Project/Area Number |
20J11624
|
Research Category |
Grant-in-Aid for JSPS Fellows
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Allocation Type | Single-year Grants |
Section | 国内 |
Review Section |
Basic Section 40020:Wood science-related
|
Research Institution | Osaka University |
Principal Investigator |
朱 陸亭 大阪大学, 工学研究科, 特別研究員(DC2)
|
Project Period (FY) |
2020-04-24 – 2022-03-31
|
Project Status |
Completed (Fiscal Year 2021)
|
Budget Amount *help |
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2021: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2020: ¥900,000 (Direct Cost: ¥900,000)
|
Keywords | Cellulose paper / Laser writing / Humidity sensor / Polydopamine doping / 3D nanocarbon / Capacitive performance / Chitin nanofiber paper / Electrical conductivity / 3D porous nanocarbon / Nitrogen doped carbon / Photo sensor / Supercapacitor |
Outline of Research at the Start |
Biomass is a sustainable and environment-friendly resource on the earth which plays an important role in human life, especially bio-nanofiber materials with high strength, specific surface area and transparency. However, as insulators, bio-nanofibers have difficulty to be applied to electronics without hybridizing with other conductive materials. Therefore, we’d like to impart the electrical conductivity to bio-nanofibers by some green methods such as carbonization and laser irradiation, which could broaden their electrical applications such as sensors, supercapacitors and actuators.
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Outline of Annual Research Achievements |
In this year, I finished the following research. 1. All-cellulose-derived humidity sensor prepared by direct laser writing of electrodes on TEMPO-oxidized cellulose paper Cellulose is humidity-sensing due to many hydrophilic groups. However, the electrical insulation of cellulose makes nonrenewable noble metal electrodes essential to effectively detect electrical signals. Herein, I prepared sustainable laser-carbonized electrodes with good electrical conductivity and moisture-stable performance on TEMPO-oxidized cellulose paper. This all-cellulose-derived humidity sensor showed high sensitivity and linearity, and it can be used to monitor different biological activities. The research was published in Journal of Materials Chemistry C as an Inside Back Cover Paper (IF: 7.39, DOI: 10.1039/d1tc05339f). Moreover, I received an Excellent Poster Award at the 28th Annual Meeting of the Cellulose Society of Japan. 2. Polydopamine doping and pyrolysis of cellulose nanofiber paper for three-dimensional (3D) nanocarbon with improved yield and capacitive performances Pyrolysis of cellulose inevitably causes drastic carbon loss and volume shrinkage. I found that a small amount of polydopamine doping before pyrolysis can improve the yield and volume retention of cellulose derived nanocarbon. The pyrolyzed polydopamine-doped cellulose nanofiber paper had a larger specific surface area and electrical conductivity, therefore affording better specific capacitance as a supercapacitor electrode. This research was published in Nanomaterials as a Feature Paper (IF: 5.08, DOI: 10.3390/nano11123249).
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Research Progress Status |
令和3年度が最終年度であるため、記入しない。
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Strategy for Future Research Activity |
令和3年度が最終年度であるため、記入しない。
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