| Budget Amount *help |
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2023: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2022: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2021: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2020: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
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| Outline of Final Research Achievements |
In this study, we have created coordinatively unsaturated molecular transition metal carbide clusters, which serve as models for catalytic active species in the Fischer-Tropsch reaction and nitrogen fixation enzymes. Furthermore, we investigated the carbon chain formation reactions from carbides and the coordination and transformation modes of nitrogen fixation-related substrates using these clusters as the reaction field. This led to the acquisition of new academic insights that serve as an intellectual foundation for elucidating the functions of metal carbide species in the active sites of FT reactions and nitrogenases.
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