| Budget Amount *help |
¥30,940,000 (Direct Cost: ¥23,800,000、Indirect Cost: ¥7,140,000)
Fiscal Year 2011: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2010: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2009: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
|
|---|
| Research Abstract |
Aluminum has attracted considerable attention because of their extreme versatility and unique range of properties, including acidity, hardness, and electroconductivity. In this study, various aluminum compounds possessing mono- and multi-aluminum sites were synthesized by using Keggin and Dawson-type lacunary polyoxometalates as inorganic ligands. For the oxidation of alcohols in water catalyzed by aluminum-coordinated polyoxotungstates with molecular oxygen, the activities were significantly affected by the structures around aluminum sites. Furthermore, a cationic organozirocnium fragment was successfully supported onto the aluminum site constructed in polyoxometalate; this is the first example of the polyoxoanion-supported organometallic compound by utilizing the aluminum site as an atomic-level support.
|
