d0cc07916b

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Active, Selective, and Durable Catalyst for Alkane Dehydrogenation Based on a Well-designed Trimetallic Alloy2020

    • Author(s)
      Yuki Nakaya, Masayoshi Miyazaki, Seiji Yamazoe, Ken-ichi Shimizu, Shinya Furukawa
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 9 Pages: 5163-5172

    • DOI

      10.1021/acscatal.0c00151

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation2020

    • Author(s)
      Nakaya Yuki、Hirayama Jun、Yamazoe Seiji、Shimizu Ken-ichi、Furukawa Shinya
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 2838-2838

    • DOI

      10.1038/s41467-020-16693-9

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Catalyst design concept based on a variety of alloy materials: a personal account and relevant studies2020

    • Author(s)
      Furukawa Shinya、Komatsu Takayuki、Shimizu Ken-ichi
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 8 Issue: 31 Pages: 15620-15645

    • DOI

      10.1039/d0ta03733h

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PdIn-Based Pseudo-Binary Alloy as a Catalyst for NOx Removal under Lean Conditions2020

    • Author(s)
      Jeon Jaewan、Ham Hyungwon、Xing Feilong、Nakaya Yuki、Shimizu Ken-ichi、Furukawa Shinya
    • Journal Title

      ACS Catalysis

      Volume: 10 Issue: 19 Pages: 11380-11384

    • DOI

      10.1021/acscatal.0c03427

    • NAID

      120007160297

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Correlation between Activation Energy and the Electronic State of Pd-based Bimetallic Catalysts for H2-D2 Equilibration Obtained by XPS and DFT Calculations2020

    • Author(s)
      Miyazaki Masayoshi、Furukawa Shinya、Komatsu Takayuki
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: - Issue: 8 Pages: 1020-1025

    • DOI

      10.1246/bcsj.20200085

    • NAID

      130007888073

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] 合金材料を基盤とした高効率NOx還元およびアルカン脱水素触媒の開発2021

    • Author(s)
      古川 森也
    • Organizer
      石油学会第63回年会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Design of multi-functional catalyst based on alloy materials2021

    • Author(s)
      Shinya Furukawa
    • Organizer
      The 8th International Symposium of Institute for Catalysis
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多元合金反応場設計に基づく 高効率脱水素触媒系の構築2021

    • Author(s)
      古川 森也
    • Organizer
      第128回触媒討論会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Design of trimetallic alloy catalysts for highly efficient alkane dehydrogenation2021

    • Author(s)
      Shinya Furukawa
    • Organizer
      the 17th Japan-Taiwan Joint Symposium on Catalysis
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 合金材料を駆使した 革新的反応場の創製2021

    • Author(s)
      古川 森也
    • Organizer
      令和2年度日本表面真空学会 東北・北海道支部講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 多元素合金を駆使した反応場の設計と高効率脱水素触媒システムの開発2020

    • Author(s)
      古川 森也・中谷勇希・清水研一
    • Organizer
      MRMフォーラム2020
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 多元素合金を駆使した 高効率脱水触媒システムの開発2020

    • Author(s)
      古川 森也
    • Organizer
      水素エネルギー協会  第163回定例研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 合金材料を用いた 触媒科学の研究2020

    • Author(s)
      古川 森也
    • Organizer
      石油学会第20回北海道支部講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Highly efficient catalysis based on multimetallic alloys2020

    • Author(s)
      Shinya Furukawa
    • Organizer
      The 21st RIES-HOKUDAI International Symposium 間 [MA]
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Patent(Industrial Property Rights)] 脱水素用触媒2022

    • Inventor(s)
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Holder
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-090373
    • Filing Date
      2022
    • Related Report
      2022 Annual Research Report 2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 脱水素用触媒2021

    • Inventor(s)
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Holder
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-166497
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 脱水素用触媒2021

    • Inventor(s)
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Holder
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 脱水素用触媒2021

    • Inventor(s)
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Holder
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 脱水素用触媒2021

    • Inventor(s)
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Holder
      古川森也、中谷勇希、林田英悟
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 酸化脱水素用触媒2021

    • Inventor(s)
      古川森也、&#37026;飛龍
    • Industrial Property Rights Holder
      古川森也、&#37026;飛龍
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-088480
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 酸化脱水素用触媒2021

    • Inventor(s)
      古川森也、&#37026;飛龍
    • Industrial Property Rights Holder
      古川森也、&#37026;飛龍
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2021 Annual Research Report
    • Overseas

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Published: 2020-04-28   Modified: 2024-01-30  

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