| Budget Amount *help |
¥46,540,000 (Direct Cost: ¥35,800,000、Indirect Cost: ¥10,740,000)
Fiscal Year 2011: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
Fiscal Year 2010: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Fiscal Year 2009: ¥20,800,000 (Direct Cost: ¥16,000,000、Indirect Cost: ¥4,800,000)
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| Research Abstract |
In this research, development of transition metal-catalyzed carboxylation reactions of various hydrocarbons based on the exploitation of novel functional transition metal complexes was accomplished. It was found that 1,3-dienes undergo a smooth hydrocarboxylation reaction to give ・・・-unsaturated carboxylic acids in high yields using a PSiP pincer-type palladium complex. In addition, unique dynamic behavior of the pincer palladium complex was disclosed. Direct carboxylation of aromatic C-H bonds was also developed by using a catalytic amount of rhodium complex in the presence of methylaluminum reagent as a reductant.
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