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Novel properties generated by edge sites of layered oxides and hydroxides

Research Project

Project/Area Number 20K20450
Project/Area Number (Other) 19H05532 (2019)
Research Category

Grant-in-Aid for Challenging Research (Pioneering)

Allocation TypeMulti-year Fund (2020)
Single-year Grants (2019)
Review Section Medium-sized Section 36:Inorganic materials chemistry, energy-related chemistry, and related fields
Research InstitutionWaseda University

Principal Investigator

Kuroda Kazuyuki  早稲田大学, 理工学術院, 名誉教授 (90130872)

Project Period (FY) 2019-06-28 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥25,870,000 (Direct Cost: ¥19,900,000、Indirect Cost: ¥5,970,000)
Fiscal Year 2021: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Fiscal Year 2020: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2019: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Keywords層状物質 / 形態制御 / ナノ材料 / 層端面
Outline of Research at the Start

無機層状化合物の結晶端(層端面)には結晶内とは異なる配位環境を有した化学種が存在しており、様々な層状化合物の機能発現に関わる重要な役割を担っていると考えられる。そこで本研究課題では、層端面を多く露出させた異方形状の層状酸化物や層状水酸化物の合成・解析・機能評価により、層状化合物の層端面が有する化学的・物理的性質の解明に挑む。

Outline of Final Research Achievements

Edge surfaces of two-dimensional crystals are expected to have unique properties, but the nature of edge surfaces has not been explored. In this study, some synthetic methods, such as the anisotropic crystal growth of layered metal hydroxides along with the stacking direction and the size-controlled bottom-up preparation of metal hydroxide nanosheets through two-dimensional crystal growth, were developed to control the proportion of the exposed edge surfaces to the whole crystal surfaces. We also successfully detected hydroxy groups probably located on edge surfaces by analyzing rod-like crystals with an unusually high aspect ratio of the thickness to the lateral size higher than 1.

Academic Significance and Societal Importance of the Research Achievements

無機層状化合物は古くから幅広い分野で用いられてきた材料群であるが、結晶端となる層端面に由来する情報は平均構造の中に埋もれていた。本研究で開発に成功した結晶外表面に対する層端面の露出割合を制御する様々な形態制御法は、層端面の理解・活用を大きく前進させるものであり、二次元化合物の科学の深化や次世代材料開発に向け、幅広い無機材料を横断する新たな研究領域の開拓につながると期待される。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Annual Research Report
  • Research Products

    (15 results)

All 2022 2021 2020 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (11 results) (of which Int'l Joint Research: 2 results) Remarks (1 results)

  • [Journal Article] Anisotropic crystal growth of layered nickel hydroxide along stacking direction using amine ligands2022

    • Author(s)
      Muramatsu Keisuke、Mina Jimba、Yumiko Yamada、Wada Hiroaki、Shimojima Atsushi、Kuroda Kazuyuki
    • Journal Title

      Inorganic Chemistry

      Volume: - Issue: 22 Pages: 8490-8497

    • DOI

      10.1021/acs.inorgchem.2c00421

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrolysis of Methoxylated Nickel Hydroxide Leading to Single-Layer Ni(OH)2 Nanosheets2021

    • Author(s)
      Muramatsu Keisuke、Kuroda Yoshiyuki、Wada Hiroaki、Shimojima Atsushi、Kuroda Kazuyuki
    • Journal Title

      Inorganic Chemistry

      Volume: - Issue: 10 Pages: 7094-7100

    • DOI

      10.1021/acs.inorgchem.0c03830

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct bottom-up synthesis of size-controlled monodispersed single-layer magnesium hydroxide nanosheets modified with tripodal ligands2021

    • Author(s)
      Muramatsu Keisuke、Kamiusuki Yuya、Kuroda Yoshiyuki、Wada Hiroaki、Shimojima Atsushi、Kuroda Kazuyuki
    • Journal Title

      Dalton Transactions

      Volume: 50 Issue: 9 Pages: 3121-3126

    • DOI

      10.1039/d1dt00207d

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Presentation] Preparation of anisotropic crystals of β-Ni(OH)<sub>2</sub> grown along stacking direction using Ni-diamine complexes2022

    • Author(s)
      Keisuke Muramatsu, Mina Jimba, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
    • Organizer
      The 17th International Clay Conference (ICC2022)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ホランダイト型マンガン酸化物の形態に及ぼす酢酸の効果2021

    • Author(s)
      水野貴大, 村松佳祐, 上宇宿雄哉, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第11回CSJ化学フェスタ2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 層状遷移金属水酸化物の積層方向への成長条件2021

    • Author(s)
      神場未菜, 村松佳祐, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第64回粘土科学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] メトキシ化金属水酸化物の加水分解反応を利用した遷移金属水酸化物ナノシートの合成法2021

    • Author(s)
      村松佳祐, 黒田義之, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      電気化学会東海支部・東北支部合同シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] Bottom-up preparation routes for metal hydroxide nanosheets through in situ surface modification with alkoxy groups2021

    • Author(s)
      Keisuke Muramatsu, Yuya Kamiusuki, Yoshiyuki Kuroda, Hiroaki Wada, Atsushi Shimojima, Kazuyuki Kuroda
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 積層方向へ優先的に結晶成長した層状水酸化ニッケルの液相合成2021

    • Author(s)
      神場未菜, 村松佳祐, 山田裕美子, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      2020年度第7回ZAIKEN Festa
    • Related Report
      2020 Research-status Report
  • [Presentation] 層状水酸化ニッケルの結晶形態に及ぼすアミン系配位子の効果2020

    • Author(s)
      神場未菜, 村松佳祐, 山田裕美子, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      公益社団法人日本セラミックス協会第33回秋季シンポジウム
    • Related Report
      2020 Research-status Report
  • [Presentation] 三脚型配位子により修飾された単分散性水酸化マグネシウムナノシートの直接合成2020

    • Author(s)
      上宇宿雄哉, 村松佳祐, 黒田義之, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Research-status Report
  • [Presentation] アミン系配位子存在下での層状水酸化ニッケルの結晶成長挙動2020

    • Author(s)
      神場未菜, 村松佳祐, 山田裕美子, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第10回CSJ化学フェスタ2020
    • Related Report
      2020 Research-status Report
  • [Presentation] 三脚型配位子により修飾された水酸化マグネシウムナノシートの結晶成長挙動2020

    • Author(s)
      上宇宿雄哉, 村松佳祐, 黒田義之, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      第49回結晶成長国内会議
    • Related Report
      2020 Research-status Report
  • [Presentation] アミン系配位子を用いた層状水酸化ニッケルの積層方向への異方成長2020

    • Author(s)
      神場未菜, 村松佳祐, 山田裕美子, 和田宏明, 下嶋敦, 黒田一幸
    • Organizer
      日本化学会第100春季年会(2020)
    • Related Report
      2019 Annual Research Report
  • [Remarks] 黒田・下嶋・和田研究室

    • URL

      http://www.waseda.jp/sem-kuroda_lab/

    • Related Report
      2019 Annual Research Report

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Published: 2019-07-04   Modified: 2024-03-26  

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