Ion intercalation and functionality at Prussian blue interface

• Project/Area Number: 21244052
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Condensed matter physics II
• Research Institution: University of Tsukuba
• Principal Investigator: MORITOMO Yutaka 筑波大学, 数理物質系, 教授 (00283466)
• Co-Investigator(Renkei-kenkyūsha): KAMIOKA Hayato 筑波大学, 数理物質系, 助教 (40431671)
• Project Period (FY): 2009 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥47,580,000 (Direct Cost: ¥36,600,000、Indirect Cost: ¥10,980,000); Fiscal Year 2012: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000); Fiscal Year 2011: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000); Fiscal Year 2010: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000); Fiscal Year 2009: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
• Keywords: プルシャンブルー類似体 / リチウムイオン二次電池 / ナトリウムイオン二次電池 / Cs除染 / 量子ビーム / プルシャンブルー類似体薄膜 / リチウムイオン電池 / 電位曲線 / X線吸収分光 / 粉末構造解析 / シアノ錯体接 / 高速エレクトロクロミズム / カチオン経路 / 第一原理計算 / 価数差分分光 / 構造相転移 / シアノ錯体接合

Research Abstract

Prussian blue analogues consists of jungle-gym-type host framework due to covalent bonding between transition metal ion and cyano group and guest alkali ions. We obtained following results:
(1) all-solid ion device
(2) determination of the ion conduction path
(3) ion distribution analysis based on depth-resolved X-ray absorption spectroscopy
(4) determination of the Na site
(5) excellent cathode properties in lithium-ion secondary battery
(6) ultra-rapid discharge process
(7) structural and electronic properties against lithium-ion concentration
(8) highly-efficient decontamination of radioactive Cesium-ion, and
(9) excellent cathode properties in sodium-ion secondary battery. Thus obtained results are far beyond the original proposal.

Research Products

• [Journal Article] Alkali cation potential and functionality in the nanoporous Prussian blue analogues (2013)
  • Author(s): Y. Moritomo and H. Tanaka
  • Journal Title: Advance in Condenced Matter Physics Volume: 2013 Pages: 539620-539620
  • DOI: 10.1155/2013/539620
  • Peer Reviewed
• [Journal Article] Cobalt Hexacyanoferrate as Cathode Material for Nap Secondary Battery (2013)
  • Author(s): M. Takachi, T. Matsuda, and Y. Moritomo
  • Journal Title: Appl. Phys. Express Volume: 6 Issue: 2 Pages: 25802-25802
  • DOI: 10.7567/apex.6.025802
  • Peer Reviewed
• [Journal Article] A sodium manganese ferrocyanide thin film for Na-ion batteries (2013)
  • Author(s): T. Matsuda, M. Takachia and Y. Moritomo
  • Journal Title: Chem. Comm. Volume: 49 Issue: 27 Pages: 2721-2721
  • DOI: 10.1039/c3cc38839e
  • Peer Reviewed
• [Journal Article] Structural Properties of Manganese Hexaqyanoferrates against Li Concentration (2013)
  • Author(s): Yutaro Kurihara, Tomoyuki Matsuda, Yutaka Moritomo
  • Journal Title: Japanese Journal of Applied Physics Volume: 52 Issue: 1R Pages: 17301-17301
  • DOI: 10.7567/jjap.52.017301
  • Peer Reviewed
• [Journal Article] Intrinsic rapid Na+ intercalation observed in NaxCoO2 thin film (2013)
  • Author(s): T. Shibata, W. Kobayashi, and Y. Moritomo
  • Journal Title: AIP Advances Volume: 3 Issue: 3 Pages: 32104-32104
  • DOI: 10.1063/1.4794719
  • Peer Reviewed
• [Journal Article] Structural, Electronic, and Electrochemical Properties of LixCo[Fe(CN)6]0:902.9H2O (2013)
  • Author(s): Masamitsu Takachi, Tomoyuki Matsuda, and Yutaka Moritomo
  • Journal Title: Japanese Journal of Applied Physics Volume: 52 Issue: 4R Pages: 44301-44301
  • DOI: 10.7567/jjap.52.044301
  • Peer Reviewed
• [Journal Article] Photoinduced Phase Transition into a Hidden Phase n Cobalt Hexacyanoferrate as Investigated by Time-Resolved X-ray Absorption Fine Structure (2013)
  • Author(s): Yutaka MORITOMO, Hayato KAMIOKA, Takayuki SHIBATA,Shunsuke NOZAWA, Tokushi SATO, and Shin-ichi ADACHI
  • Journal Title: Journal of the Physical Society of Japan Volume: 82 Issue: 3 Pages: 033601-033601
  • DOI: 10.7566/jpsj.82.033601
  • Peer Reviewed
• [Journal Article] Thin Film Electrodes of Prussian Blue Analogues with Rapid Li^+ Intercalation (2012)
  • Author(s): Yutaka Moritomo, Masamitsu Takachi, Yutaro Kurihara, Tomoyuki Matsuda
  • Journal Title: Applied Physics Express Volume: 5 Issue: 4 Pages: 41801-41801
  • DOI: 10.1143/apex.5.041801
  • Peer Reviewed
• [Journal Article] Fast Discharge Process of Thin Film Electrode of Prussian Blue Analogue (2012)
  • Author(s): Y. Moritomo, X.-H. Zhu, M. Takachi, and T. Matsuda
  • Journal Title: Jpn. J. Appl. Phys Volume: 51 Issue: 10R Pages: 107301-107301
  • DOI: 10.1143/jjap.51.107301
  • NAID: 40019456520
• [Journal Article] Cs+ trapping in size-controlled nanospaces of hexacyanoferrates (2012)
  • Author(s): A. Omura and Y. Moritomo
  • Journal Title: Appl. Phys. Express Volume: 5 Issue: 5 Pages: 157101-157101
  • DOI: 10.1143/apex.5.057101
  • NAID: 10030593976
  • Peer Reviewed
• [Journal Article] Thin Film Electrodes of Prussian Blue Analogues with Rapid Liþ Intercalation (2012)
  • Author(s): Yutaka Moritomo, Masamitsu Takachi, Yutaro Kurihara, and Tomoyuki Matsuda
  • Journal Title: Appl. Phys. Express Volume: 5
  • Peer Reviewed
• [Journal Article] Channel Size Dependence of Li+ Insertion/Extraction in (2012)
  • Author(s): Masamitsu Takachi, Yutaro Kurihara and Yutaka Moritomo
  • Journal Title: Journal of Materials Science and Engineering Volume: 2 Pages: 45-457
  • Peer Reviewed
• [Journal Article] Thermal rectification in the vicinity of a structural phase transition (2012)
  • Author(s): W.Kobayashi, D.Sawaki, T.Omura, T, Katsufuji Y.Moritomo, I.Terasaki
  • Journal Title: Appl.Phys.Express Volume: 5 Issue: 2 Pages: 027302-027302
  • DOI: 10.1143/apex.5.027302
  • NAID: 10030156047
  • Peer Reviewed
• [Journal Article] Thin film electrode of Prussian blue analogue for Li-ion battery (2011)
  • Author(s): T. Matsuda and Y. Moritomo
  • Journal Title: Appl. Phys. Express Volume: 4 Issue: 4 Pages: 47101-47101
  • DOI: 10.1143/apex.4.047101
  • NAID: 10028210041
  • Peer Reviewed
• [Journal Article] Simultaneous Measurement of Electron and Ion Transfer in All-Solid Ion-Transfer Device Made of Transition Metal Cyanide Films (2011)
  • Author(s): Takayuki Shibata, Hayato Kamioka, Yutaka Moritomo
  • Journal Title: Jpn.J.Appl.Phys. Volume: 50 Issue: 12R Pages: 124101-124101
  • DOI: 10.1143/jjap.50.124101
  • Peer Reviewed
• [Journal Article] Cation Extraction Process in Bilayer Cyanide Film as Investigated by Depth-Resolved X-ray Absorption Spectroscopy (2011)
  • Author(s): Ayako Omura, Yutaro Kurihara, Tomoyuki Matsuda, Hajime Tanida, Tomoya Uruga, Yutaka Moritomo
  • Journal Title: Japanese Journal of Applied Physics Volume: 50 Issue: 12R Pages: 125802-125802
  • DOI: 10.1143/jjap.50.125802
  • Peer Reviewed
• [Journal Article] Cubic-rhombohedral structural phase transition in Na_<1.32>Mn[Fe(CN)_6]_<0.83>3.6H_2O (2011)
  • Author(s): Yutaka Moritomo, Tomoyuki Matsuda, Yutaro Kurihara, Jungeun Kim
  • Journal Title: Journal of the Physical Society of Japan Volume: 80 Issue: 7 Pages: 74608-74608
  • DOI: 10.1143/jpsj.80.074608
  • Peer Reviewed
• [Journal Article] Charge-Transfer State and Charge Dynamics in Poly(9,90-dioctylfluorene-co-bithiophene) and[6,6]-Phenyl C70-butyric Acid Methyl Ester Blend Film (2011)
  • Author(s): K.Yonezawa, M.Ito, H.Kamioka, T.Yasuda, L.Han, Y.Moritomo
  • Journal Title: Appl.Phys.Express Volume: 4 Issue: 12 Pages: 122601-122601
  • DOI: 10.1143/apex.4.122601
  • Peer Reviewed
• [Journal Article] Network dimensionalities and thermal expansion properties of metal nitroprussides (2011)
  • Author(s): T.Matsuda, a J.E.Kim, Y.Moritomo
  • Journal Title: RSC Advances Volume: 1 Pages: 1716-1720
  • NAID: 120007137190
  • Peer Reviewed
• [Journal Article] Fabrication of Epitaxial Interfece between Transition Metal Cyanides (2011)
  • Author(s): Yutaro Kurihara, Yutaka Moritomo
  • Journal Title: Japanese Journal of Applied Physics Volume: 50 Issue: 6R Pages: 60210-60210
  • DOI: 10.1143/jjap.50.060210
  • Peer Reviewed
• [Journal Article] Three-to-one dimensional crossover of growth mode in transition metal cyanide film (2011)
  • Author(s): Y.Moritomo, M.Ito, T.Shibata
  • Journal Title: Jpn.J.Appl.Phys Volume: 50 Issue: 8R Pages: 085602-085602
  • DOI: 10.1143/jjap.50.085602
  • NAID: 210000071035
  • Peer Reviewed
• [Journal Article] Lattice-mediated propagation of photoinduced phase transition in Co-Fe cyanide (2011)
  • Author(s): M.Ito, H.Kamioka, Y.Moritomo
  • Journal Title: J.Phys.Soc.Jpn. Volume: 80 Issue: 6 Pages: 065002-065002
  • DOI: 10.1143/jpsj.80.065002
  • NAID: 210000109063
  • Peer Reviewed
• [Journal Article] Structural Phase Diagram of Mn-Fe Cyanide against Cation Concentration (2011)
  • Author(s): Yutaka Moritomo, Yutaro Kurihara, Tomoyuki Matsuda, Jungeun Kim
  • Journal Title: Journal of the Physical Society of Japan Volume: 80 Issue: 10 Pages: 103601-103601
  • DOI: 10.1143/jpsj.80.103601
  • Peer Reviewed
• [Journal Article] Magnetic properties of valence-controlled Na_<3y-2>Cr[Cr(CN)_6]_yH_2O (2011)
  • Author(s): Y.Moritomo, K.Wakaume, Y.Kurihara, J.E.Kim
  • Journal Title: Journal of the Physical Society of Japan Volume: 80 Issue: 7 Pages: 74716-74716
  • DOI: 10.1143/jpsj.80.074716
  • Peer Reviewed
• [Journal Article] Thermal rectification in bulk materials with asymmetric shape (2011)
  • Author(s): D.Sawaki, W.Kobayashi、Y.Moritomo, I.Terasaki
  • Journal Title: Appl.Phys.Lett. Volume: 98 Issue: 8
  • DOI: 10.1063/1.3559615
  • NAID: 120007130930
  • Peer Reviewed
• [Journal Article] Anisotropic thermoelectric properties of quasi-one-dimensional SrNbO_<3.4> (d～0.03) (2011)
  • Author(s): W.Kobayashi, D. Sawaki, T.Omura, T. Katsufuji, Y.Moritomo, I.Terasaki
  • Journal Title: Phys.Rev.B Volume: 84 Issue: 8
  • DOI: 10.1103/physrevb.84.085118
  • Peer Reviewed
• [Journal Article] Extended d-Electron State of Fe(CN)6 Unit in Prussian Blue Analogue (2011)
  • Author(s): J.E.Kim, H.Tanaka, K.Kato, M., Takata, Y.Moritomo
  • Journal Title: Appl.Phys.Express Volume: 4
  • Peer Reviewed
• [Journal Article] Electric properties of all solid ion-transfer device fabricated with transition metal cyanides (2011)
  • Author(s): T.Shibata, Y Moritomo
  • Journal Title: Jpn.J.Appl.Phys. Volume: 49
  • Peer Reviewed
• [Journal Article] Oxidization process of Fe-Ni mixed Prussian blue analogue as investigated by valence-differential spectroscopy (2011)
  • Author(s): A.Omura, Y.Kurihara, M.Ishizaki, M.Kurihara, Y.Moritomo
  • Journal Title: Jpn.J.Appl.Phys. Volume: 50
  • NAID: 210000070100
  • Peer Reviewed
• [Journal Article] Symmetry switch of cobalt ferrovyanide framework by alkaline cation exchange (2010)
  • Author(s): T.Matsuda, J.E.Kim, Y.Moritomo
  • Journal Title: J.Am.Chem.Soc Volume: 132 Pages: 12206-12207
  • Peer Reviewed
• [Journal Article] Crystallization process of photoexcited high-spin sites in Co-Fe cyanide film (2010)
  • Author(s): M.Ito, H.kamioka, Y.Moritomo
  • Journal Title: J.Phys.Soc.Jpn. Volume: 80
  • NAID: 40018273841
  • Peer Reviewed
• [Journal Article] High-pressure Raman spectroscopy of transition metal cyanide (2010)
  • Author(s): Y.Moritomo, T.Matsuda, R.Fuchikawa, Y.Abe, H.Kamioka
  • Journal Title: J.Phys.Soc.Jpn. Volume: 80
  • NAID: 210000108894
  • Peer Reviewed
• [Journal Article] Electronic Structure of Hole-Doped Transition Metal Cyanidese (2010)
  • Author(s): Y.Kurihara, H, .Funashima, M Ishida, N.Hamada, T.Matsuda, K.Igarashi, H.Tanida, T.Uruga, Y.Moritomo
  • Journal Title: J.Phys.Soc.Jpn. Volume: 79
  • Peer Reviewed
• [Journal Article] Electric pressure-induced ferromagnetism mediated by Prussian blue junction (2009)
  • Author(s): Y. Moritomo and T. Shibata
  • Journal Title: Appl. Phys. Lett. Volume: 94 Issue: 4
  • DOI: 10.1063/1.3075063
• [Journal Article] Quick response of all solid electrochromic device (2009)
  • Author(s): T. Shibata and Y. Moritomo
  • Journal Title: Appl. Phys. Express Volume: 2 Issue: 10 Pages: 105502-105502
  • DOI: 10.1143/apex.2.105502
  • NAID: 10025518309
• [Journal Article] Size dependent cation cannel in Nanoporous Prrussian blue lattice (2009)
  • Author(s): Y. Moritomo, K. Igarashi, J. E. Kim and H. Tanaka
  • Journal Title: Appl. Phys. Express Volume: 2
• [Journal Article] Quick response of all solid electrochromic device (2009)
  • Author(s): T.Shibata, Y.Moritomo
  • Journal Title: Appl.Phys.Ex. 2
  • NAID: 10025518309
  • Peer Reviewed
• [Journal Article] Size dependent cation cannel in Nanoporous Prussian blue lattice (2009)
  • Author(s): Y.Moritomo, K.Igarashi, J.E.Kim, H.Tanaka
  • Journal Title: Appl.Phys.Ex. 2
  • Peer Reviewed
• [Journal Article] Valence-differential spectroscopy of Co-Fe cyanide films (2009)
  • Author(s): Y.Moritomo, F.Nakada, Y.Kurihara
  • Journal Title: Appl.Phys.Lett. 94
  • NAID: 120007138325
  • Peer Reviewed
• [Journal Article] Electric pressure-induced ferromagnetism mediated by Prussian blue junction (2009)
  • Author(s): Y.Moritomo, T.Shibata
  • Journal Title: Appl.Phys.Lett. 94
  • Peer Reviewed
• [Journal Article] Doing-induced structural transition in Na_<1.60-δ>Co[Fe(CN)_6]_<0.90> 2.9H_2O (2009)
  • Author(s): Y.Moritomo, K.Igarashi, T.Matsuda, J.E.Kim
  • Journal Title: J.Phys.Soc.Jpn. 78
  • Peer Reviewed
• [Journal Article] Oxidization/reduction process of Prussian blue film as investigated by valence-differential spectroscopy (2009)
  • Author(s): Y.Kurihara, H.Kamioka, F.Nakada, Y.Moritomo
  • Journal Title: Jpn.J.Appl.Phys. 4
  • NAID: 40016743013
  • Peer Reviewed
• [Presentation] NaxMnO2の化学ポテンシャルと構造のx依存性 (2013)
  • Author(s): 下野貴弘，小林航，守友浩
  • Organizer: 日本物理学会2012年年次大会
  • Place of Presentation: 広島
• [Presentation] Na0.7MO2の化学ポテンシャルと構造物性 (2013)
  • Author(s): 棚辺大輝，下野貴弘，小林航，浜田典昭，守友浩
  • Organizer: 日本物理学会2012年年次大会
  • Place of Presentation: 広島
• [Presentation] AxCo[Fe(CN)6]0.90(A=Li,Na)の構造物性のx依存性 (2013)
  • Author(s): 高地雅光，松田智行，守友浩
  • Organizer: 日本物理学会2012年年次大会
  • Place of Presentation: 広島
• [Presentation] LixMn[Fe(CN)6]0.81のLiインターカレーションダイナミクス (2013)
  • Author(s): 若梅一真，高地雅光，XuHao ZHU，上岡隼人，守友浩
  • Organizer: 日本物理学会2012年年次大会
  • Place of Presentation: 広島
• [Presentation] NaxCoO2薄膜の充放電特性 (2013)
  • Author(s): 柴田恭幸，小林航，守友浩
  • Organizer: 第60回応用物理学会春季学術講演会
  • Place of Presentation: 神奈川
• [Presentation] Structural properties of network-type cathode material for Li-ion battery (2012)
  • Author(s): Y, Moritomo
  • Organizer: AOFSRR2012
  • Place of Presentation: Bangkok, (Thailand)
  • Year and Date: 2012-08-10
• [Presentation] LiおよびNaイオン電池正極材料としてネットワークポリマー (2012)
  • Author(s): 守友 浩
  • Organizer: JST大学連携新技術研究会
  • Place of Presentation: 東京
  • Year and Date: 2012-07-24
• [Presentation] Ultrafast discharge in Nanoporous cathode material for Li ion battery (2012)
  • Author(s): Y. Moriotmo
  • Organizer: MOLMAT2012
  • Place of Presentation: Barcerona (Spain)
  • Year and Date: 2012-07-06
• [Presentation] Mn-Feシアノ錯体の構造と電子状態のLi濃度依存性 (2012)
  • Author(s): 松田智行, 守友浩
  • Organizer: 日本物理学会2011年次大会
  • Place of Presentation: 兵庫県西宮市関西学院大学
  • Year and Date: 2012-03-26
• [Presentation] Mn-Fe薄膜電極の充放電特性の膜厚依存性 (2012)
  • Author(s): 朱徐皓, 栗原佑太朗, 松田智行, 守友浩
  • Organizer: 日本物理学会2011年次大会
  • Place of Presentation: 兵庫県西宮市関西学院大学
  • Year and Date: 2012-03-26
• [Presentation] ポリマー型材料を用いたカラー電池 (2012)
  • Author(s): 高地雅光, 栗原佑太朗, 松田智行, 守友浩
  • Organizer: 日本物理学会2011年次大会
  • Place of Presentation: 兵庫県西宮市関西学院大学
  • Year and Date: 2012-03-26
• [Presentation] 三次元ポリマー型正極材料とその先にあるもの (2012)
  • Author(s): 守友浩
  • Organizer: 二回学振研究開発「有機物の電子物性
  • Place of Presentation: 大阪市大阪大学(招待講演)
  • Year and Date: 2012-02-18
• [Presentation] ポリマー型正極材料とその展開 (2012)
  • Author(s): 守友浩
  • Organizer: 第五回東北大G-COE研究会
  • Place of Presentation: 仙台市東北大学(招待講演)
  • Year and Date: 2012-01-22
• [Presentation] ポリマー型正極材料とその先にあるもの (2012)
  • Author(s): 守友浩
  • Organizer: 物性研研究会「エネルギー変換の物質科学」
  • Place of Presentation: 柏市東京大学物性研究所(招待講演)
  • Year and Date: 2012-01-15
• [Presentation] Photoinduced transition and other topics in PBA (2012)
  • Author(s): Y. Moriotmo
  • Organizer: PDSTM2012
  • Place of Presentation: Paris(France)
• [Presentation] sumiltaneous measurement of ps charge and latttice dynamics (2012)
  • Author(s): Y, Moritomo
  • Organizer: AsCa2012
  • Place of Presentation: アデレード（オーストラリア）
  • Invited
• [Presentation] Photoinduced transition and other topics in PBA (2012)
  • Author(s): Y. Moritomo
  • Organizer: PDSTM2012
  • Place of Presentation: パリ（フランス）
  • Invited
• [Presentation] 高容量を示すCo-Feシアノ錯体電池正極の充放電メカニズム (2012)
  • Author(s): 高地雅光，栗原佑太朗，松田智行，守友浩
  • Organizer: 日本物理学会2012年秋季大会
  • Place of Presentation: 横浜
• [Presentation] カチオン濃度制御されたMn-Feシアノ錯体薄膜電極のリチウムイオン電池特性 (2012)
  • Author(s): 栗原佑太朗，松田智行，守友浩
  • Organizer: 日本物理学会2012年秋季大会
  • Place of Presentation: 横浜
• [Presentation] 層状岩塩型酸化物のアルカリ金属インターカレーション (2012)
  • Author(s): 下野貴弘，小林航，守友浩
  • Organizer: 日本物理学会2012年秋季大会
  • Place of Presentation: 横浜
• [Presentation] プルシアンブルー類似体薄膜のイオン電池正極特性 (2012)
  • Author(s): 松田 智行・守友 浩
  • Organizer: 錯体化学会第６２回討論会
  • Place of Presentation: 富山
• [Presentation] Coordination polymer electrode for Li-ion battery cathode (2012)
  • Author(s): Tomoyuki Matsuda
  • Organizer: ICCC40
  • Place of Presentation: バレンシア（スペイン）
• [Presentation] Network polymer as cathode material of Li-ion secondary battery (2011)
  • Author(s): Y.Moritomo
  • Organizer: IC of New Science and related materials with nano spaces
  • Place of Presentation: 仙台市東北大学
  • Year and Date: 2011-11-24
• [Presentation] ポリマー型正極材料とその展開 (2011)
  • Author(s): 守友浩
  • Organizer: 第二回つくばグリーンイノベーションフォーラム
  • Place of Presentation: つくば市筑波大学(招待講演)
  • Year and Date: 2011-11-18
• [Presentation] プルシアンブルー類似体電気化学薄膜の正極特性 (2011)
  • Author(s): 松田智行, 守友浩
  • Organizer: 第52回電池討論
  • Place of Presentation: 船橋市タワーホテル船橋
  • Year and Date: 2011-10-19
• [Presentation] Mn-Feシアノ錯体薄膜の充放電特性-膜厚及びカチオン濃度依存性- (2011)
  • Author(s): 栗原佑太朗, 松田智行, 守友浩
  • Organizer: 第52回電池討論
  • Place of Presentation: 船橋市タワーホテル船橋
  • Year and Date: 2011-10-19
• [Presentation] ポリマー型正教材料と界面状態の計測 (2011)
  • Author(s): 守友浩
  • Organizer: PF研究会「磁性薄膜・多層膜を極める」
  • Place of Presentation: つくば市高エネルギー加速器研究機構(招待講演)
  • Year and Date: 2011-10-15
• [Presentation] ポリマー型リチウムイオン正極材料の中性子構造解析 (2011)
  • Author(s): 守友浩
  • Organizer: 第一回連携研究会
  • Place of Presentation: つくば市筑波大学
  • Year and Date: 2011-10-01
• [Presentation] Mn-Fe薄膜電極のLiイオン拡散係数 (2011)
  • Author(s): 柴田恭幸, 上岡隼人, 守友浩
  • Organizer: 日本物理学会2011分科会
  • Place of Presentation: 富山市富山大学
  • Year and Date: 2011-09-21
• [Presentation] プルシアンブルー類似体薄膜電極によるリチウムイオン電池特性 (2011)
  • Author(s): 松田智行, 守友浩
  • Organizer: 日本物理学会2011分科会
  • Place of Presentation: 富山市富山大学
  • Year and Date: 2011-09-21
• [Presentation] プルシアンブルー型シアノ錯体二層膜の深さ分解XAFS分光 (2011)
  • Author(s): 大村彩子, 栗原佑太朗, 松田智行, 宇留賀朋哉, 守友浩
  • Organizer: 日本物理学会2011分科会
  • Place of Presentation: 富山市富山大学
  • Year and Date: 2011-09-21
• [Presentation] Mn-Feシアノ錯体へのLi導入 (2011)
  • Author(s): 栗原佑太朗, 松田智行, 金延恩, 守友浩
  • Organizer: 日本物理学会2011分科会
  • Place of Presentation: 富山市富山大学
  • Year and Date: 2011-09-21
• [Presentation] Li intercalation and structural properties of nanoporous Prussian blue (2011)
  • Author(s): Y.Moritomo
  • Organizer: Workshop on Nanostructured Materials for Clean Energy
  • Place of Presentation: つくば市産業技術総合研究所(invited)
  • Year and Date: 2011-08-18
• [Presentation] Lattice-mediated propagation of PIPT in Co-Fe cyanide (2011)
  • Author(s): Y.Moriotmo, M. Ito, H.Kamioka
  • Organizer: PIPT2011
  • Place of Presentation: ポーランドHala stulecia
  • Year and Date: 2011-06-29
• [Presentation] Li intercalation and structure of "Prussian blue framework (2011)
  • Author(s): Y.Moritomo
  • Organizer: ICIS16
  • Place of Presentation: チェコJezerkaコングレスホテル
  • Year and Date: 2011-05-26
• [Presentation] 過渡吸収分光による有機薄膜のダイナミクスの研究 (2011)
  • Author(s): 守友浩
  • Organizer: 第6回連携研究会「有機太陽電池の基礎と応用」、KEK大学等連携支援事業
  • Place of Presentation: 筑波大学(招待講演)
• [Presentation] 錯体におけるLiドープと構造物性 (2010)
  • Author(s): 守友浩、松田智行
  • Organizer: 第4回連携研究会、KEK大学等連携支援事業
  • Place of Presentation: 筑波大学(招待講演)
  • Year and Date: 2010-11-29
• [Presentation] Fast electrochromism in all solid device made by Prussian blue analogues (2010)
  • Author(s): Y. Moriotmo
  • Organizer: IEM-9
  • Place of Presentation: Boedeaux (France)
• [Presentation] シアノ錯体薄膜のイオニクス (2010)
  • Author(s): 守友浩
  • Organizer: 第5回連携研究会「熱電変換材料と新規機能材料」、KEK大学等連携支援事業
  • Place of Presentation: 筑波大学(招待講演)
• [Presentation] ゲストーホスト相互作用系としてのシアノ錯体の構造物性の展開 (2010)
  • Author(s): 守友浩
  • Organizer: ナノテクシンポジウム、筑波大学ナノテク人材育成プログラム
  • Place of Presentation: 筑波大学(招待講演)
• [Presentation] シアノ錯体のイオン制御 (2010)
  • Author(s): 守友浩
  • Organizer: 第4回東北大COEシンポジウム、東北大COE事業
  • Place of Presentation: 東北大学(招待講演)
• [Presentation] Fast electrochromism in all solid device made by Prussian blue analogues (2010)
  • Author(s): Y.Moritomo
  • Organizer: IEM-9(第9回エレクトロクロミズム国際会議)
  • Place of Presentation: 筑波大学(招待講演)
• [Presentation] All solid electrochromic device made by Prussian blue analogues (2010)
  • Author(s): Y.Moritomo
  • Organizer: 3rd Hsinchu-Tsukuba Joint WorkshoP筑波大学戦略イニシャティブ(A)
  • Place of Presentation: 台湾、新竹(招待講演)
• [Presentation] Noble functionality of Prussian blue analogues (2010)
  • Author(s): Y.Moritomo
  • Organizer: ICSM2010(合成金属国際会議)
  • Place of Presentation: 国立京都国際会館
• [Presentation] (invited)Hole-doping and functionality of Prussian blue junction (2010)
  • Author(s): Y.Moritomo
  • Organizer: PDSTM2010
  • Place of Presentation: 筑波
• [Presentation] 価数制御された遷移金属シアノ錯体の電子構造 (2010)
  • Author(s): 栗原佑太朗, 舩島洋紀, 石田雅也, 浜田典詔, 守友浩
  • Organizer: 日本物理学会2010年年次大会
  • Place of Presentation: 岡山大学
• [Presentation] 価数差分分光によるFe-Niシアノ錯体混晶了の酸化・還元プロセス (2010)
  • Author(s): 大村彩子, 栗原佑太朗, 石崎学, 栗原正人, 守友浩
  • Organizer: 日本物理学会2010年年次大会
  • Place of Presentation: 岡山大学
• [Presentation] シアノ錯体接合体の機能性と膜形態 (2010)
  • Author(s): 柴田恭幸, 守友浩
  • Organizer: 日本物理学会2010年年次大会
  • Place of Presentation: 岡山大学
• [Presentation] プルシアンブルー類似体のカチオン応答性 (2009)
  • Author(s): 松田智行、金廷恩、大沢仁志、谷田肇、宇留賀朋哉、守友浩
  • Organizer: 第59向錯体化学討論会
  • Place of Presentation: 長崎
  • Year and Date: 2009-09-27
• [Presentation] (invited)プルシャンブルー類似体薄膜の光学スペクトル (2009)
  • Author(s): 守友浩, 栗原佑太郎
  • Organizer: 第三回学際物質研究会
  • Place of Presentation: 筑波
  • Year and Date: 2009-08-21
• [Presentation] (invited)"配列ナノ空間物質シアノ錯体の機能発現と構造物性 (2009)
  • Author(s): 守友浩
  • Organizer: 第一回連携研究会
  • Place of Presentation: 筑波
• [Presentation] (invited)プルシャンブルー格子の特異な構造応答 (2009)
  • Author(s): 守友浩
  • Organizer: 第一回連携ミニ研究会
  • Place of Presentation: 筑波
• [Presentation] (invited)XAFSを用いたナノポーラスシアノ錯体の研究 (2009)
  • Author(s): 守友浩
  • Organizer: 第三回連携ミニ研究会
  • Place of Presentation: 筑波
• [Presentation] (invited)シアノ錯体と機能化 (2009)
  • Author(s): 守友浩
  • Organizer: 第三回東北大COE研究会
  • Place of Presentation: 東北大学(仙台)
• [Presentation] XAFSを用いたナノポーラスシアノ錯体の研究 (2009)
  • Author(s): 守友浩
  • Organizer: 第12回XAFS討論会
  • Place of Presentation: 弘前
• [Presentation] カチオンに応答するCo-Feプルシャンブルー類似体の局所構造 (2009)
  • Author(s): T.Mastuda, J.E.Kim, T.Uruga, Y.Moritomo
  • Organizer: 第12回XAFS討上論
  • Place of Presentation: 弘前
• [Presentation] (invited)Advanced Functionality of Prussian blue junction" (2009)
  • Author(s): Y.Moritomo
  • Organizer: TSAMS2009
  • Place of Presentation: 筑波
• [Presentation] Co-Feシアノ錯体のカチオンの伝導経路 (2009)
  • Author(s): 守友浩, 五十嵐一泰, 金廷恩, 田中宏志
  • Organizer: 日本物理学会2009年秋季大会
  • Place of Presentation: 熊本大学
• [Presentation] シアノ錯体界面を通じたカチオン移動 (2009)
  • Author(s): 柴田恭幸, 守友浩
  • Organizer: 日本物理学会2009年秋季大会
  • Place of Presentation: 熊本大学
• [Presentation] シアノ錯体薄膜の価数差分分光 (2009)
  • Author(s): 栗原佑太朗, 上岡隼人, 守友浩
  • Organizer: 日本物理学会2009年秋季大会
  • Place of Presentation: 熊本大学
• [Presentation] プルシャンブルー格子の圧力誘起構造相転移 (2009)
  • Author(s): 松田智行、金延恩、大沢仁志、谷田肇、宇留賀朋哉、守友浩
  • Organizer: 日本物理学会2009年秋季大会
  • Place of Presentation: 熊本大学
• [Presentation] how to addphysics to green technology
  • Author(s): Y. Moritomo
  • Organizer: 4th Tsukuba-Hsinchu joint symposium
  • Place of Presentation: つくば市
  • Invited
• [Presentation] 物性物理学の視点からの電池材材料研究
  • Author(s): 守友 浩
  • Organizer: 物性物理と二次電池
  • Place of Presentation: つくば市
  • Invited
• [Presentation] Structural properties of network-type cathode material for Li-ion battery
  • Author(s): Y, Moritomo
  • Organizer: AOFSRR2012
  • Place of Presentation: バンコク（タイ）
  • Invited
• [Presentation] SR investigation of photoinduced reaction
  • Author(s): Y. Moritomo
  • Organizer: SagamoreXVII
  • Place of Presentation: 洞爺湖（北海道）
  • Invited
• [Presentation] Ultrafast discharge in Nanoporous cathode material for Li ion battery
  • Author(s): Y. Moritomo
  • Organizer: 2nd German-Japanese Workshop
  • Place of Presentation: デュイスブルク（ドイツ）
  • Invited
• [Presentation] Ultrafast discharge in Nanoporous cathode material for Li ion battery
  • Author(s): Y. Moritomo
  • Organizer: MOLMAT2012
  • Place of Presentation: バルセロナ（スペイン）
  • Invited
• [Book] ネットワークポリマー化合物を用いた薄膜型電極の開発 (2011)
  • Author(s): 守友 浩、松田智行
  • Publisher: ファインケミカル
• [Book] ネットワークポリマー型電池材料の容量増大に向けて (2011)
  • Author(s): 守友 浩、栗原佑太朗
  • Publisher: 機能材料
• [Book] リチウムイオン電池のための三次元ポリマー正極材料-カラー電池への展開ー (2011)
  • Author(s): 守友 浩
  • Publisher: MATERIAL
• [Book] 原子のジャングルジムと負の熱膨張係数 (2010)
  • Author(s): 守友 浩
  • Publisher: パリティ
• [Remarks]
  • URL: http://www.u.tsukuba.ac.jp/~moritomo.yutaka.gf/
• [Remarks] 新聞報道・等 (1) 科学新聞(2013.1.1)リチウムイオン電池に新材料:配位高分子への期待 (2) NHK茨城(2012.7.10)放射性Cs除去技術 (3) 日刊工業(2012.7.24)セシウム効率回収 (4) 日経新聞(2012、一部)放射線汚染徐染技術進む (5) 日刊工業(2012.416)10万分の1まで除去 (6) 日経産業(2012.416)セシウム高効率除去 (7) 毎日新聞(2012.3.15)リチウムイオン電池に新材料 (8) 茨城新聞(2012.3.15)リチウムイオン
• [Remarks] 守友 浩
  • URL: http://www.u.tsukuba.ac.jp/~moritomo.yutaka.gf/
• [Remarks]
  • URL: http://www.sakura.cc.tsukuba.ac.jp/~moritomo/
• [Remarks]
  • URL: http://www.sakura.cc.tsukuba.ac.jp/~moritomo/
• [Patent(Industrial Property Rights)] ナトリウムイオン電池 (2013)
  • Inventor(s): 守友 浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2013-01-25
• [Patent(Industrial Property Rights)] セシウムイオンの除去方法およびセシウムイオンの除去装置 (2012)
  • Inventor(s): 守友 浩、大村彩子
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2012-01-23
• [Patent(Industrial Property Rights)] 電極材料の製造方法、電池および電極部材 (2012)
  • Inventor(s): 守友 浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2012-07-26
• [Patent(Industrial Property Rights)] 酸化還元反応を利用した熱電変換方法および熱電変換素子 (2012)
  • Inventor(s): 守友 浩、小林航
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2012-04-05
  • Overseas
• [Patent(Industrial Property Rights)] バインダーフリー電池および電池用バインダーフリー正極部材 (2012)
  • Inventor(s): 守友 浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2012-03-01
  • Overseas
• [Patent(Industrial Property Rights)] 電極材料の製造方法、電池および電極部材 (2012)
  • Inventor(s): 守友 浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Rights Type: 特許
  • Filing Date: 2012-07-26
• [Patent(Industrial Property Rights)] 酸化還元反応を利用した熱電変換方法および熱電変換素子 (2012)
  • Inventor(s): 守友 浩、小林航
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Rights Type: 特許
  • Filing Date: 2012-04-05
  • Overseas
• [Patent(Industrial Property Rights)] セシウムイオンの除去方法およびセシウムイオンの除去装置 (2012)
  • Inventor(s): 守友浩、大村彩子
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2012-011269
  • Filing Date: 2012-01-23
• [Patent(Industrial Property Rights)] ナトリウムイオン電池 (2012)
  • Inventor(s): 守友浩、松田智
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2012-013469
  • Filing Date: 2012-01-25
• [Patent(Industrial Property Rights)] バインダーフリーなリチウムイオンカラー電池 (2011)
  • Inventor(s): 守友 浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2011-12-05
• [Patent(Industrial Property Rights)] 酸化還元反応を利用した熱電変換方法および熱電変換素子 (2011)
  • Inventor(s): 守友 浩、小林航
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2011-04-12
• [Patent(Industrial Property Rights)] バインダーフリー電池および電池用のバインダーフリー正極材料 (2011)
  • Inventor(s): 守友 浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2011-03-18
• [Patent(Industrial Property Rights)] 酸化還元反応を利用した熱電変換方法および熱電変換素子 (2011)
  • Inventor(s): 守友 浩、小林航
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2011-01-04
• [Patent(Industrial Property Rights)] 酸化還元反応を利用した熱電変換方法および熱電変換素子 (2011)
  • Inventor(s): 守友浩、小林航
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2011-088683
  • Filing Date: 2011-04-12
• [Patent(Industrial Property Rights)] バインダーフリーなリチウムイオンカラー電池(優先権主張出願) (2011)
  • Inventor(s): 守友浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2011-265920
  • Filing Date: 2011-12-05
• [Patent(Industrial Property Rights)] 酸化還元反応を利用した熱電変換方法および熱電変換素子(優先権主張出願) (2011)
  • Inventor(s): 守友浩、小林航
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2011-220060
  • Filing Date: 2011-10-04
• [Patent(Industrial Property Rights)] バインダーフリー電池および電池用のバインダーフリー正極材料 (2011)
  • Inventor(s): 守友浩、松田智行
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2011-060503
  • Acquisition Date: 2011-03-18
• [Patent(Industrial Property Rights)] シアノ架橋金属錯体作成方法およびエレクトロクロミック素子 (2010)
  • Inventor(s): 守友 浩、大塚洋一、柴田恭幸
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2010-08-22
• [Patent(Industrial Property Rights)] 不揮発性エレクトロクロミック素子およびカチオンの移動を制御する方法 (2010)
  • Inventor(s): 守友 浩、五十嵐一泰
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2010-04-30
• [Patent(Industrial Property Rights)] シアノ架橋金属錯体作成方法およびエレクトロクロミック素子 (2010)
  • Inventor(s): 守友浩、大塚洋一、柴田恭幸
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2010-180002
  • Acquisition Date: 2010-08-22
• [Patent(Industrial Property Rights)] エレクトロクロミック素子および表示装置 (2009)
  • Inventor(s): 守友 浩、柴田恭幸
  • Industrial Property Rights Holder: 筑波大学
  • Filing Date: 2009-09-01
• [Patent(Industrial Property Rights)] 不揮発性エレクトロクロミック素子およびカチオンの移動を制御する方法 (2009)
  • Inventor(s): 守友浩、五十嵐一泰
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2009-111178
  • Filing Date: 2009-04-30
• [Patent(Industrial Property Rights)] エレクトロクロミック素子および表示装置 (2009)
  • Inventor(s): 守友浩、柴田恭幸
  • Industrial Property Rights Holder: 筑波大学
  • Industrial Property Number: 2009-202058
  • Filing Date: 2009-09-01