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Exploration of physics of two-dimensional superstructures

Research Project

Project/Area Number 20H02566
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionNagoya University

Principal Investigator

Kitaura Ryo  名古屋大学, 理学研究科, 特任准教授 (50394903)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2022: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2021: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2020: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywords二次元半導体 / 結晶成長 / 光物性 / 二次元ヘテロ構造 / 超構造 / 機能開拓 / 二次元超構造 / 先端薄膜成長 / 固体物性 / 二次元結晶
Outline of Research at the Start

二次元結晶(原子層)の積層・接合によって生み出される二次元超構造を用いた機能・デバイス創出が、化学・物理・材料を巻き込んで基礎および応用に渡って大きな注目を集めている。本研究では、自由自在に二次元超構造を構築する新たな方法論の確立を通して、多彩な新奇二次元超構造を用いた革新的な物性化学を切り開く。

Outline of Final Research Achievements

This study has discovered a new method for growing two-dimensional semiconductor crystals with nanoscale junction structures, which was previously assumed to be impossible. The technique used was organic metalorganic chemical vapor deposition (MOCVD), where high vapor pressure Mo and W precursors were supplied to the growth chamber sequentially. This resulted in the creation of junction widths ranging from sub-nanometers to a few nanometers on hexagonal boron nitride substrates. The same approach was successful in creating stacked structures with junction interfaces. Through first-principles calculations and spectroscopic measurements, the electronic states and optical properties of these new nanostructures were thoroughly examined and verified.

Academic Significance and Societal Importance of the Research Achievements

本研究の意義は、新たなナノ構造作製手法を開発したことにある。これによって、従来法では実現できなかったナノスケール二次元ヘテロ構造をデザインして実現可能となり、これによって構造のデザインに基づいてさまざまな機能・物性を引き出すことが可能となる。とくに、二次元構造中にナノスケールの局所構造を作り込むことが可能となることから、量子光源や量子ビットといった量子技術への展開も視野に入る。

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (36 results)

All 2023 2022 2021 2020

All Journal Article (20 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 20 results,  Open Access: 7 results) Presentation (16 results) (of which Int'l Joint Research: 8 results,  Invited: 10 results)

  • [Journal Article] Gate-Induced Trans-Dimensionality of Carrier Distribution in Bilayer Lateral Heterosheet of MoS2 and WS2 for Semiconductor Devices with Tunable Functionality2023

    • Author(s)
      Maruyama Mina、Ichinose Nanami、Gao Yanlin、Liu Zheng、Kitaura Ryo、Okada Susumu
    • Journal Title

      ACS Applied Nano Materials

      Volume: 6 Issue: 7 Pages: 5434-5439

    • DOI

      10.1021/acsanm.2c05561

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An observation of a photovoltaic effect in MoS<sub>2</sub> nanoribbons fabricated with a top-down approach2023

    • Author(s)
      Zhang Shaochun、Xue Mengsong、Zeng Fanyu、Kitaura Ryo
    • Journal Title

      Applied Physics Express

      Volume: 16 Issue: 3 Pages: 035003-035003

    • DOI

      10.35848/1882-0786/acbf9f

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Transition Metal Dichalcogenide Nanoribbons Based on a Controllable O<sub>2</sub> Etching2023

    • Author(s)
      Canton-Vitoria Ruben、Hotta Takato、Xue Mengsong、Zhang Shaochun、Kitaura Ryo
    • Journal Title

      JACS Au

      Volume: 3 Issue: 3 Pages: 775-784

    • DOI

      10.1021/jacsau.2c00536

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Formation of a one-dimensional hole channel in MoS2 by structural corrugation2023

    • Author(s)
      Gao Yanlin、Nakajima Haruna、Maruyama Mina、Taniguchi Takashi、Watanabe Kenji、Kitaura Ryo、Okada Susumu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 62 Issue: 1 Pages: 015001-015001

    • DOI

      10.35848/1347-4065/acaae0

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Observation of the photovoltaic effect in a van der Waals heterostructure2023

    • Author(s)
      Zhang Shaochun、Maruyama Mina、Okada Susumu、Xue Mengsong、Watanabe Kenji、Taniguchi Takashi、Hashimoto Kazuki、Miyata Yasumitsu、Canton-Vitoria Ruben、Kitaura Ryo
    • Journal Title

      Nanoscale

      Volume: 15 Issue: 12 Pages: 5948-5953

    • DOI

      10.1039/d2nr06616e

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-effect transistor antigen/antibody-TMDs sensors for the detection of COVID-19 samples2023

    • Author(s)
      Canton-Vitoria Ruben、Sato Kotaro、Motooka Yashiro、Toyokuni Shinya、Liu Zheng、Kitaura Ryo
    • Journal Title

      Nanoscale

      Volume: 15 Issue: 9 Pages: 4570-4580

    • DOI

      10.1039/d2nr06630k

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Trion confinement in monolayer MoSe2 by carbon nanotube local gating2022

    • Author(s)
      Hotta Takato、Nakajima Haruna、Chiashi Shohei、Inoue Taiki、Maruyama Shigeo、Watanabe Kenji、Taniguchi Takashi、Kitaura Ryo
    • Journal Title

      Applied Physics Express

      Volume: 16 Issue: 1 Pages: 015001-015001

    • DOI

      10.35848/1882-0786/aca642

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interlayer Interactions in 1D Van der Waals Moire Superlattices2021

    • Author(s)
      Sihan Zhao, Ryo Kitaura, Pilkyung Moon, Mikito Koshino, Feng Wang
    • Journal Title

      Adv. Sci.

      Volume: 9 Issue: 2 Pages: 2103460-2103460

    • DOI

      10.1002/advs.202103460

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Continuous Fermi level tuning of Nb-doped WSe2 under an external electric field2021

    • Author(s)
      Hisama Kaoru、Gao Yanlin、Maruyama Mina、Kitaura Ryo、Okada Susumu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 61 Issue: 1 Pages: 015002-015002

    • DOI

      10.35848/1347-4065/ac3726

    • NAID

      120007193866

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Identification of the position of piezoelectric polarization at the MoS2/metal interface2021

    • Author(s)
      Umeda Masaya、Higashitarumizu Naoki、Kitaura Ryo、Nishimura Tomonori、Nagashio Kosuke
    • Journal Title

      Applied Physics Express

      Volume: 14 Issue: 12 Pages: 125002-125002

    • DOI

      10.35848/1882-0786/ac3d1f

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Versatile Post-Doping Towards Two-Dimensional Semiconductors2021

    • Author(s)
      Yuya Murai, Shaochun Zhang, Takato Hotta, Zheng Liu, Takahiko Endo, Hiroshi Shimizu, Yasumitsu Miyata, Toshifumi Irisawa, Yanlin Gao, Mina Maruyama, Susumu Okada, Hiroyuki Mogi, Tomohiro Sato, Shoji Yoshida, Hidemi Shigekawa, Takashi Taniguchi, Kenji Watanabe, Canton-Vitoria Ruben, Ryo Kitaura
    • Journal Title

      ACS Nano

      Volume: 2021,15,12 Issue: 12 Pages: 19225-19232

    • DOI

      10.1021/acsnano.1c04584

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Femtosecond photoluminescence from monolayer MoSe2 : Time-domain study on exciton diffusion2021

    • Author(s)
      K Saito, M Okada, R Kitaura, H Kishida, T Koyama
    • Journal Title

      Physical Review B

      Volume: 103 Issue: 20

    • DOI

      10.1103/physrevb.103.l201401

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unveiling the Photoinduced Electron‐Donating Character of MoS 2 in Covalently Linked Hybrids Featuring Perylenediimide2021

    • Author(s)
      Sideri Ioanna K.、Jang Youngwoo、Garc?s‐Garc?s Jose、Sastre‐Santos ?ngela、Canton‐Vitoria Ruben、Kitaura Ryo、Fern?ndez‐L?zaro Fernando、D'Souza Francis、Tagmatarchis Nikos
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 60 Issue: 16 Pages: 9120-9126

    • DOI

      10.1002/anie.202016249

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilization of metallic phases through formation of metallic/semiconducting lateral heterostructures2020

    • Author(s)
      Canton-Vitoria Ruben、Hotta Takato、Liu Zheng、Inoue Tsukasa、Kitaura Ryo
    • Journal Title

      The Journal of Chemical Physics

      Volume: 153 Issue: 8 Pages: 084702-084702

    • DOI

      10.1063/5.0012782

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Exciton?Exciton Collisions in an Ultraflat Monolayer MoSe2 Prepared through Deterministic Flattening2020

    • Author(s)
      Hotta Takato、Ueda Akihiko、Higuchi Shohei、Okada Mitsuhiro、Shimizu Tetsuo、Kubo Toshitaka、Ueno Keiji、Taniguchi Takashi、Watanabe Kenji、Kitaura Ryo
    • Journal Title

      ACS Nano

      Volume: 15 Issue: 1 Pages: 1370-1377

    • DOI

      10.1021/acsnano.0c08642

    • NAID

      120007170455

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exciton diffusion in hBN-encapsulated monolayer MoSe22020

    • Author(s)
      Hotta Takato、Higuchi Shohei、Ueda Akihiro、Shinokita Keisuke、Miyauchi Yuhei、Matsuda Kazunari、Ueno Keiji、Taniguchi Takashi、Watanabe Kenji、Kitaura Ryo
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 11 Pages: 115424-115424

    • DOI

      10.1103/physrevb.102.115424

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Mechanism of Van der Waals Heteroepitaxy in the Formation of MoS2/hBN Vertical Heterostructures2020

    • Author(s)
      Okada Mitsuhiro、Maruyama Mina、Okada Susumu、Warner Jamie H.、Kureishi Yusuke、Uchiyama Yosuke、Taniguchi Takashi、Watanabe Kenji、Shimizu Tetsuo、Kubo Toshitaka、Ishihara Masatou、Shinohara Hisanori、Kitaura Ryo
    • Journal Title

      ACS Omega

      Volume: 5 Issue: 49 Pages: 31692-31699

    • DOI

      10.1021/acsomega.0c04168

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Direct observation of molecular orbitals using synchrotron X-ray diffraction2020

    • Author(s)
      S. Kitou, Y. Hosogi, R. Kitaura, T. Naito, T. Nakamura, H. Sawa
    • Journal Title

      Crystals

      Volume: 10 Issue: 11 Pages: 998-998

    • DOI

      10.3390/cryst10110998

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dark-state impact on the exciton recombination of WS2 monolayers as revealed by multi-timescale pump-probe spectroscopy2020

    • Author(s)
      Kuroda Takashi、Hoshi Yusuke、Masubuchi Satoru、Okada Mitsuhiro、Kitaura Ryo、Watanabe Kenji、Taniguchi Takashi、Machida Tomoki
    • Journal Title

      Physical Review B

      Volume: 102 Issue: 19 Pages: 195407-195407

    • DOI

      10.1103/physrevb.102.195407

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Low frequency Raman study of interlayer couplings in WS2-MoS2 van der Waals heterostructures2020

    • Author(s)
      Saito Y, Kondo T, Ito H, Okada M, Shimizu T, Kubo T, Kitaura R
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: 6 Pages: 062004-062004

    • DOI

      10.35848/1347-4065/ab9400

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fabrication and optical properties of 2D-semiconductor-based heterostructures2022

    • Author(s)
      Kitaura Ryo
    • Organizer
      The 12th Symposium on Emerging materials
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Heterostructures based on two-dimensional semiconductors2022

    • Author(s)
      Kitaura, Ryo
    • Organizer
      SSDM
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] An exploration of lateral/vertical van der Waals heterostructures2022

    • Author(s)
      Kitaura, Ryo
    • Organizer
      OPA-JSAP symposium
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] An investigation of photovoltaic effects in two-dimensional systems2022

    • Author(s)
      Shaochun Zhang and Ryo Kitaura
    • Organizer
      Nanocarbon research meeting
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Ultrathin Lateral Heterostructures Based on Two-Dimensional Semiconductors2022

    • Author(s)
      Kitaura, Ryo
    • Organizer
      241st ECS Meeting
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 二次元系をベースとした混合次元系への展開2021

    • Author(s)
      北浦 良
    • Organizer
      第16回酸化グラフェン研究会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] An exploration of mix-dimensional structures2021

    • Author(s)
      Kitaura, Ryo
    • Organizer
      the International Workshop on Materials Science
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] An exploration of mix-dimensional systems2021

    • Author(s)
      Kitaura, Ryo
    • Organizer
      MANA Special Seminar
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Two-dimensional ultrathin lateral heterostructures2021

    • Author(s)
      Kitaura, Ryo
    • Organizer
      The 11th A3 symposium on emerging materials
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] One- and two-dimensional superlattices: Fabrication and properties2021

    • Author(s)
      Kitaura, Ryo
    • Organizer
      Pacifichem
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Tailor-made two dimensional nano-scale super-structures2021

    • Author(s)
      Nanami Ichinose, Satoshi Iida, Zheng Liu, Ryo Kitaura
    • Organizer
      第61回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] Transport behaviors of excitonic carriers in monolayer transition metal dichalcogenides2021

    • Author(s)
      Mengsong Xue,Takato Hotta, Ruben Canton-Vitoria, Ryo Kitaura
    • Organizer
      第61回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] Optical properties of Zn-porphyrin covalently bounded to MoS2 and WS22021

    • Author(s)
      Ruben Canton-Vitoria, Ryo Kitaura
    • Organizer
      The 60th Fullerene Nanotube Graphene General Symposium
    • Related Report
      2020 Annual Research Report
  • [Presentation] Transport properties of two-dimensional n/p-doped Transition Metal Dichalcogenides prepared trough a post-doping method2021

    • Author(s)
      Shaochun Zhang, Yuya Murai, Toshinori Shirafuji, Ryo Kitaura
    • Organizer
      The 60th Fullerene Nanotube Graphene General Symposium
    • Related Report
      2020 Annual Research Report
  • [Presentation] Building of Platforms to Explore Transport Dynamics of Excitons and Trions in Monolayer Transition Metal Dichalcogenides2021

    • Author(s)
      Mengsong Xue, Yuya Murai, Shaochun Zhang, Toshinori Shirafuji, Ryo Kitaura
    • Organizer
      The 60th Fullerene Nanotube Graphene General Symposium
    • Related Report
      2020 Annual Research Report
  • [Presentation] ポストドーピングによる遷移金属カルコゲナイド原子層のp/n型制御2021

    • Author(s)
      村井 雄也 ,劉崢,入沢 寿史,遠藤 尚彦,宮田 耕充,吉田 昭二, 岡田 晋,北浦 良
    • Organizer
      第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report

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Published: 2020-04-28   Modified: 2024-01-30  

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