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A rotational state-selected molecular beam study on adsorption dynamics on stepped surfaces

Research Project

Project/Area Number 20H02623
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 29020:Thin film/surface and interfacial physical properties-related
Research InstitutionNational Institute for Materials Science

Principal Investigator

Kurahashi Mitsunori  国立研究開発法人物質・材料研究機構, マテリアル基盤研究センター, 主席研究員 (10354359)

Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2023: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2022: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2021: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2020: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywords表面 / 酸素分子 / 配向 / ステップ / スピン / 水素分子 / 回転状態 / 量子状態 / 回転 / 酸素 / 水素
Outline of Research at the Start

表面への分子吸着過程は触媒反応素過程として重要であり、分子の配向や内部量子状態(回転、振動等)の影響を強く受ける。これらの影響は、一部の分子/平坦表面の系に対しては詳しく研究されているが、触媒活性点として重要なステップ・キンク等の非平坦構造における吸着に対してはよく理解されていない。本研究では、量子状態選別O2、H2ビームを用いたステップ等における配向・回転制御した反応実験を実現し、これらの問題解決を目指す。

Outline of Final Research Achievements

Steps play key roles in catalytic reactions on nano-particle catalysts, but the effects of the alignment of gas-phase molecules on the adsorption processes on stepped surfaces is not understood well. In the present study, by scanning a narrow spin-rotational state-selected O2 beam across a curved Pt(111) surface on which step density varies linearly with the horizontal distance from the apex of the crystal, we have investigated the alignment-dependent O2 adsorption and CO oxidation on stepped Pt surface. We also prepared a hyperpolarized ortho-H2 beam using the magnetic deflection technique and developed a system that allows us to investigate how the nuclear spin of H2 affects its adsorption and desorption processes.

Academic Significance and Societal Importance of the Research Achievements

入射O2分子の配向・運動エネルギー等のパラメータを制御した触媒反応特性をステップ密度の関数としてモニターする手法は、高指数面を用いる方法では容易でないステップとテラスの寄与の分離、活性化吸着と間接過程の寄与の分離を可能にするため、今後、様々な試料におけるステップに由来する反応過程の分析に役立つと予想される。観測されたステップとテラスの反応特性の違いや、ステップが隣接テラスに与える影響に関する知見は新奇で重要な効果と考えている。微細な量子状態選別分子ビームを試料上で走査する方法は、面内で膜厚等のパラメータが変化する様々な試料にも応用可能で測定の効率化にも貢献できる。

Report

(4 results)
  • 2023 Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (21 results)

All 2023 2022 2021 2020 Other

All Journal Article (6 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 6 results,  Open Access: 2 results) Presentation (11 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Spin-dependent metastable He atom scattering from ferromagnetic surfaces: Potential application to polarized-gas production2023

    • Author(s)
      Maruyama Haruka、Kurahashi Mitsunori、Asakawa Kanta、Hatakeyama Atsushi
    • Journal Title

      Physical Review A

      Volume: 107 Issue: 2

    • DOI

      10.1103/physreva.107.022811

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin and alignment effects in O2 chemisorption on Fe(110), Ni(111), and Co(0001) films grown on W(110)2022

    • Author(s)
      Kurahashi Mitsunori
    • Journal Title

      The Journal of Chemical Physics

      Volume: 157 Issue: 12 Pages: 124703-124703

    • DOI

      10.1063/5.0111934

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Probing Copper and Copper-Gold Alloy Surfaces with Space-Quantized Oxygen Molecular Beam2022

    • Author(s)
      Tsuda Yasutaka、Gueriba Jessiel Siaron、Ueta Hirokazu、Dino Wilson Agerico、Kurahashi Mitsunori、Okada Michio
    • Journal Title

      JACS Au

      Volume: 2 Issue: 8 Pages: 1839-1847

    • DOI

      10.1021/jacsau.2c00156

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Alignment and impact angular dependence to O2 sticking and dissociation on Pt(111) and close-packed steps2022

    • Author(s)
      de Willigen Maatje J. E.、Kurahashi Mitsunori、Juurlink Ludo B. F.
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 24 Issue: 30 Pages: 18227-18235

    • DOI

      10.1039/d2cp00934j

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Observation of a Half-Metallic Interface State for Pyridine-Adsorbed H/Fe3O4(100)2021

    • Author(s)
      Kurahashi Mitsunori、Sun Xia
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 12 Issue: 35 Pages: 8489-8494

    • DOI

      10.1021/acs.jpclett.1c02391

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Use of hexapole magnet and spin flipper combined with time-of-flight analysis to characterize state-selected paramagnetic atomic/molecular beams2021

    • Author(s)
      Kurahashi Mitsunori
    • Journal Title

      Review of Scientific Instruments

      Volume: 92 Issue: 1 Pages: 013201-013201

    • DOI

      10.1063/5.0031903

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] 量子状態選別分子ビームによる白金ステップ表面でのO2吸着、CO酸化反応解析2023

    • Author(s)
      倉橋 光紀
    • Organizer
      日本物理学会 2023年春季大会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 強磁性薄膜表面で散乱された準安定ヘリウム原子のスピン偏極計測:固体表面を用いたスピン偏極ガス生成に向けて2023

    • Author(s)
      丸山遙香, 倉橋 光紀, 浅川寛太, 畠山温.
    • Organizer
      第3回 新方式精密計測による物理・工学的変革を目指す回路技術調査専門委員会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Application of hyperthermal spin and alignment-controlled O2 beam to surface reaction analysis.2022

    • Author(s)
      Mitsunori Kurahashi
    • Organizer
      The 11th International Conference on Reactive Plasmas / 2022 Gaseous Electronics Conference (ICRP-11 / GEC 2022)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Scattering of spin polarized metastable helium atoms on ferromagnetic surfaces.2022

    • Author(s)
      丸山遙香, 倉橋 光紀, 浅川寛太, 畠山温
    • Organizer
      The 15th Asia-Pacific Physics Conference (APPC15)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 曲面研磨Pt(111)表面と回転状態選別O2ビームによる PtステップでのO2吸着・反応特性評価2022

    • Author(s)
      倉橋光紀
    • Organizer
      日本物理学会第77回年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 励起原子、配向酸素分子が誘起する表面反応素過程の分析2021

    • Author(s)
      倉橋光紀
    • Organizer
      第82回応用物理学会秋季学術講演会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 強磁性薄膜表面で散乱された準安定He原子のスピン偏極計測2021

    • Author(s)
      丸山遙香, 倉橋 光紀, 浅川寛太, 畠山温
    • Organizer
      第41回 原子衝突学会若手の会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Spin polarization measurement of metastable He atoms scattered from Fe3O4(100)2021

    • Author(s)
      H. Maruyama, M. Kurahashi, K. Asakawa, A. Hatakeyama
    • Organizer
      The 9th International Conference on Surface Science (ISSS-9)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 強磁性薄膜表面で散乱された準安定He原子のスピン偏極計測2021

    • Author(s)
      丸山遥香、倉橋光紀、浅川寛太、畠山温
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 量子状態選別O2, H2分子ビームの生成と表面反応計測への応用2020

    • Author(s)
      倉橋光紀
    • Organizer
      第67回応用物理学会春期学術講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] ピリジン/H/Fe3O4(100)表面のスピン偏極準安定脱励起分光測定: ハーフメタル的界面状態の観測2020

    • Author(s)
      倉橋光紀, 孫霞
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Annual Research Report
  • [Remarks]

    • URL

      https://samurai.nims.go.jp/profiles/kurahashi_mitsunori

    • Related Report
      2022 Annual Research Report
  • [Remarks]

    • URL

      https://samurai.nims.go.jp/profiles/kurahashi_mitsunori?locale=ja

    • Related Report
      2021 Annual Research Report
  • [Remarks]

    • URL

      https://samurai.nims.go.jp/profiles/kurahashi_mitsunori

    • Related Report
      2020 Annual Research Report
  • [Patent(Industrial Property Rights)] 酸化物材料の洗浄装置、および洗浄方法2021

    • Inventor(s)
      倉橋光紀、松田学
    • Industrial Property Rights Holder
      物質・材料研究機構, 住友精密工業株式会社
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2020 Annual Research Report

URL: 

Published: 2020-04-28   Modified: 2025-01-30  

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