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Creating Hot-Electron Photocatalyst Architectures with Optimal Mass Transport Properties using Plasmonic Mesoporous Metal Nanoparticles

Research Project

Project/Area Number 20K05453
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 32020:Functional solid state chemistry-related
Research InstitutionNational Institute for Materials Science

Principal Investigator

HENZIE JOEL  国立研究開発法人物質・材料研究機構, ナノアーキテクトニクス材料研究センター, 主幹研究員 (80644517)

Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2021: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsナノマテリアルの合成 / 電子トモグラフィ / 光学シミュレーション / プラズモニクス / 表面増強ラマン分光法 (SERS) / 光触媒 / マイクロプラスチック / 機械学習 / Plasmon / Microplastics / メソポーラス金属 / プラズモン励起光触媒反応 / 表面増強ラマン分光法(SERS) / 表面増強ラマン散乱(SERS) / オプトメカニクス / ホットエレクトロン / 超高速分光 / トモグラフィー / 電極触媒作用 / 金属合金 / Photocatalysis / Plasmonics / Hot carrier science / Nanoparticle Synthesis / Mesoporous Materials
Outline of Research at the Start

The discovery of inexpensive catalysts is critical for improving the efficiency of renewable energy technologies. My team will examine how light can enhance the performance of metal electrocatalysts.

Outline of Final Research Achievements

We developed simple and inexpensive methods to create porous metal nanoparticles, films, and foams. To examine how these structures interact with light, we mapped the three-dimensional (3D) structures of porous gold nanoparticles with electron tomography. Then we used 3D models and computer simulations to formulate a simple theoretical framework to explain the optical properties of porous metals. These results showed that porous metals can behave as photocatalysts to facilitate the photodegradation of organic molecules. Additionally, we developed a technique to coat macroporous metal foams with mesoporous silver, and used these hybrid foams to collect and identify microplastics which are a prevalent pollutant in marine environments.

Academic Significance and Societal Importance of the Research Achievements

メソポーラス金ナノ粒子の研究は、新合成法の開発や電子トモグラフィによる3D構造の詳細なマッピング、またその構造を基にした光学特性のモデリングや理論構造の確立など、多角的に進展しています。これらをもとにナノテクノロジーと材料科学の研究はさらに発展するでしょう。また光触媒の応用で有機汚染物質の分解が可能となり、水質浄化に貢献できます。マクロポーラス-メソポーラス金属フォームの開発は、海洋環境のマイクロプラスチック収集と識別を可能にし、生態系保護に役立ちます。この成果は予想外であり、時間が経つにつれ元案から発展しました。持続可能性と社会的課題の解決に向けた重要な一歩です。

Report

(5 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (44 results)

All 2024 2023 2022 2021 2020 Other

All Int'l Joint Research (17 results) Journal Article (21 results) (of which Int'l Joint Research: 20 results,  Peer Reviewed: 21 results,  Open Access: 3 results) Presentation (5 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results) Book (1 results)

  • [Int'l Joint Research] Kaunas University of Technology(リトアニア)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] Adam Mickiewicz University(ポーランド)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] Shanghai Normal University/Xi'an Jiaotong University(中国)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] Institut Teknologi Bandung(インドネシア)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] Institut Teknologi Bandung/Institut Teknologi Sains Bandung(インドネシア)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] The University of Queensland(オーストラリア)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] Tomsk Polytechnic University(ロシア連邦)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] University of Chemistry and Technology(チェコ)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] Aix-Marseille University(フランス)

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research]

    • Related Report
      2022 Research-status Report
  • [Int'l Joint Research] The University of Queensland(オーストラリア)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Kyung Hee University/Yonsei University/Korea Electronics Institute (KETI)(韓国)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Xi'an Jiaotong University/Northwestern Polytechnical University(中国)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Institut Teknologi Bandung(インドネシア)

    • Related Report
      2021 Research-status Report
  • [Int'l Joint Research] Yonsei University/Kyung Hee University/Korea Institute of Industrial Tech(韓国)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] The University of Queensland(オーストラリア)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] Kaunas University of Technology(リトアニア)

    • Related Report
      2020 Research-status Report
  • [Journal Article] Size and crystallinity effect on the ultrafast optical response of chemically synthesized silver nanoparticles2024

    • Author(s)
      Khinevich Nadzeya、Peckus Domantas、Tamuleviciene Asta、Klimaite Gerda、Henzie Joel、Tamulevicius Tomas、Tamulevicius Sigitas
    • Journal Title

      Journal of Materiomics

      Volume: 10 Issue: 3 Pages: 594-600

    • DOI

      10.1016/j.jmat.2023.08.009

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Polarized-SERS of non-isotropic molecules on thermally-induced corrugated plasmonic surface supporting a NIR-SPP mode2024

    • Author(s)
      Mathew Ephraim、Jenczyk Jacek、Milosz Zygmunt、Henzie Joel、latsunskyi Igor、Florczak Patryk、Andrzejewska. Weronika、Lewandowski Mikolaj、Wiesner Maciej
    • Journal Title

      Applied Surface Science

      Volume: 659 Pages: 159821-159821

    • DOI

      10.1016/j.apsusc.2024.159821

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Regulating Functional Groups Enhances the Performance of Flexible Microporous MXene/Bacterial Cellulose Electrodes in Supercapacitors2024

    • Author(s)
      Luo Yijia、Que Wenxiu、Tang Yi、Kang Yunqing、Bin Xiaoqing、Wu Zhenwei、Yuliarto Brian、Gao Bowen、Henzie Joel、Yamauchi Yusuke
    • Journal Title

      ACS Nano

      Volume: 18 Issue: 18 Pages: 11675-11687

    • DOI

      10.1021/acsnano.3c11547

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Designing reliable and accurate isotope-tracer experiments for CO2 photoreduction2023

    • Author(s)
      Wang Shengyao、Jiang Bo、Henzie Joel、Xu Feiyan、Liu Chengyuan、Meng Xianguang、Zou Sirong、Song Hui、Pan Yang、Li Hexing、Yu Jiaguo、Chen Hao、Ye Jinhua
    • Journal Title

      Nature Communications

      Volume: 14 Issue: 1 Pages: 2534-2534

    • DOI

      10.1038/s41467-023-38052-0

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Plasmon-Triggered Ultrafast Operation of Color Centers in Hexagonal Boron Nitride Layers2023

    • Author(s)
      Karanikolas Vasilios、Iwasaki Takuya、Henzie Joel、Ikeda Naoki、Yamauchi Yusuke、Wakayama Yutaka、Kuroda Takashi、Watanabe Kenji、Taniguchi Takashi
    • Journal Title

      ACS Omega

      Volume: 8 Issue: 16 Pages: 14641-14647

    • DOI

      10.1021/acsomega.3c00512

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Uncovering the Role of Chemical and Electronic Structures in Plasmonic Catalysis: The Case of Homolysis of Alkoxyamines2023

    • Author(s)
      Votkina Darya、Petunin Pavel、Miliutina Elena、Trelin Andrii、Lyutakov Oleksiy、Svorcik Vaclav、Audran G?rard、Havot Jeffrey、Valiev Rashid、Valiulina Lenara I.、Joly Jean-Patrick、Yamauchi Yusuke、Mokkath Junais Habeeb、Henzie Joel、Guselnikova Olga、Marque Sylvain R. A.、Postnikov Pavel
    • Journal Title

      ACS Catalysis

      Volume: 13 Issue: 5 Pages: 2822-2833

    • DOI

      10.1021/acscatal.2c04685

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The revelation of glucose adsorption mechanisms on hierarchical metal?organic frameworks using a surface plasmon resonance sensor2023

    • Author(s)
      Gumilar Gilang、Chowdhury Silvia、Shukri Ganes、Patah Aep、Nugraha Nugraha、Henzie Joel、Anshori Isa、Kaneti Yusuf Valentino、Yuliarto Brian
    • Journal Title

      Journal of Materials Chemistry B

      Volume: Advance Article Issue: 20 Pages: 4428-4444

    • DOI

      10.1039/d3tb00138e

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Symmetry-Breaking Plasmonic Mesoporous Gold Nanoparticles with Large Pores2022

    • Author(s)
      Nugraha Asep Sugih、Guselnikova Olga、Henzie Joel、Na Jongbeom、Hossain Md Shahriar A.、Dag ?mer、Rowan Alan E.、Yamauchi Yusuke
    • Journal Title

      Chemistry of Materials

      Volume: 34 Issue: 16 Pages: 7256-7270

    • DOI

      10.1021/acs.chemmater.2c01125

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Tailored MXene Nanoarchitectonics: MXene with Mesoporous Nitrogen-Doped Carbon Confined Ultrafine Molybdenum Carbide Nanodots for Efficient Electrocatalytic Hydrogen Evolution2022

    • Author(s)
      Tang Yi、Yang Chenhui、Xie Yangyang、Kang Yunqing、Que Wenxiu、Henzie Joel、Yamauchi Yusuke
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 11 Issue: 1 Pages: 168-176

    • DOI

      10.1021/acssuschemeng.2c05106

    • Related Report
      2022 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Performance enhancement strategies for surface plasmon resonance sensors in direct glucose detection using pristine and modified UiO-66: effects of morphology, immobilization technique, and signal amplification2022

    • Author(s)
      Gumilar Gilang、Henzie Joel、Yuliarto Brian、Patah Aep、Nugraha Nugraha、Iqbal Muhammad、Amin Mohammed A.、Hossain Md. Shariar A.、Yamauchi Yusuke、Kaneti Yusuf Valentino
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 10 Issue: 12 Pages: 6662-6678

    • DOI

      10.1039/d1ta08741j

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] MXene Nanoarchitectonics: Defect‐Engineered 2D MXenes towards Enhanced Electrochemical Water Splitting2022

    • Author(s)
      Tang Yi、Yang Chenhui、Xu Xingtao、Kang Yunqing、Henzie Joel、Que Wenxiu、Yamauchi Yusuke
    • Journal Title

      Advanced Energy Materials

      Volume: 12 Issue: 12 Pages: 2103867-2103867

    • DOI

      10.1002/aenm.202103867

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Mesoporous Au films assembled on flexible cellulose nanopaper as high-performance SERS substrates2021

    • Author(s)
      Kim Dabum、Kim Jeonghun、Henzie Joel、Ko Youngsang、Lim Hyunsoo、Kwon Goomin、Na Jongbeom、Kim Hyun-Jong、Yamauchi Yusuke、You Jungmok
    • Journal Title

      Chemical Engineering Journal

      Volume: 419 Pages: 129445-129445

    • DOI

      10.1016/j.cej.2021.129445

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Amorphous Alloy Architectures in Pore Walls: Mesoporous Amorphous NiCoB Alloy Spheres with Controlled Compositions via a Chemical Reduction2020

    • Author(s)
      Kang Yunqing、Jiang Bo、Yang Juanjuan、Wan Zhe、Na Jongbeom、Li Qian、Li Hexing、Henzie Joel、Sakka Yoshio、Yamauchi Yusuke、Asahi Toru
    • Journal Title

      ACS Nano

      Volume: 14 Issue: 12 Pages: 17224-17232

    • DOI

      10.1021/acsnano.0c07178

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Ag Nanocube Optomechanical Modes on Plasmonic Surface Lattice Resonances2020

    • Author(s)
      Juodenas Mindaugas、Peckus Domantas、Tamulevicius Tomas、Yamauchi Yusuke、Tamulevicius Sigitas、Henzie Joel
    • Journal Title

      ACS Photonics

      Volume: 7 Issue: 11 Pages: 3130-3140

    • DOI

      10.1021/acsphotonics.0c01187

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Plasmonic-induced self-assembly of WGM cavities via laser cavitation2020

    • Author(s)
      Sato Rodrigo、Henzie Joel、Ishii Satoshi、Takazawa Ken、Takeda Yoshihiko
    • Journal Title

      Optics Express

      Volume: 28 Issue: 21 Pages: 31923-31923

    • DOI

      10.1364/oe.401662

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A universal approach for the synthesis of mesoporous gold, palladium and platinum films for applications in electrocatalysis2020

    • Author(s)
      Lim Hyunsoo、Kani Kenya、Henzie Joel、Nagaura Tomota、Nugraha Asep Sugih、Iqbal Muhammad、Ok Yong Sik、Hossain Md. Shahriar A.、Bando Yoshio、Wu Kevin C. W.、Kim Hyun-Jong、Rowan Alan E.、Na Jongbeom、Yamauchi Yusuke
    • Journal Title

      Nature Protocols

      Volume: 15 Issue: 9 Pages: 2980-3008

    • DOI

      10.1038/s41596-020-0359-8

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A mesopore-stimulated electromagnetic near-field: electrochemical synthesis of mesoporous copper films by micelle self-assembly2020

    • Author(s)
      Lim Hyunsoo、Kim Dabum、Kim Yena、Nagaura Tomota、You Jungmok、Kim Jeonghun、Kim Hyun-Jong、Na Jongbeom、Henzie Joel、Yamauchi Yusuke
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 8 Issue: 40 Pages: 21016-21025

    • DOI

      10.1039/d0ta06228f

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] General synthesis of hierarchical sheet/plate-like M-BDC (M = Cu, Mn, Ni, and Zr) metal-organic frameworks for electrochemical non-enzymatic glucose sensing2020

    • Author(s)
      Gumilar Gilang、Kaneti Yusuf Valentino、Henzie Joel、Chatterjee Sauvik、Na Jongbeom、Yuliarto Brian、Nugraha Nugraha、Patah Aep、Bhaumik Asim、Yamauchi Yusuke
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 14 Pages: 3644-3655

    • DOI

      10.1039/c9sc05636j

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrafast relaxation dynamics of aluminum nanoparticles in solution2020

    • Author(s)
      Peckus Domantas、Henzie Joel、Tamulevicius Tomas、Andrulevicius Mindaugas、Lazauskas Algirdas、Rajackaite Erika、Meskinis Sarunas、Tamulevicius Sigitas
    • Journal Title

      Physica E: Low-dimensional Systems and Nanostructures

      Volume: 117 Pages: 113795-113795

    • DOI

      10.1016/j.physe.2019.113795

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An asymmetric aluminum active quantum plasmonic device2020

    • Author(s)
      Mokkath Junais Habeeb、Henzie Joel
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 22 Issue: 3 Pages: 1416-1421

    • DOI

      10.1039/c9cp04926f

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A mesoporous non-precious metal boride system: synthesis of mesoporous cobalt boride by strictly controlled chemical reduction2020

    • Author(s)
      Jiang Bo、Song Hui、Kang Yunqing、Wang Shengyao、Wang Qi、Zhou Xin、Kani Kenya、Guo Yanna、Ye Jinhua、Li Hexing、Sakka Yoshio、Henzie Joel、Yusuke Yamauchi
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 3 Pages: 791-796

    • DOI

      10.1039/c9sc04498a

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Rational Design of Single-phase Multi-metal Mesoporous Nanostructures for a Sustainable Future2023

    • Author(s)
      Ravi Nandan, Joel Henzie, Hiroyuki Nara, Yusuke Yamauchi
    • Organizer
      Materials Oceania 2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Hierarchical porous metals2023

    • Author(s)
      Joel Henzie, Olga Guselnikova
    • Organizer
      Materials Oceania 2023
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] Creating High Anisotropy Hierarchical Metals2022

    • Author(s)
      Joel Henzie
    • Organizer
      Kaunas Technological University (Lithuania)
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Controlling Materials-Space in Inorganic Materials2021

    • Author(s)
      Joel Henzie
    • Organizer
      Advanced Materials and Technologies 2021 (https:/advancedmaterials.ktu.edu)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Making Catalysts More Efficient using Nanoarchitectonics2021

    • Author(s)
      Joel Henzie
    • Organizer
      MANA International Symposium
    • Related Report
      2020 Research-status Report
    • Invited
  • [Book] System-Materials Nanoarchitectonics (ISBN: 978-4-431-56912-1)2022

    • Author(s)
      Yusuke Ide, Joel Henzie, Kenya Kani,Yusuke Yamauchi
    • Total Pages
      274
    • Publisher
      Springer Nature
    • Related Report
      2022 Research-status Report

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Published: 2020-04-28   Modified: 2025-01-30  

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