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Control of Phase Transition Temperature on Environmental Friendly Lead-free Piezoelectric Ceramics based on Bismuth Sodium Titanate

Research Project

Project/Area Number 20K04564
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 21050:Electric and electronic materials-related
Research InstitutionTokyo University of Science

Principal Investigator

Nagata Hajime  東京理科大学, 理工学部電気電子情報工学科, 教授 (70339117)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2021: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2020: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords非鉛圧電セラミックス / チタン酸ビスマスナトリウム / 脱分極温度 / 急冷処理 / 非鉛強誘電体セラミックス / 菱面晶 / 結晶構造解析 / クエンチ
Outline of Research at the Start

環境にやししい非鉛系圧電セラミックスの候補として注目されているチタン酸ビスマスナトリウム系セラミックスは、圧電性の消失する温度が100~200℃と低いことから実用化に向けて課題を有している。我々はこれまでに、セラミックスを急冷して作製することにより動作温度範囲を広げることが出来ることを実験的に明らかにしてきた。しかしながらそのメカニズムが明らかになっていなかった。そこで本研究では、材料の結晶構造や内部構造を詳細に分析することによりそのメカニズム解明を行う。さらに、メカニズム解明を通じて、優れた圧電性と広い動作温度範囲を併せもつ材料設計指針を得る。

Outline of Final Research Achievements

Bismuth sodium titanate [(Bi1/2Na1/2)TiO3, BNT]-based ceramics is attracting attention as a candidate material for environment-friendly lead-free piezoelectric materials because it exhibits relatively good piezoelectric properties. However, the depolarization temperature Td at which the piezoelectricity disappears is as low as about 100 to 200oC. This is one of the major concerns for the practical piezoelectric applications of BNT-based ceramics. We have experimentally found that Td could be increased about 50 to 80oC by quenching treatment from 1000oC after sintering without deteriorating the excellent piezoelectricity. In addition, it was clarified that the mechanism is strongly related to the increase in rhombohedral distortion of crystal structure and the increase in the domain size.

Academic Significance and Societal Importance of the Research Achievements

本研究成果で提案するクエンチ処理は、BNT系セラミックスのTd高温化に寄与するだけでなく、ハイパワー圧電特性(超音波性能)を維持する結果を示した。すなわち、本成果はBNT系セラミックスを環境にやさしい非鉛圧電材料として、超音波応用デバイスへの実用化していく点において、大きく前進させたものと考えられる。また、構造歪みの増大やドメインサイズの増大はビスマス系ペロブスカイト型強誘電体セラミックスの相転移制御において新たな学術的コンセプトを与えたものと考えられる。

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (22 results)

All 2023 2022 2021 2020

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 3 results) Presentation (14 results) (of which Int'l Joint Research: 6 results,  Invited: 6 results)

  • [Journal Article] Oxygen tracer diffusion analysis and observation of domain structure in quenched (Bi<sub>0.5</sub>Na<sub>0.5</sub>)TiO<sub>3</sub> ceramics2022

    • Author(s)
      Takagi Yuka、Ochiai Yuta、Ito Mihiro、Kawagoe Takumi、Nagata Hajime、Sakaguchi Isao
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 61 Issue: SN Pages: SN1034-SN1034

    • DOI

      10.35848/1347-4065/ac8d9e

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] High-power piezoelectric properties of quenched (Bi<sub>0.5</sub>Na<sub>0.5</sub>)TiO<sub>3</sub>-based solid-solution ceramics2022

    • Author(s)
      Tayama Takeru、Takagi Yuka、Nagata Hajime
    • Journal Title

      Journal of Applied Physics

      Volume: 132 Issue: 6 Pages: 064101-064101

    • DOI

      10.1063/5.0094400

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quenching effects on depolarization temperature and 18O tracer diffusion in (Bi0.5Na0.5)TiO3 ceramics with acceptor and donor additives2021

    • Author(s)
      Yuka TAKAGI, Kohtaro EGUCHI, Hajime NAGATA, Isao SAKAGUCHI and Tadashi TAKENAKA
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 129 Pages: 383-389

    • NAID

      130008060692

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of dielectric properties and phase transition behavior in quenched (Bi0.5Na0.5)TiO3 ceramics2021

    • Author(s)
      Yuka Takagi, Yuta Ochiai, and Hajime Nagata
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 60 Issue: SF Pages: SFFD02-SFFD02

    • DOI

      10.35848/1347-4065/ac1c40

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Quenching effects on electrical properties of Cu-doped (Bi1/2Na1/2)TiO3-based solid solution ceramics2020

    • Author(s)
      S. Harada, Y. Takagi, H. Nagata, T. Takenaka
    • Journal Title

      Journal of Materials Research

      Volume: 36 Issue: 5 Pages: 0-0

    • DOI

      10.1557/s43578-020-00048-7

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] The quenching effects for depolarization temperature of (Bi0.5Na0.5)TiO3ceramics with Mn dopants2020

    • Author(s)
      K. Eguchi, Y. Takagi, H. Nagata, T. Takenaka
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SP Pages: SPPD03-SPPD03

    • DOI

      10.35848/1347-4065/aba9b5

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Correlation between depolarization temperature and lattice distortion in quenched (Bi1/2Na1/2)TiO3-based ceramics2020

    • Author(s)
      H. Nagata, Y. Takagi, T. Takenaka
    • Journal Title

      Applied Physics Express

      Volume: 13 Issue: 6 Pages: 061002-061002

    • DOI

      10.35848/1882-0786/ab8c1d

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effects of quenching on bending strength and piezoelectric properties of (Bi0.5Na0.5)TiO3 ceramics2020

    • Author(s)
      Y. Takagi, H. Nagata, T. Takenaka
    • Journal Title

      Journal of Asian Ceramic Societies,

      Volume: 8 Issue: 2 Pages: 277-283

    • DOI

      10.1080/21870764.2020.1732020

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Presentation] 急冷した (Bi0.5Na0.5)TiO3系セラミックスの酸素拡散とドメイン構造観察2023

    • Author(s)
      髙木 優香 , 落合 勇太 , 永田 肇
    • Organizer
      圧電材料・デバイスシンポジウム2023
    • Related Report
      2022 Annual Research Report
  • [Presentation] 落合 勇太, 高木 優香, 永田 肇2022

    • Author(s)
      (Bi0.5,Na0.5)TiO3セラミックスの構造相転移に及ぼす急冷効果と分極処理効果
    • Organizer
      日本セラミックス協会 第61回セラミックス基礎科学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] ZnOを複合化した(Bi0.5Na0.5)TiO3セラミックスの脱分極温度に及ぼす分極固定効果と急冷効果2022

    • Author(s)
      岡田海人、高木優香、永田 肇
    • Organizer
      日本セラミックス協会 第42回電子材料研究討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Hardening and Softening Behavior on High-power Piezoelectric Properties of Quenched (Bi0.5Na0.5)TiO3-based Solid Solution Ceramics2022

    • Author(s)
      Takeru Tayama, Yuka Takagi, and Hajime Nagata
    • Organizer
      15th International Symposium on Ferroic Domains & Micro- to Nano-scopic Structures (ISFD-15)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of (Bi0.5Na0.5)TiO3-based Lead-free Piezoelectric Ceramics by Quenching Treatment for Ultrasonic Applications2022

    • Author(s)
      Hajime Nagata, and Yuka Takagi
    • Organizer
      2022 US-Japan Seminar on Dielectric and Piezoelectric Ceramics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 超音波デバイス応用に向けた(Bi0.5Na0.5)TiO3系非鉛系圧電セラミックスの開発研究2022

    • Author(s)
      永田 肇
    • Organizer
      日本セラミックス協会 2022年 年会
    • Related Report
      2021 Research-status Report
    • Invited
  • [Presentation] Piezoelectric Properties and Depolarization Temperature on Quenched (Bi1/2Na1/2)TiO3-Based Solid Solution Ceramics2021

    • Author(s)
      Hajime Nagata, Yuka Takagi, Tadashi Takenaka
    • Organizer
      International Symposium on Applications of Ferroelectrics (ISAF) 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] (Bi1/2Na1/2)TiO3系固溶体圧電セラミックスの脱分極温度と経時変化2021

    • Author(s)
      栗原慧聖、髙木優香、永田肇
    • Organizer
      日本セラミックス協会 第41回電子材料研究討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] Quenching Effects for Depolarization Temperature and Phase Transition Behavior on (Bi0.5Na0.5)TiO3-based Ceramics2021

    • Author(s)
      Yuka Takagi, Hajime Nagata
    • Organizer
      The Joint International Conference on Applied Physics and Materials Applications & Applied Magnetism and Ferroelectrics (ICAPMA-JMAG-2021)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] (Bi0.5Na0.5)TiO3セラミックスにおける誘電特性と相転移挙動の温度依存性に及ぼす添加剤及び急冷の効果2021

    • Author(s)
      川越 拓海、高木 優香、永田 肇
    • Organizer
      第69回応用物理学会 春季学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] Quenching Effects for Electrical and Mechanical Properties on (Bi1/2Na1/2)TiO3 Ceramics2021

    • Author(s)
      H. Nagata, Y. Takagi, T. Takenaka
    • Organizer
      Electronic Materials and Applications 2021
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 急冷した(Bi0.5Na0.5)TiO3系セラミックスにおける 脱分極温度と添加物効果2020

    • Author(s)
      高木 優香,江口 浩太郎, 永田 肇, 竹中 正
    • Organizer
      第37回強誘電体応用会議
    • Related Report
      2020 Research-status Report
  • [Presentation] Control of piezoelectric properties and phase transition temperature for realization of lead-free ultrasonic devices by using (Bi1/2Na1/2)TiO3-based ceramics2020

    • Author(s)
      Hajime NAGATA
    • Organizer
      The 5th International Conference on Smart Materials and Nonotachnology
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] アクセプタおよびドナーを添加した(Bi0.5Na0.5)TiO3系セラミックスにおける 脱分極温度に対する急冷の効果2020

    • Author(s)
      髙木 優香, 江口 浩太郎, 永田 肇, 坂口 勲, 竹中 正
    • Organizer
      日本セラミックス協会電子材料部会
    • Related Report
      2020 Research-status Report

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Published: 2020-04-28   Modified: 2024-01-30  

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