| Budget Amount *help |
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2023: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2022: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2021: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2020: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
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| Outline of Final Research Achievements |
Synthesis of transition metal catalysts composed of common metals such as iron is expected to contribute the development of an alternative to the catalysis mediated by precious metal catalysts used in conventional methods. In general, iron complexes are known to be less active compared with the precious metal complex catalysts in activating the various kinds of chemical bonds of reaction substrates. However, we have developed the iron complex catalysts that can activate molecular hydrogen as well as hydrosilanes with high efficiency by utilizing the “metal-silicon bond” constructed by the introduction of organosilicon-based ligands into the metal center as a reaction site for substrate activation.
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