| Budget Amount *help |
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2022: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2021: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2020: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
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| Outline of Final Research Achievements |
A new improved synthetic route for DATB derivatives has been identified. This chromatography free method allows us to access wide variety of derivatives in a highly reliable and efficient way, leading to further exploration in practical direct admiration catalysis and integrated one-pot transformations. As for the development of non-flat quinoline oligomers, we have developed the synthetic protocol for TEtraQuinoline and oxo-TriQuinoline. They can serve as a tetra dentate and tridentate nitrogen-based macrocyclic ligands, exhibiting attractive physicochemical properties and catalytic competency.
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