| Budget Amount *help |
¥48,100,000 (Direct Cost: ¥37,000,000、Indirect Cost: ¥11,100,000)
Fiscal Year 2011: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2010: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2009: ¥30,290,000 (Direct Cost: ¥23,300,000、Indirect Cost: ¥6,990,000)
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| Research Abstract |
This research was undertaken aiming at the elucidation of guiding principles for constructing programmed two-dimensional molecular networks on solid surfaces and thus exploring the undeveloped field of two-dimensional crystal engineering. Through experimentations, the following unprecedented results were uncovered :(1) complex two-dimensional crystals(molecular mosaics) consisting of multiple components including the one composed by four components were achieved,(2) guiding principles for control of two-dimensional crystal structures were elucidated by constructing thermodynamic models for the control, and(3) functions of pores formed in two-dimensional crystals as molecular binding sites as well as chemical reaction sites were developed.
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