Design and synthesis of responsive, elastic, porous single crystalline materials using mechanically interlocked molecules
Project/Area Number |
20K15251
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Research Category |
Grant-in-Aid for Early-Career Scientists
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Allocation Type | Multi-year Fund |
Review Section |
Basic Section 32020:Functional solid state chemistry-related
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Research Institution | National Institute for Materials Science |
Principal Investigator |
メン ウェンジン 国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 研究員 (30838470)
|
Project Period (FY) |
2020-04-01 – 2024-03-31
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Project Status |
Granted (Fiscal Year 2022)
|
Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2023: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2022: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2021: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2020: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
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Keywords | catenane / Catenane / Metal-organic framework / single crystal / mechanical bond |
Outline of Research at the Start |
Single crystals are typically rigid and fragile. Building on the applicant’s recent discovery, in this work, we would like to explore the possibility of rational design of elastic, responsive single crystalline materials by using metal-organic framework containing mechanically interlocked molecules.
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Outline of Annual Research Achievements |
A general route for the synthesis of asymmetric catenanes with multiple, different functional groups was established. There were many synthetic challenges involved in the synthesis. For example, the solubility of the key intermediates needed to be finely tuned, and the compatibility of various protecting groups required careful consideration. Now a variety of catenanes with asymmetric rings can be readily synthesized.
As for the formation of MOF, it was found that the functional groups in catenane ligand affect the formation of the crystal, as well as the morphology of the crystal. However, crystals which are good enough for further characterization have not been successfully obtained.
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Current Status of Research Progress |
Current Status of Research Progress
3: Progress in research has been slightly delayed.
Reason
The design and synthesis of suitable catenane ligands are the first major challenge of the project. Given the difficulty of the synthetic work, longer time may be required to understand the system.
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Strategy for Future Research Activity |
Catenane ligands with diverse functional groups will be synthesized in order to understand how the property of functional groups affect MOF formation. We aim to find the best combination of functional groups which can produce MOF crystals that are robust enough for further characterization.
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Report
(3 results)
Research Products
(1 results)