| Project/Area Number |
20K15121
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| Research Category |
Grant-in-Aid for Early-Career Scientists
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| Allocation Type | Multi-year Fund |
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| Review Section |
Basic Section 28020:Nanostructural physics-related
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| Research Institution | Institute of Physical and Chemical Research |
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Principal Investigator |
李 臻 国立研究開発法人理化学研究所, 光量子工学研究センター, 基礎科学特別研究員 (20869359)
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| Project Period (FY) |
2020-04-01 – 2022-03-31
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| Project Status |
Discontinued (Fiscal Year 2021)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2021: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2020: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | carbon nanotubes / boron nitride nanotubes / heterostructure / excitons / photoluminescence / heterostructures |
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| Outline of Research at the Start |
Novel excitonic properties in the 1D coaxial heterostructures will be explored via optical means. Exciton energy modulation in the carbon nanotube core and interlayer excitons induced by BN coating will be studied. Field-effect transistors will be developed to realize tunable single-photon emission.
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| Outline of Annual Research Achievements |
Boron nitride coated single-walled carbon nanotubes were synthesized on location-tagged TEM grids by chemical vapor deposition. The number of boron nitride shells was controlled by adjusting the coating time. Due to the atomically thin nature of carbon nanotubes, boron nitride coating with different thickness yields different excitonic energy shifts observed by photoluminescence excitation spectroscopy. Both blueshift and redshift of the excitonic energy were observed, the redshift was considered to be caused by dielectric screening from the boron nitride shells and the blueshift was a result of the strain introduced by nonuniform coating. Nonetheless, more coating of boron nitride shells indeed gave rise to large excitonic energy shifts. Transmission electron microscopy was also performed to explore the relationship between the actual boron nitride shell number and the redshift of the excitonic energies. Identification of the carbon nanotubes that had been measured by photoluminescence excitation spectroscopy turned out to be difficult. A lower density of carbon nanotubes were necessary to ease the identification process. Chemical vapor deposition with lower density of catalysts and shorter coating time are in process.
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