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Development of multi-elements triple stable isotope measurements and its application

Research Project

Project/Area Number 20K04108
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 17040:Solid earth sciences-related
Research InstitutionOkayama University

Principal Investigator

Tanaka Ryoji  岡山大学, 惑星物質研究所, 教授 (00379819)

Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2021: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2020: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords安定同位体 / 遷移金属元素 / 遷移元素同位体 / 物質反応過程 / 質量依存同位体分別 / ケイ素同位体 / 質量依存分別 / エンスタタイトコンドライト / ケイ素 / 遷移元素
Outline of Research at the Start

安定同位体は、自然界における物質反応過程を解読する為の優れたトレーサーである。安定同位体は個々の反応過程において、平衡論的同位体効果と速度論的同位体効果を生じるが、2つの同位体では、これらを判別する術を持たない。これを解決するのが、3安定同位体法である。本研究では、これまで開発してきた3酸素同位体解析法に加え、ケイ素と遷移元素の3安定同位体解析法を開発し、これを同位体分別係数の決定、天然における化学・生物反応過程による同位体分別解読に応用する。期待される研究成果は、小惑星や初期惑星系における固液気相間反応過程、初期惑星表層における生命活動痕跡解読、初期地球表層温度推定等の研究に応用できる。

Outline of Final Research Achievements

High-precision isotopic measurements for oxygen, silicon, magnesium, calcium, nickel, and chromium were developed, and these methods were applied to the study of gas-melt reaction processes in the inner region of the protoplanetary disk, submarine hydrothermal system, the formation of the parent body of the asteroid Ryugyu, etc. In this project, multi-element isotopes were mainly used for these studies. In addition, the possibility to discriminate the equilibrium and kinetic isotope effects based on the relationship between two isotope ratios. With current analytical precision, only oxygen isotopes are applicable, and further improvement of analytical precision is required for the use of other elements.

Academic Significance and Societal Importance of the Research Achievements

安定同位体は、様々な物質の反応過程を解析するための強力なツールである。本研究で開発された、微少量かつ様々な化学組成を持つ試料に応用可能な多元素同位体分析法は、地球惑星科学だけでなく他の研究分野への応用も可能である。また、2つの同位体比を用いて平衡論的または速度論的反応過程を判別する方法は、現在は限られた元素にのみ有効だが、さらなる技術革新により、より広範囲の元素にこの手法を適用可能にすることが期待される。

Report

(5 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (42 results)

All 2024 2023 2022 2021 2020 Other

All Int'l Joint Research (16 results) Journal Article (16 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 16 results,  Open Access: 8 results) Presentation (5 results) (of which Int'l Joint Research: 5 results) Remarks (5 results)

  • [Int'l Joint Research] Uppsala University/Stockholm University(スウェーデン)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] Natural History Museum Vienna(オーストリア)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] University of Arkansas(米国)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] Physical Research Laboratory(インド)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] Uppsala University/Stockholm University(スウェーデン)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] University of Lausanne/ETH(スイス)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] The University of New South Wales/The University of Newcastle(オーストラリア)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Lehigh University/Brown University/Florida State University(米国)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Natural History Museum Vienna(オーストリア)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research]

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] The Open University(英国)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] Uppsala University/Stockholm University(スウェーデン)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] Natural History Museum Vienna(オーストリア)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] University of Lausanne(スイス)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] The University of New South Wales/The University of Newcastle(オーストラリア)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research]

    • Related Report
      2020 Research-status Report
  • [Journal Article] Unraveling the Cr Isotopes of Ryugu: An Accurate Aqueous Alteration Age and the Least Thermally Processed Solar System Material2024

    • Author(s)
      Tanaka, R., Ratnayake, D. M. et al.
    • Journal Title

      The Astrophysical Journal

      Volume: 965 Issue: 1 Pages: 52-52

    • DOI

      10.3847/1538-4357/ad276a

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Determination of mass-dependent chromium isotopic compositions in geological samples by double spike-total evaporation-thermal ionization mass spectrometry (DS-TE-TIMS)2023

    • Author(s)
      Ratnayake, D. M., Tanaka, R. Nakamura, E.
    • Journal Title

      Analytica Chimica Acta

      Volume: 1278 Pages: 341723-341723

    • DOI

      10.1016/j.aca.2023.341723

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Insights into the formation and evolution of extraterrestrial amino acids from the asteroid Ryugu2023

    • Author(s)
      Potiszil Christian, Ota Tsutomu, Yamanaka Masahiro, Sakaguchi Chie, Kobayashi Katsura, Tanaka Ryoji, Kunihiro Tak, Kitagawa et al.
    • Journal Title

      Nature Communications

      Volume: 14 Issue: 1 Pages: 1482-1482

    • DOI

      10.1038/s41467-023-37107-6

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] A rapid method of simultaneous chromatographic purification of Li and Mg for isotopic analyses using MC-ICP-MS2022

    • Author(s)
      Zhang Wei, Tanaka Ryoji, Kitagawa Hiroshi, Bohlin Madeleine, Nakamura Eizo
    • Journal Title

      International Journal of Mass Spectrometry

      Volume: 480 Pages: 116893-116893

    • DOI

      10.1016/j.ijms.2022.116893

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Malotas (b), a new eucrite from an old fall2022

    • Author(s)
      Saavedra Marcela E., Roszjar Julia, Riebe My E. I., Varela Maria E., Yang Shuying, Humayun Munir, Tanaka Ryoji, Busemann H.
    • Journal Title

      Meteoritics & Planetary Science

      Volume: 57 Issue: 11 Pages: 2081-2101

    • DOI

      10.1111/maps.13913

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Liquid-phase water isotope separation using graphene-oxide membranes2022

    • Author(s)
      Karin, C., Andy, B., Tanaka, R., Tingwen, Z., Zhen, S., Ruoff, R. S., Chuan, Z., Xianjue, C.
    • Journal Title

      Carbon

      Volume: 186 Pages: 344-354

    • DOI

      10.1016/j.carbon.2021.10.009

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nitrogenous Altered Volcanic Glasses as Targets for Mars Sample Return: Examples From Antarctica and Iceland2022

    • Author(s)
      M. P. Nikitczuk, G. E. Bebout, T. Ota, T. Kunihiro, J. F. Mustard, R. L. Flemming, R. Tanaka, S. A. Halldorsson, E. Nakamura
    • Journal Title

      Advancing Earth and Space Science

      Volume: 125 Issue: 2 Pages: 1-31

    • DOI

      10.1029/2021je007052

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mineralogical Factors Controlling the Ability to Retain 137Cs in Andosols in Japan2022

    • Author(s)
      Nakao, A., Uno, S., Tanaka, R., Yanai, J.
    • Journal Title

      Behavior of Radionuclides in the Environment III

      Volume: - Pages: 365-375

    • DOI

      10.1007/978-981-16-6799-2_16

    • ISBN
      9789811667985, 9789811667992
    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] The ice-organic-silicate contents of small solar system bodies: indicators for a comet to asteroid evolutionary pathway2022

    • Author(s)
      Tripathi, H., Potiszil, C., Tanaka, R., Nakamura, E.
    • Journal Title

      Monthly Notices of the Royal Astronomical Society

      Volume: -

    • DOI

      10.1093/mnras/stac1068

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] On the origin and evolution of the asteroid Ryugu: A comprehensive geochemical perspective2022

    • Author(s)
      Nakamura, E., Kobayashi, K., Tanaka, R, et al.
    • Journal Title

      Proceedings of the Japan Academy, Series B

      Volume: -

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Novel nickel isolation procedure for a wide range of sample matrices without using dimethylglyoxime for isotope measurements using MC-ICP-MS2021

    • Author(s)
      Ratnayake, D. M., Tanaka, R., Nakamura, E.
    • Journal Title

      Analytica Chimica Acta

      Volume: 1181 Pages: 338934-338934

    • DOI

      10.1016/j.aca.2021.338934

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] A New Insight Into Seawater-Basalt Exchange Reactions Based on Combined δ18O?Δ′17O?87Sr/86Sr Values of Hydrothermal Fluids From the Axial Seamount Volcano, Pacific Ocean2021

    • Author(s)
      Zakharov D. O., Tanaka R., Butterfield D. A., Nakamura E.
    • Journal Title

      Frontiers in Earth Science

      Volume: 9 Pages: 691699-691699

    • DOI

      10.3389/feart.2021.691699

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Silicon and oxygen isotope evolution of the inner solar system2021

    • Author(s)
      Tanaka, R., Potiszil, C., Nakamura, E.
    • Journal Title

      The Planetary Science Journal

      Volume: 2 Issue: 3 Pages: 102-102

    • DOI

      10.3847/psj/abf490

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Distance-dependence from volcano for Asian dust inclusions in Andosols: A key to control soil ability to retain radiocesium2021

    • Author(s)
      Nakao, A., Uno, S., Yanai, J., Kubotera, H., Tanaka, R., Robert A. Root, R. A., Kosaki, T.
    • Journal Title

      Geoderma

      Volume: 385 Pages: 114889-114889

    • DOI

      10.1016/j.geoderma.2020.114889

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Comment on: ‘A simple cryogenic method for efficient measurement of triple oxygen isotopes in silicates’ by Ghoshmaulik et al. (Rapid Commun Mass Spectrom. 2020;34(18):e8833)2020

    • Author(s)
      Miller, M. F., Tanaka. R., Greenwood, R. C.
    • Journal Title

      Rapid Communications in Mass Spectrometry

      Volume: 34 Issue: 22

    • DOI

      10.1002/rcm.8913

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] The Albedo of Ryugu: Evidence for a High Organic Abundance, as Inferred from the Hayabusa2 Touchdown Maneuver2020

    • Author(s)
      Christian Potiszil, Ryoji Tanaka, Katsura Kobayashi, Tak Kunihiro, Eizo Nakamura
    • Journal Title

      Astrobiology

      Volume: 20 Issue: 7 Pages: 916-921

    • DOI

      10.1089/ast.2019.2198

    • NAID

      120007004817

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Aqueous alteration on the progenitor body of the asteroid Ryugu revealed through H-C-N-O isotope systematics2023

    • Author(s)
      Tanaka, R., Potiszil, C., Ota, T,, Kunihiro, T., Sakaguchi, C., Kobayashi, K., Kitagawa, H., Yamanaka, M., Nakamura, E.
    • Organizer
      Goldschmidt 2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a sequential ion exchange chromatography method to separate geochemically important tracers for isotope measurements2023

    • Author(s)
      Ratnayake, D., Tanaka, R., Nakamura, E.
    • Organizer
      Goldschmidt 2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Aqueous alteration on the progenitor body of the asteroid Ryugu revealed through H-C-N-O isotope systematics2023

    • Author(s)
      Ryoji Tanaka, Christian Potiszil, Tsutomu Ota, Tak Kunihiro, Chie Sakaguchi, Katsura Kobayashi, Hiroshi Kitagawa, Masahiro Yamanaka, Eizo Nakamura
    • Organizer
      Goldshmidt 2023
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Constraining the processes responsible for the origin and evolution of extraterrestrial organic matter: evidence from the asteroid Ryugu2023

    • Author(s)
      Christian Potiszil, Katsura Kobayashi, Ryoji Tanaka, Tak Kunihiro, Hiroshi Kitagawa, Tsutomu Ota, Masahiro Yamanaka, Chie Sakaguchi, Eizo Nakamura
    • Organizer
      Goldshmidt 2023
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of a sequential ion exchange chromatography method to separate geochemically important tracers for isotope measurements2023

    • Author(s)
      Ratnayake Mudiyanselage Dilan Madusanka Ratnayake, Ryoji Tanaka, Eizo Nakamura
    • Organizer
      Goldshmidt 2023
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Remarks] 小惑星リュウグウの起源と進化 -- 地球化学総合解析による太陽系物質進化の描像

    • URL

      https://pml.misasa.okayama-u.ac.jp/pages/projects/Ryugu2022/

    • Related Report
      2022 Research-status Report
  • [Remarks] 小惑星リュウグウに記録されたアミノ酸生成の痕跡

    • URL

      https://pml.misasa.okayama-u.ac.jp/pages/projects/Ryugu2023/index-ja.php

    • Related Report
      2022 Research-status Report
  • [Remarks] 初期太陽系における地球型惑星の材料物質の進化を解明

    • URL

      https://pml.misasa.okayama-u.ac.jp/pages/projects/tanakaetal2021siois.php

    • Related Report
      2021 Research-status Report
  • [Remarks] 大量の有機物からなる小惑星「リュウグウ」

    • URL

      https://pml.misasa.okayama-u.ac.jp/pages/projects/ryugu-albedo-2020.php

    • Related Report
      2020 Research-status Report
  • [Remarks] Discussing Science

    • URL

      https://pml.misasa.okayama-u.ac.jp/pages/news/ryocomm2020rpcms.php

    • Related Report
      2020 Research-status Report

URL: 

Published: 2020-04-28   Modified: 2025-01-30  

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