| Project/Area Number |
21245020
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
OKADA Tetsuo 東京工業大学, 大学院・理工学研究科, 教授 (20183030)
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| Co-Investigator(Kenkyū-buntansha) |
HARADA Makoto 東京工業大学, 大学院・理工学研究科, 助教 (60313326)
HASEGAWA Takeshi 京都大学, 化学研究所, 教授 (30258123)
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| Co-Investigator(Renkei-kenkyūsha) |
FURUKAWA Yoshinori 北海道大学, 低温科学研究所, 教授 (20113623)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥48,880,000 (Direct Cost: ¥37,600,000、Indirect Cost: ¥11,280,000)
Fiscal Year 2011: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Fiscal Year 2009: ¥29,900,000 (Direct Cost: ¥23,000,000、Indirect Cost: ¥6,900,000)
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| Keywords | 氷 / 物質分離 / 計測 / マイクロリアクタ / 共存液相 / イオンの水和 / ハイドレート / ラマン / X線吸収微細構造 / 電気化学 / キラル分離 |
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| Research Abstract |
Various analytical methods, including chromatography, microreactor etc, have been developed with ice and salt-doped ice as functional materials. We can, for example, detect 1000 magnesium ions confined in a liquid inclusion with a diameter of 1. m using salt-doped ice as a microreactor. This strongly suggests that sensitive analyses are possible with salt-doped ice as a platform for microreaction. These analytical studies have revealed that some reactions are remarkably facilitated in a liquid phase coexistent with ice. In addition, X-ray absorption fine structural analyses have revealed the difference in the hydration structure of ions between in bulk doped ice and on its surface.
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