Clarification of operation mechanisms of next-generation organic/perovskite hybrid devices
Project/Area Number |
20H02817
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Review Section |
Basic Section 35030:Organic functional materials-related
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Research Institution | Kyushu University |
Principal Investigator |
Matsushima Toshinori 九州大学, カーボンニュートラル・エネルギー国際研究所, 准教授 (40521985)
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Project Period (FY) |
2020-04-01 – 2023-03-31
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Project Status |
Completed (Fiscal Year 2022)
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Budget Amount *help |
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2022: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2021: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2020: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
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Keywords | 2次元ペロブスカイト / 発光性有機アミン / LED / エネルギー移動 / キャリア輸送 / 金属ハライドペロブスカイト / 外部量子効率 / 蛍光性有機分子 / 有機分子 / 有機EL素子 / 一重項励起状態 |
Outline of Research at the Start |
これまでに申請者は、蛍光性有機分子を金属ハライドペロブスカイトに導入することにより、高効率で発光する有機EL(エレクトロルミネッセンス)素子を実現した。本研究では、なぜ高効率の発光が得られるのか理由を明らかにすることを目指す。本技術を用いれば、より低コストで高効率・高耐久性・低電圧駆動の有機EL製品を製造できるようになる。次に、有機材料とペロブスカイトを融合させたレーザーデバイス及び太陽電池などの次世代型デバイスに関する研究に着手する。
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Outline of Final Research Achievements |
In LEDs with a two-dimensional perovskite emitter, in which a benzothiadiazole (BT) derivative is used as the large organic cation for the structural organization, the electrons and holes injected from external electrodes are transported through inorganic metal halogen sheets. Then, the excitons are formed in inorganic metal halogen sheets by the recombination between the electrons and the holes. The bright exciton number is higher by three-fold than the dark exciton number, and the conversion from the dark excitons to the bright excitons efficiently happens. Therefore, all the excitons formed inside LEDs can be used to induce the energy transfer to the emissive singlet state of the BT moiety in the two-dimensional perovskite structure. In that case, 100% internal quantum efficiency is achieved in organic-fluorophore-containing two-dimensional perovskite LEDs.
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Academic Significance and Societal Importance of the Research Achievements |
有機EL素子において、通常は非発光性である三重項励起状態を発光に利用するためには、高価なりん光性イリジウム化合物もしくは精密な分子設計が必要な熱活性化遅延蛍光性(TADF)化合物を用いる必要があった。ところが、本研究で見出した、2次元ペロブスカイト構造中に蛍光性有機アミンを導入する方法を用いれば、りん光及びTADF型有機EL素子に匹敵する高い外部量子効率が得られるようになり、従って、将来的にディスプレイ及び照明産業に大きなインパクトを与える。
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Report
(4 results)
Research Products
(134 results)
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[Journal Article] Artificial p-n‐like Junction Based on Pure 2D Organic-Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moieties2023
Author(s)
Zhao Feng, Xuelong Liu, Kentaro Imaoka, Tomohiro Ishii, Ganbaatar Tumen‐Ulzii, Xun Tang, George F Harrington, Benoit Heinrich, Jean‐Charles Ribierre, Lise‐Marie Chamoreau, Lydia Sosa Vargas, David Kreher, Kenichi Goushi, Toshinori Matsushima, Guijiang Zhou, Fabrice Mathevet, Chihaya Adachi
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Journal Title
Advanced Optical Materials
Volume: 2202734
Issue: 10
Pages: 1-8
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Advanced Organic Laser System Having Triplet Scavengers2021
Author(s)
Buddhika S. B. Karunathilaka, Umamahesh Balijapalli, Toshinori Matsushima*, Atula S. D. Sandanayaka*, and Chihaya Adachi*
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Journal Title
NIHON GAZO GAKKAISHI (Journal of the Imaging Society of Japan)
Volume: 60
Issue: 6
Pages: 615-630
DOI
NAID
ISSN
1344-4425, 1880-4675
Year and Date
2021-12-10
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Energy transfer in (PEA)2FAn-1PbnBr3n+1 quasi-2D perovskites2021
Author(s)
Dziugas Litvinas, Ramunas Aleksiejunas*, Patrik Scajev, Paulius Baronas, Vaiva Soriute, Chuanjiang Qin, Takashi Fujihara, Toshinori Matsushima, Chihaya Adachi, and Saulius Jursenasy
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Journal Title
Journal of Materials Chemistry C
Volume: 9
Issue: 14
Pages: 4782-4791
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Improved Performance of Perovskite Solar Cells by Suppressing The Energy-Level Shift of The PEDOT:PSS Hole Transport Layer2021
Author(s)
Masayuki Yahiro*, Shun Sugawara, Shinichi Maeda, Yuko Shimoi, Pangpang Wang, Shin-ichiro Kobayashi, Kotaro Takekuma, Ganbaatar Tumen-Ulzii, Chuanjiang Qin, Toshinori Matsushima, Tadayuki Isaji, Yoshinori Kasai, Takashi Fujihara, and Chihaya Adachi
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Journal Title
ACS Applied Energy Materials
Volume: 4
Issue: 12
Pages: 14590-14598
DOI
Related Report
Peer Reviewed
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[Presentation] 有機膜の密度制御とデバイス応用2022
Author(s)
松島 敏則, 江崎 有, 青山 哲也, 安達 千波矢
Organizer
日本化学会第102春季年会(2022)中長期テーマシンポジウム ~高密度共役物質の未来~新しい電子共役から生み出される機能~(オンライン)
Related Report
Invited
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[Presentation] チエノキノイド分子配向薄膜トランジスタにおける冷間等方圧加圧による移動度向上2021
Author(s)
青山 哲也, 松島 敏則, 田中 利彦, Benoit Heinrich, Fabrice Mathevet, 村中 厚哉, 高石 和人, 内山 真伸, 松本 真哉, 山形 豊, 安達 千波矢, Jean-Charles Ribierre
Organizer
2021年第82回応用物理学会秋季学術講演会(オンライン)
Related Report
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[Presentation] High efficiency and durability from perovskite-organic hybrid light-emitting diodes2020
Author(s)
Toshinori Matsushima, Chuanjiang Qin, William J. Potscavage Jr, Atula S. D. Sandanayaka, Matthew R. Leyden, Fatima Bencheikh, Kenichi Goushi, Fabrice Mathevet, Benot Heinrich, Go Yumoto, Yoshihiko Kanemitsu and Chihaya Adachi
Organizer
The 27th International Display Workshops (IDW'20)
Related Report
Int'l Joint Research / Invited
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[Presentation] Efficient perovskite light-emitting diodes with triplet exciton management2020
Author(s)
Toshinori Matsushima, Chuanjiang Qin, William J. Potscavage Jr, Atula S. D. Sandanayaka, Matthew R. Leyden, Fatima Bencheikh, Kenichi Goushia, Fabrice Mathevete, Benot Heinrichf, Go Yumoto, Yoshihiko Kanemitsu and Chihaya Adachi
Organizer
The 12th Asian Conference on Organic Electronics (A-COE2020)
Related Report
Int'l Joint Research
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[Presentation] 有機半導体レーザーダイオードの電流励起発振の兆候2020
Author(s)
A. S. D. Sandanayaka, 松島敏則, F. Bencheikh, 寺川しのぶ, W. J. Potscavage, Jr., C. Qin, 藤原隆, 合志憲一, J-C Ribierre, 安達千波矢
Organizer
第81回応用物理学会秋季学術講演会
Related Report
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[Book] High efficiency and durability from perovskite-organic hybrid light-emitting diodes2020
Author(s)
Toshinori Matsushima, Chuanjiang Qin, William J. Potscavage Jr, Atula S. D. Sandanayaka, Matthew R. Leyden, Fatima Bencheikh, Kenichi Goushi, Fabrice Mathevet, Benot Heinrich, Go Yumoto, Yoshihiko Kanemitsu and Chihaya Adachi
Total Pages
4
Publisher
Proceedings of The 27th International Display Workshops (IDW'20)
Related Report
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[Book] Continuous-wave operation of solution-processed organic thin-film lasers2020
Author(s)
Adikari Mudiyanselage Chathuranganie Senevirathne, Van T. N. Mai, Atul Shukla, Buddhika S. B. Karunathilaka, Toshinori Matsushima, Atula S. D. Sandanayaka, Shih-Chun Lo, Ebinazar B. Namdas, and Chihaya Adachi
Total Pages
1
Publisher
Proceedings of SPIE, Organic and Hybrid Light Emitting Materials and Devices XXIV
Related Report
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