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Development of novel high strength-ductility steel sheet using nitrogen

Research Project

Project/Area Number 20K05148
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 26050:Material processing and microstructure control-related
Research InstitutionTohoku University

Principal Investigator

Sato Mitsutaka  東北大学, 金属材料研究所, 助教 (10547706)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2021: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords窒素鋼 / 相変態 / エネルギー散逸 / 機械特性 / 高強度-高延性鋼 / 複相組織 / ベイナイト変態 / 高強度鋼 / フェライト変態 / 相界面析出 / 高強度稿
Outline of Research at the Start

CrおよびMnを含む低合金鋼に対し、浸窒処理により窒素を均一に固溶させ、その後の変態温度および変態時間の変化に伴う材料の硬さ、微細組織、サイズ、分布、相分率、析出物の同定およびそれらの定量について系統的に調査し、フェライト・ベイナイト変態に及ぼす侵入型原子および置換型原子の影響を明らかにする。また、フェライト変態時の相界面析出およびベイナイト変態を組み合わせることにより形態の異なる2つのフェライト組織を有する窒素を用いた新しい高強度‐高延性な鉄鋼材料の開発を目指す。

Outline of Final Research Achievements

The ferrite and bainite transformation of Fe-0.3N-xMn (x=0, 1, 2) alloys was investigated in terms of morphology, crystallography, growth rate and elemental partitioning, and the effects of Mn and Cr additions on those transformation behavior and mechanical properties were investigated. With decreasing transformation temperature, the microstructures of the ferrite changed to AF, WF and BF, and the growth of ferrite was retarded with increasing Mn addition.
The mechanical properties of bainitic transformed Fe-0.3N and 1Mn alloy showed an increase in uniform elongation and work hardening due to the increase in the volume fraction of retained g, confirming the occurrence of the TRIP effect. The strength-ductility balance of the Fe-0.3N and 1Mn alloy was comparable, while the 2Mn1Cr alloy had a higher yield stress due to a larger martensite volume fraction, but no increase in elongation.

Academic Significance and Societal Importance of the Research Achievements

本研究では,正変態におけるα/γ界面での元素分配を詳細に測定し,窒素鋼の正変態挙動をα/γ界面の平衡組成からのずれ、すなわち、エネルギー散逸という観点から評価した.Fe-0.3N材およびMn添加材いずれいおいても,変態時にエネルギー散逸生じており,それらを物理的作用および化学的作用にて定量的に説明することが可能であることを明らかにした.また,炭素鋼との比較では,MnとNおよびCとの間の引力的相互作用から説明でき,i-s相互作用とNおよびC自身の偏析エネルギーの観点から理解することが可能であることを明らかにし,従来の炭素鋼の知見を基にして窒素鋼の相変態も理解することが可能であることを示した.

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (13 results)

All 2023 2022 2021 2020

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 5 results) Presentation (7 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Sublattice alloy design of high-strength steels: Application of clustering and nanoscale precipitation of interstitial and substitutional solutes2023

    • Author(s)
      Tadashi Furuhara, Yongjie Zhang, Mitsutaka Sato, Goro Miyamoto, Masanori Enoki, Hiroshi Ohtani, Tokuteru Uesugi, Hiroshi Numakura
    • Journal Title

      Scripta Materialia

      Volume: 223 Pages: 115063-115063

    • DOI

      10.1016/j.scriptamat.2022.115063

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Strengthening of Low Carbon Steel by Nano-sized Vanadium Carbide in Ferrite and Tempered Martensite2022

    • Author(s)
      Yongjie Zhang, Mitsutaka Sato, Goro Miyamoto, Tadashi Furuhara
    • Journal Title

      ISIJ International

      Volume: 62 Issue: 10 Pages: 2016-2024

    • DOI

      10.2355/isijinternational.ISIJINT-2022-156

    • ISSN
      0915-1559, 1347-5460
    • Year and Date
      2022-10-15
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Comparison of Solute Nanoclusters in Fe-Cr-N Tempered Martensite Observed by Different Atom Probe Instruments2022

    • Author(s)
      Zhang Yong-Jie、Young Shao-Wen、Rice Katherine P、Sato Mitsutaka、Miyamoto Goro、Furuhara Tadashi、Ohkubo Tadakatsu、Hono Kazuhiro
    • Journal Title

      Microscopy and Microanalysis

      Volume: 29 Issue: 1 Pages: 86-93

    • DOI

      10.1093/micmic/ozac004

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ferrite Transformation from Fe-0.3N Austenite2021

    • Author(s)
      Sato Mitsutaka、Murata Takamasa、Shimaya Shota、Miyamoto Goro、Furuhara Tadashi
    • Journal Title

      ISIJ International

      Volume: 61 Issue: 1 Pages: 343-349

    • DOI

      10.2355/isijinternational.ISIJINT-2020-166

    • NAID

      130007969958

    • ISSN
      0915-1559, 1347-5460
    • Year and Date
      2021-01-15
    • Related Report
      2021 Research-status Report 2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fe-N合金のフェライト・ベイナイト変態における現状の理解2021

    • Author(s)
      佐藤 充孝、宮本 吾郎、古原 忠
    • Journal Title

      熱処理

      Volume: 61 Pages: 82-86

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of Alloying Elements on the High-Temperature Tempering of Fe-0.3N Martensite2021

    • Author(s)
      Young Shao-Wen、Sato Mitsutaka、Yamamitsu Kazuhiro、Shimada Yusuke、Zhang Yongjie、Miyamoto Goro、Furuhara Tadashi
    • Journal Title

      Acta Materialia

      Volume: 206 Pages: 116612-116612

    • DOI

      10.1016/j.actamat.2020.116612

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Fe-0.3N-xMn (x = 0 ~ 3 mass%) 合金マルテンサイトの二相域焼鈍による逆変態挙動と機械特性2022

    • Author(s)
      多田陸人、佐藤充孝、宮本吾郎、古原忠
    • Organizer
      日本鉄鋼協会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Fe-0.3N オーステナイトのフェライト変態に及ぼす Mn 添加の影響とエネルギー散逸2022

    • Author(s)
      粂田晴陽、佐藤充孝、宮本吾郎、古原忠
    • Organizer
      熱処理技術協会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Fe-0.3N-xMn オーステナイトのフェライト変態におけるエネルギー散逸の定量評価2022

    • Author(s)
      粂田晴陽、佐藤充孝、宮本吾郎、古原忠
    • Organizer
      日本鉄鋼協会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Effect of Alloying Element on Phase Transformation in Fe-0.3N Alloy2021

    • Author(s)
      Mitsutaka Sato, Goro Miyamoto, Tadashi Furuhara
    • Organizer
      ASIA STEEL 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] 窒素含有TRIP鋼の引張り特性におよぼす残留オーステナイトの影響2020

    • Author(s)
      佐藤充孝 菊地一茂 宮本吾郎 古原忠
    • Organizer
      日本鉄鋼協会 第180回秋季講演大会
    • Related Report
      2020 Research-status Report
  • [Presentation] Fe-0.3Nオーステナイトのフェライト変態挙動と合金元素添加の影響2020

    • Author(s)
      佐藤充孝 宮本吾郎 古原忠
    • Organizer
      日本熱処理技術協会 第90回秋季講演大会
    • Related Report
      2020 Research-status Report
  • [Presentation] Fe-Mn-N 合金のベイナイト変態挙動と引張特性におよぼすCr 添加の影響2020

    • Author(s)
      佐藤充孝 原一貴 宮本吾郎 古原忠
    • Organizer
      日本鉄鋼協会 第181回春季講演大会
    • Related Report
      2020 Research-status Report

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Published: 2020-04-28   Modified: 2024-01-30  

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