Control and Functions of Two-Dimensional Molecular Crystals at Solid Liquid Interfaces Based on Precise Molecular Design
Project/Area Number |
21245012
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | Osaka University |
Principal Investigator |
TOBE Yoshito 大阪大学, 基礎工学研究科, 教授 (60127264)
|
Co-Investigator(Kenkyū-buntansha) |
HIROSE Keiji 大阪大学, 大学院・基礎工学研究科, 准教授 (10252628)
TAHARA Kazukni 大阪大学, 大学院・基礎工学研究科, 助教 (40432463)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥48,100,000 (Direct Cost: ¥37,000,000、Indirect Cost: ¥11,100,000)
Fiscal Year 2011: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Fiscal Year 2010: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2009: ¥30,290,000 (Direct Cost: ¥23,300,000、Indirect Cost: ¥6,990,000)
|
Keywords | 2次元結晶光学 / 自己組織化 / 走査プローブ顕微鏡 / パイ共役系 / 分子認識 / 有機合成化学 / 合成化学 / 2次元結晶工学 |
Research Abstract |
This research was undertaken aiming at the elucidation of guiding principles for constructing programmed two-dimensional molecular networks on solid surfaces and thus exploring the undeveloped field of two-dimensional crystal engineering. Through experimentations, the following unprecedented results were uncovered :(1) complex two-dimensional crystals(molecular mosaics) consisting of multiple components including the one composed by four components were achieved,(2) guiding principles for control of two-dimensional crystal structures were elucidated by constructing thermodynamic models for the control, and(3) functions of pores formed in two-dimensional crystals as molecular binding sites as well as chemical reaction sites were developed.
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Report
(4 results)
Research Products
(75 results)
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[Journal Article] One Building Block, Two Different Nanoporous Self-Assembled Monolayers: a Combined STM and Monte Carlo Study2012
Author(s)
Adisoejoso, J.; Tahara, K.; Lei, S.; Szabelski, P.; Rzysko, W.; Inukai, K.; Blunt, M. O.; Tobe, Y.*; De Feyter, S.*
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Journal Title
ACS Nano.
Volume: 6
Issue: 1
Pages: 897-903
DOI
Related Report
Peer Reviewed
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[Presentation] Control and Induction of Surface Confined Homochiral Porous Molecular Networks2011
Author(s)
Tahara, Kazukuni; Yamaga, Hiroyuki; Ghijsens, Elke; Inukai, Koji; Adisoejoso, Jinne; Blunt, Matthew; De Feyter, Steven; Tobe, Yoshito
Organizer
14th International Symposium on Novel Aromatic Compounds
Place of Presentation
Eugene, Oregon, USA
Year and Date
2011-07-25
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