| Budget Amount *help |
¥213,330,000 (Direct Cost: ¥164,100,000、Indirect Cost: ¥49,230,000)
Fiscal Year 2013: ¥37,180,000 (Direct Cost: ¥28,600,000、Indirect Cost: ¥8,580,000)
Fiscal Year 2012: ¥37,180,000 (Direct Cost: ¥28,600,000、Indirect Cost: ¥8,580,000)
Fiscal Year 2011: ¥37,180,000 (Direct Cost: ¥28,600,000、Indirect Cost: ¥8,580,000)
Fiscal Year 2010: ¥37,180,000 (Direct Cost: ¥28,600,000、Indirect Cost: ¥8,580,000)
Fiscal Year 2009: ¥64,610,000 (Direct Cost: ¥49,700,000、Indirect Cost: ¥14,910,000)
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| Outline of Final Research Achievements |
Catalytic collaboration between transition-metal complexes and inorganic Lewis acid was found to show unique activity toward the straightforward activation of otherwise stable carbon-hydrogen and carbon-carbon bonds in organic substrates, which are directly alkenylated or alkylated by insertion of various unsaturated reactants into the activated bonds. A broad variety of π-conjugated frameworks could be synthesized by the collaborative catalysts, e.g. Ni/Al-catalyzed hydrocarbamoylation of terminal alkenes using N,N-dimethylformamide as basic organic chemicals and Ni/B-catalyzed polyfluoroarylcyanation of alkynes employing polyfluorobenzonitriles for the construction of functional organic materials. In addition, the collaborative catalysts between palladium metals and silylethynoxy group activated carbon-hydrogen bonds followed by annulation with other unsaturated reactants to form chromene derivatives.
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