Budget Amount *help |
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2023: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2022: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2021: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2020: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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Outline of Final Research Achievements |
In this study, we promoted the development of ionic molecular association whose functionalities can drastically change in response to external stimulus and/or environment. The specific achievements are as follows: 1.We successfully prepared liquescent ionic open-shell species based on dihydrophenazine, TTF, TCNQ, and Ni(mnt)2 salt, and found that simultaneous modulation of magnetic properties and near-infrared absorption characteristics. 2.We successfully prepared a metal complex salts with intriguing luminescent properties, such as rapid luminescence enhancement upon needle-stick stimulation, changes in emission wavelength significantly depending on the cooling rate after the solid-liquid phase transition, and significant changes in the luminescent properties depending on counter ions.
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