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Development of novel solid-state cooling technology that delivers innovation to global warming countermeasures

Research Project

Project/Area Number 20K20296
Project/Area Number (Other) 17H06239 (2017-2019)
Research Category

Grant-in-Aid for Challenging Research (Pioneering)

Allocation TypeMulti-year Fund (2020)
Single-year Grants (2017-2019)
Research Field Inorganic materials chemistry, Energy-related chemistry, and related fields
Research InstitutionKumamoto University (2020, 2022)
The University of Tokyo (2017-2019)

Principal Investigator

Noguchi Yuji  熊本大学, 大学院先端科学研究部(工), 教授 (60293255)

Project Period (FY) 2017-06-30 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥25,350,000 (Direct Cost: ¥19,500,000、Indirect Cost: ¥5,850,000)
Fiscal Year 2021: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2020: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2019: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2018: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2017: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywords強誘電体 / 電気熱量効果 / 分極 / 欠陥 / ドメイン / ドメイン壁 / 格子欠陥 / エントロピー / 反強誘電体 / 酸素空孔 / 第一原理計算 / 電子材料 / エンタルピー / セラミックス / 温度 / 自発分極 / 遷移金属 / 欠陥ダイポール / 球温暖化ガス排出削減 / 代替フロン
Outline of Research at the Start

2020年以降の温暖化対策に関する国際ルール「パリ協定」が発行された.産業革命前と比べた世界の気温上昇を2℃未満にし,1.5℃以内に向けて努力することが明記されている.この2℃目標の達成には,世界で300億tのCO2の削減が必要とされている.我々は,次世代の冷却機器に利用可能な固体冷却技術の研究を進める過程で,フェリ誘電体の電場誘起相転移型と強誘電体の自発的分極反転型の新規電気熱量効果を発見した.しかし,これらのメカニズムの解明は進んでいない.本研究では,電場誘起相転移型と自発的分極反転型の新規電気熱量効果による冷却メカニズムの解明を目的とする.

Outline of Final Research Achievements

The purpose of this research is to develop solid-state cooling technology that can be used for next-generation cooling equipment. We utilized the interaction between defect dipoles with Cu ion-oxygen vacancy and the spontaneous polarization of ferroelectric barium titanate to control the polarization reversal. The electrocaloric effect in the single-domain state was not significantly different from the pristine sample without polarization reversal, and no temperature change was confirmed. In the multi-domain state, we obtained the world's highest figure of merit measured at room temperature due to de-insertion of ferroelastic domain walls. We have demonstrated that materials design utilizing an interaction between defect dipoles and ferroelectric polarization is effective for enhancing the electrocaloric effect.

Academic Significance and Societal Importance of the Research Achievements

強誘電体の自発分極と欠陥複合体の相互作用を巧みに利用することで,ユニポーラーの電圧印加で温度変化0.6 Kを観測した。ここで得られた性能指数は、室温における値としては世界最高性能である。欠陥複合体と自発分極の相互作用を利用した材料設計が、電気熱量効果の増強に有効であることを実証した。
空間反転対称性が破れた極性材料の一つである強誘電体の欠陥を制御して固体冷却が可能であることを実証した本研究は,既存の科学技術の延長線上にはない独創的な機能材料研究である.本成果は,自発分極が非常に大きいZnO、GaNやAlNなどの極性材料にも展開可能であり,固体冷却技術に変革をもたらす成果の創出が期待される。

Report

(6 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • Research Products

    (45 results)

All 2022 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (25 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 24 results,  Open Access: 9 results,  Acknowledgement Compliant: 1 results) Presentation (17 results) (of which Int'l Joint Research: 15 results,  Invited: 16 results) Remarks (1 results)

  • [Int'l Joint Research] チェコ科学アカデミー(チェコ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] アルゴンヌ国立研究所(米国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Order-disorder nature and elastic anomaly of successive phase transition of (K0.5Na0.5)NbO3 proved by broadband Brillouin scattering2022

    • Author(s)
      Kojima Seiji、Tsukada Shinya、Noguchi Yuji
    • Journal Title

      Ferroelectrics

      Volume: 586 Issue: 1 Pages: 2-9

    • DOI

      10.1080/00150193.2021.2014256

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferroelectric polarization of tetragonal BiFeO3; an approach from DFT calculations for BiFeO3-BaTiO3 superlattices2022

    • Author(s)
      Noguchi Yuji、Matsuo Hiroki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 61 Issue: SN Pages: SN1002-SN1002

    • DOI

      10.35848/1347-4065/ac7bd2

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-quality ferroelectric Bi0.5K0.5TiO3-BiFeO3 solid-solution single crystals grown under high-pressure oxygen atmosphere2022

    • Author(s)
      Matsuo Hiroki、Noguchi Yuji
    • Journal Title

      Applied Physics Express

      Volume: 15 Issue: 8 Pages: 081002-081002

    • DOI

      10.35848/1882-0786/ac7eab

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Utilizing ferrorestorable polarization in energy-storage ceramic capacitors2022

    • Author(s)
      Matsuo Hiroki、Utsunomiya Masashi、Noguchi Yuji
    • Journal Title

      NPG Asia Materials

      Volume: 14 Issue: 1

    • DOI

      10.1038/s41427-022-00426-z

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] High Photocurrent Anisotropy in Domain‐Engineered Ferroelectrics for Visible‐Light Polarization Detection2022

    • Author(s)
      Matsuo Hiroki、Noguchi Yuji
    • Journal Title

      Advanced Optical Materials

      Volume: 10 Issue: 21 Pages: 2201280-2201280

    • DOI

      10.1002/adom.202201280

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of Ferroelectricity in BiFeO3-Based Solid Solutions2022

    • Author(s)
      Noguchi Yuji、Matsuo Hiroki
    • Journal Title

      Nanomaterials

      Volume: 12 Issue: 23 Pages: 4163-4163

    • DOI

      10.3390/nano12234163

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Visualization of spontaneous electronic polarization in Pb ion of ferroelectric PbTiO3 by synchrotron-radiation x-ray diffraction2020

    • Author(s)
      Abe Tomohiro、Kim Sangwook、Moriyoshi Chikako、Kitanaka Yuuki、Noguchi Yuji、Tanaka Hiroshi、Kuroiwa Yoshihiro
    • Journal Title

      Applied Physics Letters

      Volume: 117 Issue: 25 Pages: 252905-252905

    • DOI

      10.1063/5.0037396

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Successive redox-mediated visible-light ferrophotovoltaics2020

    • Author(s)
      Noguchi Yuji、Taniguchi Yuki、Inoue Ryotaro、Miyayama Masaru
    • Journal Title

      Nature Communications

      Volume: 11 Issue: 1 Pages: 966-966

    • DOI

      10.1038/s41467-020-14763-6

    • Related Report
      2020 Research-status Report 2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Nanoscale structural analysis of Bi0.5Na0.5TiO32020

    • Author(s)
      Yoneda Yasuhiro、Noguchi Yuji
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 59 Issue: SP Pages: SPPA01-SPPA01

    • DOI

      10.35848/1347-4065/aba2c2

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhanced photovoltaic effects in ferroelectric solid solution thin films with nanodomains2020

    • Author(s)
      Matsuo Hiroki、Noguchi Yuji、Miyayama Masaru、Kiguchi Takanori、Konno Toyohiko J.
    • Journal Title

      Applied Physics Letters

      Volume: 116 Issue: 13 Pages: 132901-132901

    • DOI

      10.1063/1.5142880

    • Related Report
      2020 Research-status Report 2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Uncovering ferroelectric polarization in tetragonal (Bi1/2K1/2)TiO3?(Bi1/2Na1/2)TiO3 single crystals2019

    • Author(s)
      Kitanaka Yuuki、Noguchi Yuji、Miyayama Masaru
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1 Pages: 19275-19275

    • DOI

      10.1038/s41598-019-55576-y

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Composition-driven structural variation in ferrielectric phase of (Bi1/2Na1/2)TiO3-Ba(Mg1/3Nb2/3)O32019

    • Author(s)
      Kitanaka Yuuki、Makisumi Kohei、Noguchi Yuji、Miyayama Masaru、Hoshikawa Akinori、Ishigaki Toru
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: SL Pages: SLLA04-SLLA04

    • DOI

      10.7567/1347-4065/ab37c4

    • NAID

      210000156858

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local structure analysis of PbTiO3 in high-temperature cubic phase2019

    • Author(s)
      Yoneda Y.、Taniguchi H.、Kitanaka Y.、Noguchi Y.
    • Journal Title

      Ferroelectrics

      Volume: 538 Issue: 1 Pages: 57-62

    • DOI

      10.1080/00150193.2019.1569986

    • NAID

      130007735868

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferroelectrics with a controlled oxygen-vacancy distribution by design2019

    • Author(s)
      Noguchi Yuji、Matsuo Hiroki、Kitanaka Yuuki、Miyayama Masaru
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1 Pages: 4225-4225

    • DOI

      10.1038/s41598-019-40717-0

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Successive phase transition of lead-free ferroelectric sodium potassium niobate crystals studied by Raman scattering2018

    • Author(s)
      S. Kojima, J. Zushi, Y. Noguchi, and M. Miyayama
    • Journal Title

      Ferroelectrics

      Volume: 532 Issue: 1 Pages: 183-189

    • DOI

      10.1080/00150193.2018.1430443

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and characterization of (Ba, Sr)RuO3 ceramic targets and thin films for ferroelectric BaTiO3 thin-film capacitors2018

    • Author(s)
      Noguchi Yuji、Tada Masaru、Kitanaka Yuuki、Miyayama Masaru
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 11 Pages: 115135-115135

    • DOI

      10.1063/1.5063861

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal structure and ferroelectric polarization of tetragonal (Bi1/2Na1/2)TiO3-12BaTiO32018

    • Author(s)
      Kitanaka Yuuki、Ogino Motohiro、Noguchi Yuji、Miyayama Masaru、Hoshikawa Akinori、Ishigaki Toru
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 11S Pages: 11UD05-11UD05

    • DOI

      10.7567/jjap.57.11ud05

    • NAID

      210000149799

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Piezoelectric Ca3TaAl3Si2O14 (CTAS): High quality 2-in. single-crystal growth and electro-elastic properties from room to high (650?°C) temperature2018

    • Author(s)
      Fu Xiuwei、Vllora Encarnacin G.、Matsushita Yoshitaka、Kitanaka Yuuki、Noguchi Yuji、Miyayama Masaru、Shimamura Kiyoshi、Ohashi Naoki
    • Journal Title

      Journal of Crystal Growth

      Volume: 501 Pages: 38-42

    • DOI

      10.1016/j.jcrysgro.2018.08.030

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of misfit strain in ferroelectric BaTiO3 thin-film capacitors with SrRuO3-based electrodes on (Ba, Sr)TiO3-buffered SrTiO3 substrates2018

    • Author(s)
      Noguchi Yuji、Maki Hisashi、Kitanaka Yuuki、Matsuo Hiroki、Miyayama Masaru
    • Journal Title

      Applied Physics Letters

      Volume: 113 Issue: 1 Pages: 012903-012903

    • DOI

      10.1063/1.5031156

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Quality Single-Crystal Growth of Polar Perovskites —A Case Study on AgNbO<sub>3</sub>—2018

    • Author(s)
      野口 祐二、北中 佑樹
    • Journal Title

      Journal of the Japanese Association for Crystal Growth

      Volume: 45 Issue: 3 Pages: n/a

    • DOI

      10.19009/jjacg.33-45-3-04

    • NAID

      130007502970

    • ISSN
      0385-6275, 2187-8366
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Novel Ferroelectric Materials2018

    • Author(s)
      Noguchi Yuji、Miyayama Masaru
    • Journal Title

      Nanoparticle Technology Handbook (Third Edition)

      Volume: 214111 Pages: 651-654

    • DOI

      10.1016/b978-0-444-64110-6.00054-8

    • ISBN
      9780444641106
    • Related Report
      2017 Annual Research Report
  • [Journal Article] Gap-state engineering of visible-light-active ferroelectrics for photovoltaic applications2017

    • Author(s)
      Matsuo Hiroki、Noguchi Yuji、Miyayama Masaru
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 207-207

    • DOI

      10.1038/s41467-017-00245-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhanced polarization properties of ferroelectric (Bi<sub>1/2</sub>Na<sub>1/2</sub>)TiO<sub>3</sub>&ndash;Ba(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub> single crystals grown under high-pressure oxygen atmosphere2017

    • Author(s)
      MAKISUMI Kohei、KITANAKA Yuuki、NOGUCHI Yuji、MIYAYAMA Masaru
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 6 Pages: 463-467

    • DOI

      10.2109/jcersj2.16285

    • NAID

      130006899929

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Resistivity and piezoelectric properties of Ca3TaGa1.5Al1.5Si2O14 single crystals for high temperature sensors2017

    • Author(s)
      Fu Xiuwei、Villora Encarnacion G.、Matsushita Yoshitaka、Kitanaka Yuuki、Noguchi Yuji、Miyayama Masaru、Shimamura Kiyoshi、Ohashi Naoki
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 89 Pages: 56697-56703

    • DOI

      10.1039/c7ra11926g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bulk and domain-wall effects in ferroelectric photovoltaics2016

    • Author(s)
      Hiroki Matsuo, Yuuki Kitanaka, Ryotaro Inoue, Yuji Noguchi, Masaru Miyayama, Takanori Kiguchi, Toyohiko J. Konno
    • Journal Title

      Physical Review B

      Volume: 94 Issue: 21 Pages: 214111-214111

    • DOI

      10.1103/physrevb.94.214111

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Energy storage ceramic capacitors utilizing ferrorestorable polarization2022

    • Author(s)
      Yuji Noguchi and Hiroki Matsuo
    • Organizer
      15th International Symposium on Ferroic Domains & Micro- to Nano-scopic Structures (ISFD-15)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Progress and future prospects of bismuth titanate-based polar materials2022

    • Author(s)
      Yuji Noguchi
    • Organizer
      International Session at the Ceramic Society of Japan Annual Meeting (International Session)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrically controlled polar perovskites2020

    • Author(s)
      Yuji Noguchi
    • Organizer
      The 5th International Conference on Smart Materials and Nanotechnology (SmartMat@2020)
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 格子欠陥を利用した強誘電体・フェリ誘電体設計2020

    • Author(s)
      野口 祐二
    • Organizer
      第33日本セラミックス協会秋季シンポジウム
    • Related Report
      2020 Research-status Report
    • Invited
  • [Presentation] 分極性ペロブスカイトの材料設計と新機能開拓2020

    • Author(s)
      野口 祐二
    • Organizer
      強的秩序とその操作に関わる研究グループ 第10回 研究会
    • Related Report
      2020 Research-status Report
    • Invited
  • [Presentation] Electric-filed-induced ferrielectric-ferroelectric transitions in polar perovskites2019

    • Author(s)
      Yuji Noguchi
    • Organizer
      19th US‐Japan Seminar on Dielectric and Piezoelectric Ceramics (19th US-Japan)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrical control of ferrielectric and ferroelectric perovskites2019

    • Author(s)
      Yuji Noguchi
    • Organizer
      The 11th China and Japan Symposium on Ferroelectric Materials and Their Applications (CJFMA11)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrical control of ferrielectric and ferroelectric phases in Bi-based polar perovskite2019

    • Author(s)
      Yuji Noguchi
    • Organizer
      19th International Conference on Crystal Growth and Epitaxy (ICCGE-19
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ferroelectric capacitors with a controlled oxygen-vacancy distribution2019

    • Author(s)
      Yuji Noguchi
    • Organizer
      10th INTERNATIONAL CONFERENCE ON MATERIALS FOR ADVANCED TECHNOLOGIES (ICMAT 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Giant Photovoltaic Effect of Ferroelectric Domain Walls in Perovskite Ferroelectrics2018

    • Author(s)
      Yuji Noguchi
    • Organizer
      2018 ISAF-FMA-AMF-AMEC-PFM Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Polarization Twist in Perovskite Ferrielectrics Enhanced Piezoresponse in (Bi,Na)TiO3-Based Single Crystals2018

    • Author(s)
      Yuji Noguchi
    • Organizer
      2018 ISAF-FMA-AMF-AMEC-PFM Joint Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Gap-state engineering of visible-light-active photoferroelectrics2018

    • Author(s)
      Yuji Noguchi
    • Organizer
      International Conference on Science and Technology of Emerging Materials 2018 (STEMa2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Local Structure Analysis of PbTiO3 in High-Temperature Cubic Phase2018

    • Author(s)
      Y. Yoneda, H. Taniguchi, and Y. Noguchi
    • Organizer
      14th Russia / CIS / Baltic / Japan Symposium on Ferroelectricity RCBJSF 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polarization twist in perovskite ferrielectrics: A study on (Bi,Na)TiO3-BaTiO3 single crystals2017

    • Author(s)
      Yuji Noguchi
    • Organizer
      The Fourteenth International Meeting on Ferroelectricity (IMF 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ferroelectric Photovoltaics Delivering Abnormally High Photovoltages2017

    • Author(s)
      Yuji Noguchi
    • Organizer
      The 6th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Enhanced piezoresponse in polar perovskite oxides: Polarization twist in (Bi,Na)TiO3-based ferrielectrics2017

    • Author(s)
      Yuji Noguchi
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology including Glass & Optical Materials Division Meeting 2017 (PACRIM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Giant Photovoltaic Effect of Ferroelectric Domain Walls in BiFeO3 and BaTiO32017

    • Author(s)
      Yuji Noguchi
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology including Glass & Optical Materials Division Meeting 2017 (PACRIM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] researchmap

    • URL

      https://researchmap.jp/read0103227

    • Related Report
      2020 Research-status Report

URL: 

Published: 2017-07-21   Modified: 2024-12-25  

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