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Hierarchically Ordered Nanocomposites based on Block Copolymers and Nanodiamonds

Research Project

Project/Area Number 20K15347
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 35020:Polymer materials-related
Research InstitutionOkinawa Institute of Science and Technology Graduate University

Principal Investigator

SUTISNA Burhannudin  沖縄科学技術大学院大学, 力学と材料科学ユニット, ポストドクトラルスカラー (90866922)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Discontinued (Fiscal Year 2022)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2021: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2020: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
KeywordsNanodiamond suspension / Colloidal stability / Self-assembly / Nanocomposite / Nanodiamond / Organic solvent / Self-assembled channels / Block copolymer / Block copolymers / Nanodiamonds / Nanocomposites
Outline of Research at the Start

The use of nanodiamonds (NDs) as reinforcing fillers in polymer nanocomposites has been limited by challenges related to creating uniform dispersions. This research will solve this issue by exploiting enthalpic and entropic factors of co-assembly between block copolymers (BCPs)and NDs. It will involve ND surface functionalization and use BCPs with various configurations to obtain well-ordered BCP-ND nanocomposites via solvent-based techniques. This research will provide a foundation for the synthesis of hierarchically ordered nanocomposites, relevant for coating, tribology, and biotech.

Outline of Annual Research Achievements

A manuscript on the preparation of stable suspensions of nanodiamonds (NDs) in organic solvents has been written and is currently under revision by co-authors. The manuscript mainly discusses the mechanism of ND stabilization in the suspension. More characterizations on self-assembled membranes with ND channels were also performed, which focused on the mechanical properties of the nanocomposite films. The experiments revealed more understanding on the structure-property relationship of the films.

Report

(3 results)
  • 2022 Annual Research Report
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (3 results)

All 2021

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (2 results)

  • [Journal Article] Block copolymer-nanodiamond coassembly in solution: towards multifunctional hybrid materials2021

    • Author(s)
      B. Sutisna, S. D. Janssens, A. Giussani, D. Vazquez-Cortes, and E. Fried
    • Journal Title

      Nanoscale

      Volume: 13巻 Issue: 3 Pages: 1639-1651

    • DOI

      10.1039/d0nr07441a

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Self-assembled nanocomposites based on block copolymers and nanodiamonds2021

    • Author(s)
      Sutisna, Burhannudin
    • Organizer
      48th World Polymer Congress (IUPAC-MACRO2020+)
    • Related Report
      2021 Research-status Report
  • [Presentation] Nanodiamond and block copolymer co-assembly in solutions: towards hierarchically ordered nanocomposites for bio-applications2021

    • Author(s)
      Sutisna, Burhannudin
    • Organizer
      14th International Conference on New Diamond and Nano Carbons (NDNC 2020/2021)
    • Related Report
      2021 Research-status Report

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Published: 2020-04-28   Modified: 2023-12-25  

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