| Budget Amount *help |
¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2023: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2022: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2021: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Fiscal Year 2020: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
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| Outline of Final Research Achievements |
Tribo-luminescence is an unique phenomenon in crystalline compounds, wherein tribo-energy is converted to light energy. Recently, the lanthanide complex design with strong tribo-luminesence were revealed. In this study, the tribo-excited chemical reactions have been studied using the lanthanide complex based on the design with strong tribo-luminescence. The trivalent europium (Eu(III)) and gadolinium (Gd(III) complexes with stacked anthracene framework were prepared for the demonstration of the tribo-excited chemical reactions. The tribo-stimulus induced oxidation reaction and dimerizaiton of Eu(III) and Gd(III) complexes, respectively. Thus, I also successfully demonstrated the lanthanide ion dependent reactivity of tribo-excited chemical reaction.
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