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Heterojunction formation of conductive diamond and GaN, Ga2O3 for vertical device applications

Research Project

Project/Area Number 20K04581
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 21050:Electric and electronic materials-related
Research InstitutionOsaka Metropolitan University (2022)
Osaka City University (2020-2021)

Principal Investigator

Liang Jianbo  大阪公立大学, 大学院工学研究科, 准教授 (80757013)

Co-Investigator(Kenkyū-buntansha) 重川 直輝  大阪公立大学, 大学院工学研究科, 教授 (60583698)
Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2021: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2020: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsダイヤモンド / GaN / 放熱問題 / Ga2O3 / 直接接合 / 高耐熱性 / ヘテロ接合 / GaN/ダイヤモンド直接接合 / 高温耐熱性 / 接合界面構造 / ダイヤモンドの再結晶 / 中間層 / Si/ダイヤモンドヘテロ接合 / 電流-電圧特性 / ヘテロ構造 / 結合状態 / 界面構造 / 耐熱性 / 直接接合界面 / 導電性ダイヤモンド
Outline of Research at the Start

ダイヤモンドの有する非常に高い絶縁破壊電界と最高熱伝導率という材料的メリットを活かした次世代パワーデバイスの実現を目指す。導電性ダイヤモンドと窒化ガリウム(GaN)、酸化ガリウム(Ga2O3)基板との直接接合技術を開発する。導電性を有するn型ダイヤモンドと大口径ダイヤモンド基板の欠如という2つの問題点を解決するための技術開発を行う。本提案課題においては、ダイヤモンド/GaN、ダイヤモンド/Ga2O3ヘテロ接合を試作し、そのダイオード特性を実証し、熱処理条件による界面のナノ構造と電気的特性に及ぼす影響を調査する。ヘテロ接合の電流輸送機構とバンド構造を解明し、電気特性向上のための課題を明らかにする。

Outline of Final Research Achievements

GaN and diamond direct bonding were successfully fabricated at room temperature and the bonding interface demonstrated a high thermal stability of 1000°C. The intermediate layer thickness decreased with increasing annealing temperature due to the direct conversion of amorphous carbon into diamond. After annealing at 1000 °C, the thickness of the intermediate layer was decreased to 1.5 nm, where lattice fringes were observed. These results demonstrate that the GaN/diamond heterointerface has high mechanical stability and can withstand the harsh device fabrication process. Room-temperature bonding of diamond and Ga2O3 was achieved, and the interface structure was investigated. p+-Si/p-diamond and n+-Si/p-diamond heterojunction diodes were successfully fabricated by direct bonding Si and diamond and their current-voltage and current-voltage-temperature characteristics were investigated. The improvement of the ideality factor and the reduction of the leakage current was obtained.

Academic Significance and Societal Importance of the Research Achievements

GaN/ダイヤモンド接合界面がGaNデバイス作製プロセスに必要な耐熱温度を有することを示し、高放熱性能を有するGaNデバイスの実現を可能にした。ダイヤモンドとGa2O3の常温接合の達成により、Ga2O3の低熱伝導率に起因する放熱問題の解決に対する可能性が示された。p+-Si /p-ダイヤモンドとn+-Si/p-ダイヤモンドヘテロ接合ダイオードが良好な電流-電圧特性を示し、直接接合による高機能性デバイスの実現性が示された。

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (13 results)

All 2023 2022 2021

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (7 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results) Book (1 results)

  • [Journal Article] Electrical properties of Si/diamond heterojunction diodes fabricated by using surface activated bonding2022

    • Author(s)
      Uehigashi Yota、Ohmagari Shinya、Umezawa Hitoshi、Yamada Hideaki、Liang Jianbo、Shigekawa Naoteru
    • Journal Title

      Diamond and Related Materials

      Volume: 130 Pages: 109425-109425

    • DOI

      10.1016/j.diamond.2022.109425

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of thermal stabilities of p<sup>+</sup>-Si/p-diamond heterojunction and Al/p-diamond Schottky barrier diodes2022

    • Author(s)
      Uehigashi Yota、Ohmagari Shinya、Umezawa Hitoshi、Yamada Hideaki、Liang Jianbo、Shigekawa Naoteru
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 61 Issue: SF Pages: SF1009-SF1009

    • DOI

      10.35848/1347-4065/ac6480

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ダイヤモンドと異種材料の直接接合による超耐熱マテリアルの開発とその応用について2022

    • Author(s)
      梁剣波、重川直輝
    • Journal Title

      月刊マテリアルステージ

      Volume: 3 Pages: 67-70

    • Related Report
      2021 Research-status Report
  • [Journal Article] Fabrication of GaN/Diamond Heterointerface and Interfacial Chemical Bonding State for Highly Efficient Device Design2021

    • Author(s)
      Jianbo Liang, Ayaka Kobayashi, Yasuo Shimizu, Yutaka Ohno, Seong-Woo Kim, Koji Koyama, Makoto Kasu, Yasuyoshi Nagai, and Naoteru Shigekawa
    • Journal Title

      Adavanced Materials

      Volume: 33 Issue: 43 Pages: 2104564

    • DOI

      10.1002/adma.202104564

    • URL

      https://ocu-omu.repo.nii.ac.jp/records/2019594

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of p+-Si/p-diamond heterojunction diodes and effects of thermal annealing on their electrical properties2021

    • Author(s)
      Yota Uehigashi, Shinya Ohmagari, Hitoshi Umezawa, Hideaki Yamada, Jianbo Liang, and Naoteru Shigekawa
    • Journal Title

      Diamond and Related Materials

      Volume: 120 Pages: 108665-108665

    • DOI

      10.1016/j.diamond.2021.108665

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Presentation] GaN HEMT on-diamond構造の作製及び特性評価2023

    • Author(s)
      早川 譲稀 , 大野 裕 , 永井 康介 , 重川 直輝 , 梁 剣波
    • Organizer
      第70回応用物理学会春季学術講演会
    • Related Report
      2022 Annual Research Report
  • [Presentation] High Performance GaN-on-Diamond Devices Fabrication using Diamond Wafer Bonding Technology2023

    • Author(s)
      Jianbo Liang, Yutaka Ohno, Naoteru Shigekawa
    • Organizer
      Hasselt Diamond Workshop 2023
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] n+-Si/p-ダイヤモンドヘテロ接合ダイオードの耐熱性評価2023

    • Author(s)
      上東 洋太、大曲 新矢、梅沢 仁、山田 英明、梁 剣波、重川 直輝
    • Organizer
      第83回応用物理学会秋季学術講演会
    • Related Report
      2022 Annual Research Report
  • [Presentation] GaN/ダイヤモンド接合界面の特性評価2022

    • Author(s)
      梁 剣波、清水 康雄、大野 裕、永井 康介、重川 直輝
    • Organizer
      第69回応用物理学会春季学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] n+-Si/p-ダイヤモンドヘテロ接合ダイオードの作製と電気特性評価2022

    • Author(s)
      上東 洋太、大曲 新矢、梅沢 仁、山田 英明、梁 剣波、重川 直輝
    • Organizer
      第69回応用物理学会春季学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] Fabrication and Characterization of GaN/Diamond Boding Interface2021

    • Author(s)
      Ayaka Kobayashi, Yasuo Shimizu, Yutaka Ohno, Seong-Woo Kim, Koji Koyama, Makoto Kasu, Yasuyoshi Nagai, Naoteru Shigekawa, and Jianbo Liang
    • Organizer
      2021 IEEE International Workshop on Low Temperature Bonding for 3D Integration (LTB-3D)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] High Temperature Stability of p+-Si/p-Diamond Heterojunction diodes2021

    • Author(s)
      Yota Uehigashi, Shinya Ohmagari, Hitoshi Umezawa, Hideaki Yamada, Jianbo Liang, and Naoteru Shigekawa
    • Organizer
      2021 IEEE International Workshop on Low Temperature Bonding for 3D Integration (LTB-3D)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Book] ラマン分光スペクトルデータ解析事例集2022

    • Author(s)
      梁 剣波(担当:第7章3節)
    • Total Pages
      405
    • Publisher
      技術情報協会
    • Related Report
      2021 Research-status Report

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Published: 2020-04-28   Modified: 2024-01-30  

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