| Budget Amount *help |
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2022: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2021: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2020: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
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| Outline of Final Research Achievements |
We have investigated structures and properties of organoboron compounds in which boron vacant orbitals are integrated in various ways. We have found that (1) a diboron compound with two neighboring vacant orbitals exhibit dual fluorescence and environmental response properties due to the change in relative angles between the vacant orbitals, (2) boron-containing π-conjugated macrocycles exhibit a strong boron-olefin proximity interaction beyond van der Waals force, (3) a newly developed diborylacetylene derivative if useful for the synthesis of densely boron-containing materials, (4) boron- and nitrogen-containing heterocyclic compounds that are isoelectronic with anti-aromatic hydrocarbons show unique electronic properties.
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