Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2022: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2021: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2020: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
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Outline of Final Research Achievements |
In this project, C-H bond oxidation of alkanes catalyzed by diazaporphyrin metal complexes was performed. It was found that the diazaporphyrin metal complexes exhibit higher reactivity than conventional porphyrin metal complexes, and the difference in reactivity was attributed to the electron acceptivity of the main skeleton. The reactivity was further exploited to catalyze the C-H bond fluorination of alkanes.
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