| Budget Amount *help |
¥48,100,000 (Direct Cost: ¥37,000,000、Indirect Cost: ¥11,100,000)
Fiscal Year 2011: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Fiscal Year 2010: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Fiscal Year 2009: ¥20,280,000 (Direct Cost: ¥15,600,000、Indirect Cost: ¥4,680,000)
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| Research Abstract |
In this project, we have planned to explore the chemistry of high valent metal hydride complexes. The use of aryloxide-derived multidentate supporting ligands allows us to isolate a variety of hydride complexes of early transition metals in high oxidation states. We found that these electron-deficient hydride complexes are capable of activating small molecules. For example, a tantalum hydride complex undergo C-O bond cleavage of CO followed by C-C and C-H bond formation, resulting in formation of an ynolate complex.
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