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3次元積層デバイス開発為の分子動力学計算によるプラズマエッチング反応の解析

Research Project

Project/Area Number 20J20961
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Review Section Basic Section 14030:Applied plasma science-related
Research InstitutionOsaka University

Principal Investigator

Cagomoc Charisse Marie  大阪大学, 工学研究科, 特別研究員(DC1)

Project Period (FY) 2020-04-24 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 2022: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2021: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 2020: ¥1,100,000 (Direct Cost: ¥1,100,000)
Keywordsplasma etching / molecular dynamics / high aspect ratio / 3D NAND / ion beam experiment / high-aspect ratio / molecular dynamics (MD)
Outline of Research at the Start

- Ion beam experiments on silicon dioxide and silicon nitride using various ions for HAR etching.
- Plasma experiments in Ruhr University of Bochum
- Molecular dynamics simulations of silicon dioxide and silicon nitride HAR etching using various ions.
- Plasma diagnostics in the University of York

Outline of Annual Research Achievements

The 3D NAND flash memory technology has been the primary solution for any platforms requiring data storage. Its memory capacity is dictated by the number of alternating silicon dioxide (SiO2) and silicon nitride (SiN) stacked films (referred to as ONO) deposited on a Si substrate. Hole channels with a high aspect ratio (AR) and straight profiles are etched through the stacked films to form the memory cell arrays. However, maintaining a straight profile becomes more difficult as the AR increases. As such, high aspect ratio (HAR) etching has been the roadblock for 3D NAND devices with larger storage capacity. In this research, experiments, and simulations had been performed to understand the HAR etching process in the fabrication of 3D NAND memory devices. For the experiment, SiO2, SiN, and ONO stacked films deposited on Si wafers were etched with Ar and CF3 ions using the mass-selected ion beam system. The etch yields and etch rates were calculated, and the films were characterized by X-ray photoelectron spectroscopy (XPS). For the simulation, molecular dynamics (MD) simulations of the etching of SiO2, SiN, and ONO by Ar, Cl, and CF3 ions were done. The etch yields from the simulations were compared to the etch yields from the experiments wherein a relatively good agreement was attained. As such, some of the results of the research have been presented at various domestic and international conferences. The research has also been summarized in a dissertation and published in 3 scientific papers.

Research Progress Status

令和4年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和4年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (8 results)

All 2023 2022 2021 2020

All Journal Article (3 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 3 results) Presentation (5 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Molecular dynamics study of SiO2 nanohole etching by fluorocarbon ions2023

    • Author(s)
      Cagomoc Charisse Marie D.、Isobe Michiro、Hamaguchi Satoshi
    • Journal Title

      Journal of Vacuum Science and Technology A

      Volume: 41 Issue: 2 Pages: 023001-023001

    • DOI

      10.1116/6.0002380

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Inert-gas ion scattering at grazing incidence on smooth and rough Si and SiO2 surfaces2023

    • Author(s)
      Cagomoc Charisse Marie D.、Isobe Michiro、Hudson Eric A.、Hamaguchi Satoshi
    • Journal Title

      Journal of Vacuum Science and Technology A

      Volume: 41 Issue: 2 Pages: 023003-023003

    • DOI

      10.1116/6.0002381

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Molecular dynamics simulation of oxide-nitride bilayer etching with energetic fluorocarbon ions2022

    • Author(s)
      Cagomoc Charisse Marie D.、Isobe Michiro、Hudson Eric A.、Hamaguchi Satoshi
    • Journal Title

      Journal of Vacuum Science and Technology A

      Volume: 40 Issue: 6 Pages: 063006-063006

    • DOI

      10.1116/6.0002182

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Molecular Dynamics Simulation of Oxide-Nitride Stacked Layer Etching by Energetic Fluorocarbon Ions2022

    • Author(s)
      Charisse Marie D. Cagomoc, Michiro Isobe, Eric A. Hudson, Satoshi Hamaguchi
    • Organizer
      65th Annual SVC Technical Conference
    • Related Report
      2022 Annual Research Report
  • [Presentation] Molecular Dynamics Simulation of Oxide and Nitride Etching by CF3+ and Cl+2022

    • Author(s)
      Charisse Marie D. Cagomoc, Shoichi Taira, Michiro Isobe, Tomoko Ito, Kazuhiro karahashi, Leonid Belau, Eric A. Hudson, Satoshi Hamaguchi
    • Organizer
      AVS 68th International Symposium & Exhibition
    • Related Report
      2022 Annual Research Report
  • [Presentation] Molecular Dynamics Study of Oxide-Nitride Etching by CF3+ Ions2021

    • Author(s)
      Charisse Marie D. Cagomoc, Michiro Isobe, Eric A. Hudson, and Satoshi Hamaguchi
    • Organizer
      82nd JSAP Autumn Meeting 2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] Molecular Dynamics Simulation of Oxide-Nitride Layer Etching by Fluorocarbon Plasmas2021

    • Author(s)
      Charisse Marie D. Cagomoc, Michiro Isobe, Eric A. Hudson, and Satoshi Hamaguchi
    • Organizer
      AVS 67th Virtual Symposium
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Molecular Dynamics Study of Ion Scattering on Si and SiO22020

    • Author(s)
      Charisse Marie D. Cagomoc, Michiro Isobe, Eric A. Hudson, and Satoshi Hamaguchi
    • Organizer
      23rd Symposium on Application of Plasma Process (SAPP XXIII)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research

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Published: 2020-07-07   Modified: 2024-03-26  

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