Development of Highly Selective Deuteration Reaction Using Quantum Molecular Sieving Effect Enhanced in Nanospace Fields

• Project/Area Number: 21241026
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanomaterials/Nanobioscience
• Research Institution: Shinshu University (2010-2011); Chiba University (2009)
• Principal Investigator: KANEKO Katsumi 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 特別特任教授 (20009608)
• Co-Investigator(Kenkyū-buntansha): OHBA Tomonori 千葉大学, 大学院・理学研究科, 助教 (80406884) ; ITOH Tsutomu 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 助教 (40586822) ; FUJIMORI Toshihiko 信州大学, エキゾチック・ナノカーボンの創成と応用プロジェクト拠点, 助教 (60586824)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥47,450,000 (Direct Cost: ¥36,500,000、Indirect Cost: ¥10,950,000); Fiscal Year 2011: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000); Fiscal Year 2010: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000); Fiscal Year 2009: ¥20,540,000 (Direct Cost: ¥15,800,000、Indirect Cost: ¥4,740,000)
• Keywords: 量子分子篩効果 / ミクロポアフィリング / ナノ細孔 / 低温吸着 / カーボンナノチューブ / 水素 / メタン / 同位体分離 / 量子揺らぎ / 活性炭 / 極低温気体吸着 / 活性炭素繊維 / 量子分子篩作用 / 単層カーボンナノチューブ / 重水素 / メタン同位体 / ナノ細孔体

Research Abstract

We elucidated the effect of the nanopore structure and temperature on quantum adsorption for hydrogen isotopes using well-defined single wall carbon nanotube. Also an explicit quantum molecular sieving effect for methane isotopes for nanoporous carbons was firstly shown. In this study, the quantum molecular sieving is evidenced with pure isotope gas adsorption and the mixed isotope gas adsorption.

Research Products

• [Journal Article] Collective Interactions of Molecules with an Interfacial Solid (2012)
  • Author(s): K. Kaneko, T. Itoh, T. Fujimori
  • Journal Title: Chemistry Letters Volume: 41 Issue: 5 Pages: 466-475
  • DOI: 10.1246/cl.2012.466
  • NAID: 10030619151
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Formation of CO_x Free H_2 and Cup-stacked Carbon Nanotubes over Nano-Ni Dispersed Single Wall Carbon Nanohorns (2012)
  • Author(s): S. Wang, T. Itoh, T. Fujimori, M. M. Castro, A. S. Albero, F. Rodriguez-Reinoso, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: Langmuir Volume: 28 Issue: 19 Pages: 7564-7571
  • DOI: 10.1021/la3006986
  • Peer Reviewed
• [Journal Article] Selective Probe of the Morphology and Local Vibrations at Carbon Nanoasperities (2012)
  • Author(s): T. Fujimori, K. Urita, D. Tomanek, T. Ohba, I. Moriguchi, M. Endo, K. Kaneko
  • Journal Title: J. Chem. Phys. Volume: 136 Issue: 6
  • DOI: 10.1063/1.3682771
  • NAID: 120007102132
  • Peer Reviewed
• [Journal Article] Effect of Nanoscale Curvature Sign and Bundle Structure on Supercritical H_2 and CH_4 Adsorptivity of Single Wall Carbon Nanotube (2011)
  • Author(s): M. Yamamoto, T. Itoh, H. Sakamoto, T. Fujimori, K. Urita, Y. Hattori, T. Ohba, H. Kagita, H. Kanoh, S. Niimura, K. Hata, K. Takeuchi, M. Endo, F. Rodriguez-Reinoso, K. Kaneko
  • Journal Title: Adsorption Volume: 17 Pages: 643-651
  • Peer Reviewed
• [Journal Article] Confinement in Carbon Nanospace-Induced Production of KI Nanocrystals of High Pressure Phase (2011)
  • Author(s): K. Urita, Y. Shiga, T. Fujimori, Y. Hattori, H, Kanoh, T. Ohba, H. Tanaka, M. Yudasaka, S. Iijima, I, Moriguchi, F. Okino, M. Endo, K. Kaneko, J
  • Journal Title: Am. Chem. Soc. Volume: 133 Issue: 27 Pages: 10344-10347
  • DOI: 10.1021/ja202565r
  • Peer Reviewed
• [Journal Article] Electronically Modified Single Wall Carbon Nanohorns with Iodine Adsorption (2011)
  • Author(s): F. Khoerunnisa, T. Fujimori, T. Itoh, H. Kanoh, T. Ohba, M. Yudasaka, S. Iijima, K. Kaneko
  • Journal Title: Chem. Phys. Lett. Volume: 501 Issue: 4-6 Pages: 485-490
  • DOI: 10.1016/j.cplett.2010.11.086
  • NAID: 120007102135
  • Peer Reviewed
• [Journal Article] Anomaly of CH_4 Molecular Assembly Confined in Single Wall Carbon Nanohorn Spaces (2011)
  • Author(s): S. Hashimoto, T. Fujimori, H. Tanaka, K. Urita, T. Ohba, H. Kanoh, T. Itoh, M. Asai, H. Sakamoto, S. Niimura, M. Endo, F. Rodoriguez-Reinoso, K. Kaneko, J
  • Journal Title: Am. Chem. Soc. 133 Volume: 133 Issue: 7 Pages: 2022-2024
  • DOI: 10.1021/ja1086886
  • Peer Reviewed
• [Journal Article] Effect of nanoscale curvature sign and bundle structure on supercritical H_2 and CH_4 adsorptivity of single wall carbon nanotube (2011)
  • Author(s): M.Yamamoto, K.Kaneko, 他13名
  • Journal Title: Adsorption Volume: 17 Issue: 3 Pages: 643-651
  • DOI: 10.1007/s10450-011-9358-y
  • Peer Reviewed
• [Journal Article] Marked Adsorption Irreversibility of Graphitic Nanoribbons for CO_2 and H_2O (2011)
  • Author(s): M.Asai, K.Kaneko, 他7名
  • Journal Title: J.Am.Chem.Soc. Volume: 133 Issue: 38 Pages: 14880-14883
  • DOI: 10.1021/ja205832z
  • Peer Reviewed
• [Journal Article] Kinetically Forbidden Transformations of Water Molecular Assmblies in Hydrophobic Micropores (2011)
  • Author(s): T.Ohba, K.Kaneko
  • Journal Title: Langmuir Volume: 27 Issue: 12 Pages: 7609-7613
  • DOI: 10.1021/la201115s
  • Peer Reviewed
• [Journal Article] Selective D_2 Adsorption Enhanced by the Quantum Sieving Effect on Entangled Single-Wall Carbon Nanotubes (2010)
  • Author(s): D. Noguchi, H. Tanaka, T. Fujimori, T. Kagita, Y. Hattori, H. Honda, K. Urita, S. Utsumi, Z.-M. Wang, T. Ohba, H. Kanoh, K. Hata, K. Kaneko
  • Journal Title: J. Phys.: Condens. Matter Volume: 22 Issue: 33 Pages: 334207-334221
  • DOI: 10.1088/0953-8984/22/33/334207
  • Peer Reviewed
• [Journal Article] Evidence of Dynamic Pentagon-Heptagon Pairs in Single-Wall Carbon Nanotubes using Surface-Enhanced Raman Scattering (2010)
  • Author(s): T. Fujimori, K. Urita, T. Ohba, H. Kanoh, K. Kaneko
  • Journal Title: J. Am. Chem. Soc. Volume: 132 Issue: 19 Pages: 6764-6767
  • DOI: 10.1021/ja100760m
  • Peer Reviewed
• [Journal Article] Pseudometallization of single wall carbon nanotube bundles with intercalation of naphthalene (2010)
  • Author(s): S.Gotovac-Atlagic, et al.
  • Journal Title: Phys.Rev.B Volume: 82
  • Peer Reviewed
• [Journal Article] Selective D_2 Adsorption Enhanced by Quantum Sieving Effect on Entangled Sinle-Wall Carbon Nanotubes (2010)
  • Author(s): D.Noguchi, et al.
  • Journal Title: J.Phys.: Condens.Matter Volume: 22 Pages: 334207-334221
  • Peer Reviewed
• [Journal Article] Evidence of Dynamic Pentagon-Heptagon Pairs in Single-Wall Carbon Nanotubes using Surface-Enhanced Raman Scattering (2010)
  • Author(s): T.Fujimori, et al.
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 6764-6767
  • Peer Reviewed
• [Journal Article] Effect of a Quaternary Ammonium Salt on Propylene Carbonate Structure in Slit-Shape Carbon Nanopores (2010)
  • Author(s): A.Tanaka, et al.
  • Journal Title: J.Amer.Chem.Soc. Volume: 132 Pages: 2112-2113
  • Peer Reviewed
• [Journal Article] Equilibration-time and pore-width dependent hysteresis of water adsorption isotherm on hydrophobic microporous carbons (2010)
  • Author(s): M.Nakamura, et al.
  • Journal Title: Carbon Volume: 48 Pages: 305-312
  • Peer Reviewed
• [Journal Article] Equilibration-time and pore-width dependent hysteresis of water adsorption isotherm on hydrophobic microporous carbons (2010)
  • Author(s): M.Nakamura, T.Ohba, P.Branton, H.Kanoh, K.Kaneko
  • Journal Title: Carbon 48 Pages: 305-312
  • Peer Reviewed
• [Journal Article] Enhanced Hydrogen Adsorptivity of Single-Wall Carbon Nanotube Bundles by One-Step C_60-Pillaring Method (2009)
  • Author(s): M. Arai, S. Utsumi, M. Kanamaru, K. Urita, T. Fujimori, N. Yoshizawa, D. Noguchi, K. Nishiyama, Y. Hattori, F. Okino, T. Ohba, H. Tanaka, H. Kanoh, K. Kaneko
  • Journal Title: Nano Lett. Volume: 9 Issue: 11 Pages: 3694-3698
  • DOI: 10.1021/nl9015733
  • Peer Reviewed
• [Journal Article] Quantum Effects on Hydrogen Isotopes Adsorption in Nanopores (2009)
  • Author(s): H. Tanaka, D. Noguchi, A. Yuzawa, T. Kodaira, K. Kaneko
  • Journal Title: J. Low Temp. Phys. Volume: 157 Issue: 3-4 Pages: 352-373
  • DOI: 10.1007/s10909-009-9917-8
  • Peer Reviewed
• [Journal Article] Quantum Effects on Hydrogen Isotopes Adsorption in Nanopores (2009)
  • Author(s): H.Tanaka, D.Noguchi, A.Yuzawa, T.Kodaira, K.Kaneko
  • Journal Title: Journal of Low Temperature Physics 157 Pages: 352-373
  • Peer Reviewed
• [Journal Article] Fine Pore Mouth Structure of Molecular Sieve Carbon with GCMC-Assisted Supercritical Gas Adsorption Analysis (2009)
  • Author(s): R.Kobori, T, Ohba, T.Suzuki, T.Iiyama, S.Ozeki, M.Inagaki, A.Nakamura, M.Kawai, H, Kanoh, K.Kaneko
  • Journal Title: Adsorption 114 Pages: 114-122
  • Peer Reviewed
• [Presentation] Quantum-Fluctuation Induced Sieving Effect in Physical Adsorption on Nanoporous Materials (2012)
  • Author(s): 金子克美
  • Organizer: 2012 International Nanoporous Materials Workshop
  • Place of Presentation: Daejeon,韓国(招待講演)
  • Year and Date: 2012-03-02
• [Presentation] QUANTUM MOLECULAR SIEVING OF NANOPOROUS MATERIALS FOR HYDROGEN AND METHANE ISOTOPES (2012)
  • Author(s): K. Kaneko
  • Organizer: 6th Pacific Basin Conference on Adsorption Science and Technology(PBAST6)
  • Place of Presentation: Taiwan, Taipei
• [Presentation] Micropore Filling of Quantum Molecules (2011)
  • Author(s): 金子克美
  • Organizer: Dubinin記念MODERN PROBLEMS OF ADSORPTION国際会議
  • Place of Presentation: Moscow,ロシア(招待講演)
  • Year and Date: 2011-10-27
• [Presentation] Carbon Nanospace-Aided Quantum Molecular Sieving for Separation of Nuclear Fusion Fuels and Radioactive Wastes (2011)
  • Author(s): 金子克美
  • Organizer: アメリカ化学工学会
  • Place of Presentation: Minneapolis米国(招待講演)
  • Year and Date: 2011-10-17
• [Presentation] MICROPORE FILLING OF QUANTUM MOLECULES (2011)
  • Author(s): K. Kaneko
  • Organizer: The International Conference dedicated to the 50th anniversary of Academician M. M. Dubinin : MODERN PROBLEMS OF ADSORPTION
  • Place of Presentation: Moscow, Russia
• [Presentation] QUANTUM MOLECULAR SIEVING OF ISOTOPIC HYDROGEN AND METHANE : APPLICATION POTENTIAL TO CONTROL OF RADIOACTIVE ELEMENTS (2011)
  • Author(s): K. Kaneko
  • Organizer: 2011 AIChE Annual Meeting
  • Place of Presentation: Minneapolis, USA
• [Presentation] QUANTUM MOLECULAR SIEVING OF ISOTOPIC HYDROGEN AND METHANE (2011)
  • Author(s): K. Kaneko
  • Organizer: Annual International World Conference on Carbon(Carbon2011)
  • Place of Presentation: Shanghai, China
• [Presentation] NONOENVIRONMENT-SENSITIVE SOLID PORE WALLS (2011)
  • Author(s): K. Kaneko
  • Organizer: International Workshop on Adsorption in Compliant Nanoporous Solids : Theory, Simulation, and Experiments
  • Place of Presentation: Paris, France
• [Presentation] Application potential of Carbon Nanopore-Induced Confinent Effect (2010)
  • Author(s): K.Kaneko
  • Organizer: The 8^<th> International Conference on Carbon Saves the Earth 2010
  • Place of Presentation: 城島高原ホテル、大分
  • Year and Date: 2010-11-26
• [Presentation] Nanocon finement-Mediated Molecular and Ionic Assemblies (2010)
  • Author(s): K.Kaneko
  • Organizer: 21th International Conference on Chemical Thermodynamics
  • Place of Presentation: 国際会議場、筑波
  • Year and Date: 2010-08-02
• [Presentation] Novel Chemical Functions of Carbon Nanopaces and Their Application Potential (2010)
  • Author(s): K.Kaneko
  • Organizer: The 5th International Symposium on Novel Carbon Resource Sciences
  • Place of Presentation: Curtin Univ of Tech.Perth, Australia
  • Year and Date: 2010-04-22
• [Presentation] NOVEL CHEMICAL FUNCTIONS OF CARBON NANOPACES AND THEIR APPLICATION POTENTIAL (2010)
  • Author(s): K. Kaneko
  • Organizer: The 5th International Symposium on Novel Carbon Resource Sciences
  • Place of Presentation: Perth, Australia
• [Presentation] Structural Characterization of Molecules and Ions in Nanopore Spaces. (2009)
  • Author(s): K.Kaneko
  • Organizer: Materials Research Society
  • Place of Presentation: ボストン、USA
  • Year and Date: 2009-12-02
• [Presentation] ADSORPTION NANOSCIENCE FOR SUSTAINABLE TECHNOLOGY (2009)
  • Author(s): K.Kaneko
  • Organizer: 7th Asia Pacific Conference on Sustainable Energy and Environmental Technologies
  • Place of Presentation: 青島、中国
  • Year and Date: 2009-10-16
• [Presentation] STRUCTURAL UNDERSTANDING OF METASTABLE ADSORPTION STATE OF WATER IN NANOSCALE PORES OF HYDROPHOBIC CARBON. (2009)
  • Author(s): K.Kaneko
  • Organizer: 6th International Discussion Meeting on Relaxations in Complex System
  • Place of Presentation: ローマ、イタリア
  • Year and Date: 2009-09-01
• [Presentation] CARBON NANOPORE FIFLD-INDUCED IONIC STRUCTURES (2009)
  • Author(s): K.Kaneko
  • Organizer: 4th International Conference on Polymer Batteries and Fuel Cells
  • Place of Presentation: 横浜
  • Year and Date: 2009-08-02
• [Book] Hydrogen Adsorptivity of Bundle-Structure Controlled Single-Wall Carbon Nanotubes, Carbon Nanotubes-From Research to Applications (2011)
  • Author(s): S. Utsumi and K. Kaneko
  • Publisher: InTech Open Access Publisher, Rijeka, Croatia
• [Book] Modeling, and Processing (2011)
  • Author(s): S. Utsumi and K. Kaneko
  • Publisher: (Ed. N. Kane llopous) CRC Press
• [Book] ガス貯蔵・分離,炭素学 (2011)
  • Author(s): 金子克美、坂本裕俊
  • Publisher: 化学同人
• [Book] 二面性ナノカーボンの環境鋭敏構造性,界面の分子科学-界面デザインと界面計測(日本化学会編) (2011)
  • Author(s): 藤森利彦、伊藤努武、金子克美
  • Publisher: 化学同人
• [Book] Nanoporous Materials : Advanced Techniques for Characterization, Modeling, and Processing (2011)
  • Author(s): 内海重宣、金子克美
  • Total Pages: 33
  • Publisher: CRC Press (New York, USA)
• [Book] 水素貯蔵材料:炭素材料,「水素エネルギー技術の展開(秋葉悦男監修)」 (2010)
  • Author(s): 田中秀樹、金子克美
  • Publisher: シーエムシー出版
• [Book] 革新的な多孔質材料 (2010)
  • Author(s): 金子克美
  • Total Pages: 7
  • Publisher: 化学同人
• [Book] 水素エネルギー技術の展開 (2010)
  • Author(s): 田中秀樹
  • Total Pages: 17
  • Publisher: シーエムシー
• [Remarks] ホームページにて研究活動を公開している。
  • URL: http://www.shinshu-u.ac.jp/project/encs/
• [Remarks] 信州大学ホームページ信州知の森:先端研究知の創造、"巨大化学プラントに匹敵するナノカーボン吸着機能の夢と可能性"のTV
  • URL: http://www.shinshu-u.ac.jp/special/research/index.html