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Multimetallic cluster complexes as well-defined nano-scale catalysts for novel organic transformations

Research Project

Project/Area Number 21245027
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionOsaka University

Principal Investigator

MASHIMA Kazushi  大阪大学, 基礎工学研究科, 教授 (70159143)

Co-Investigator(Kenkyū-buntansha) OHSHIMA Takashi  大阪大学, 基礎工学研究科, 准教授 (10313123)
Project Period (FY) 2009 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥48,490,000 (Direct Cost: ¥37,300,000、Indirect Cost: ¥11,190,000)
Fiscal Year 2012: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2011: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2009: ¥33,670,000 (Direct Cost: ¥25,900,000、Indirect Cost: ¥7,770,000)
Keywordsクラスター / ナノ触媒 / 触媒反応 / ナノ反応場 / 多核金属錯体 / アミド / エステル / エタノールアミド / アミド分解反応 / 亜鉛触媒 / 多核触媒 / クラスター触媒 / ナノ構造触媒 / 官能基変換反応 / 末端官能基化 / メタラサイクル錯体 / 炭素-水素結合活性化 / C-H結合活性化 / 環化反応 / ハフニウム錯体 / メタラサイクル / カチオン性錯体 / 2+2+1環化付加反応 / 内部アセチレン / 亜鉛 / コバルト / 4核錯体 / エステル交換反応 / 官能基選択性 / 化学選択性 / フラン環合成 / オキサゾリン合成
Research Abstract

Multimetallic cluster complexes have been extensively studied due to their applicability of proximal metal centers as a reactive site for unique organic transformations. We previously reported a tetranuclear zinc cluster catalyzed selective trans-esterification in the presence of amine functionalities, and the selectivity was opposite trend to the cluster catalyst free reaction condition. Based on the unique reactivity of the tetranuclear zinc cluster, we applied several multimetallic cluster complexes as catalysts for ester transformations. During our research, we found that the mixture of multimetallic clusters and nitrogen-based ligands led to the formation of highly reactive species after the coordination of the ligands to the cluster motif. Such enhancement effects were observed in zinc cluster catalyzed several ester transformations, and in addition, octanuclear cobalt clusters became an excellent catalyst for trans-esterification upon addition of 2,2’-bipyridine. Therefore, such cluster transformation during the catalytic reaction by using additional ligands is general strategy for showing high catalytic performance.

Report

(5 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (53 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (28 results) (of which Peer Reviewed: 28 results) Presentation (19 results) (of which Invited: 1 results) Book (1 results) Remarks (5 results)

  • [Journal Article] Enzyme-like Catalysis via Ternary-Complex Mechanism:Alkoxy-bridged Dinuclear Cobalt Complex Mediates Chemoselective O-Esterification over N-Amidation2013

    • Author(s)
      林結希子
    • Journal Title

      Journal of the American Chemical Society

      Volume: 135 Issue: 16 Pages: 6192-6199

    • DOI

      10.1021/ja400367h

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Hydrogenation of Isoquinolinium Salts Catalyzed by Chiral Iridium Complexes : Direct Synthesis for Optically Active 1, 2, 3, 4-Tetrahydroisoquinolines2012

    • Author(s)
      Atsuhiro Iimuro
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 52 Issue: 7 Pages: 2046-2050

    • DOI

      10.1002/anie.201207748

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Additive Effects of Amines on Asymmetric Hydrogenation of Quinoxalines Catalyzed by Chiral Iridium Complexes2012

    • Author(s)
      真島 和志 他5名
    • Journal Title

      Chem, Eur. J.

      Volume: 18巻 Pages: 11578-11592

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Zinc-Catalyzed Amide Cleavage and Esterification of ・-Hydroxyethylamides2012

    • Author(s)
      真島 和志 他3名
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 51巻 Issue: 23 Pages: 5723-5726

    • DOI

      10.1002/anie.201201789

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-Catalyzed Direct Amination of Allylic Alcohols with Aqueous Ammonia: Selective Synthesis of Primary Allylamines2012

    • Author(s)
      大嶋 孝志 、 真島 和志 他 4名
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 51巻 Issue: 1 Pages: 150-154

    • DOI

      10.1002/anie.201106737

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sodium Methoxide : a Simple but Highly Efficient Catalyst for the Direct Amidation of Esters2012

    • Author(s)
      大嶋孝志、林結希子、安倉和志、藤井由佳、吉山麻子、真島和志
    • Journal Title

      Chemical Communications

      Volume: (In press) Issue: 44 Pages: 5434-5436

    • DOI

      10.1039/c2cc32153j

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Cyclic Carbonate Synthesis Catalyzed by Zinc Cluster Systems under Mild Conditions2012

    • Author(s)
      Yang, Yi、林結希子、藤井由佳、長野卓人、喜多祐介、大嶋孝志、Okuda, Jun、真島和志
    • Journal Title

      Catalysis Science & Technology

      Volume: 2 Issue: 3 Pages: 509-513

    • DOI

      10.1039/c1cy00404b

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] End-functionalized Polymerization of 2-Vinylpyridine through Initial C-H Bond Activation of N-Heteroaromatics and Internal Alkynes by Yttrium Ene-diamido Complexes2011

    • Author(s)
      真島 和志 他3名
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133巻 Issue: 49 Pages: 19626-19629

    • DOI

      10.1021/ja208293h

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon Radical Generation by d^0 Tantalum Complexes with r-Diimine Ligands through Ligand-Centered Redox Processes2011

    • Author(s)
      劒隼人
    • Journal Title

      Journal of the American Chemical Society

      Volume: 133 Issue: 46 Pages: 18673-18683

    • DOI

      10.1021/ja204665s

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Additive Effect of N-Heteroaromatics on Transesterification Catalyzed by Tetranuclear Zinc Cluster2011

    • Author(s)
      前川雄亮、大嶋孝志、林結希子、安倉和志、岩崎孝紀、真島和志
    • Journal Title

      ACS Catalysis

      Volume: 1 Issue: 10 Pages: 1178-1182

    • DOI

      10.1021/cs200224b

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] C1-Symmetric Rh/Phebox-Catalyzed Asymmetric Alkynylation of α-Ketoesters2011

    • Author(s)
      大嶋 孝志 、 真島 和志 他 7名
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 50巻 Issue: 28 Pages: 6296-6300

    • DOI

      10.1002/anie.201100252

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational Synthesis of Supramolecular Assemblies Based on Tetraplatinum Units: Synthesis, Characterization, and Selective Substitution Reactions of Four Different Pt_4 Clusters2011

    • Author(s)
      真島 和志 他 5 名
    • Journal Title

      Chem. Eur. J.

      Volume: 17巻 Issue: 13 Pages: 3693-3709

    • DOI

      10.1002/chem.201002808

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxidant-Free Direct Coupling of Internal Alkynes and 2-Alkylpyridine via Double C -H Activations by Alkylhafnium Complexes2011

    • Author(s)
      真島 和志 他2名
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 133巻 Issue: 4 Pages: 732-735

    • DOI

      10.1021/ja1100118

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transesterification of α-Amino Esters Catalyzed by a Tetranuclear Zinc Cluster, Zn_4(OCOCF_3)_6O2011

    • Author(s)
      前川雄亮、安倉和志、林結希子、大嶋孝志、真島和志
    • Journal Title

      Synlett

      Volume: 23 Issue: 01 Pages: 137-141

    • DOI

      10.1055/s-0031-1290096

    • Related Report
      2012 Annual Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interaction of Ferrocene Moieties Across a Square Pt_4 Unit : Synthesis, Characterization and Electrochemical Properties of Carboxylate-Bridged Bimetallic Pt_4Fe_n (n=2, 3, and 4)Complexes2011

    • Author(s)
      Shinji Tanaka, Kazushi Mashima
    • Journal Title

      Inorg.Chem.

      Volume: 50号22卷 Issue: 22 Pages: 11384-11393

    • DOI

      10.1021/ic201012m

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reaction of Neutral and Cationic Alkyltantalum Complexes with a Linked Cyclopentadienyl-Carboranyl Ligand2011

    • Author(s)
      Hayato Tsurugi, Qiu Zaozao, Koji Yamamoto, Rocio Arteaga-Muller, Kazushi Mashima, Zuowei Xie
    • Journal Title

      Organometallics

      Volume: 30 Issue: 21 Pages: 5960-5965

    • DOI

      10.1021/om200773m

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dinuclear Molybdenum Cluster-Catalyzed Radical Addition and Polymerization Reactions by Tuning the Redox Potential of a Quadruple Bonded Mo_2 Core2011

    • Author(s)
      Hayato Tsurugi, Kazushi Mashima, ら計6名
    • Journal Title

      Dalton Trans.

      Volume: 40巻 Issue: 37 Pages: 9358-9361

    • DOI

      10.1039/c1dt11129a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct substitution of the hydroxy group with highly function alized nitrogen nucleophiles catalyzed by Au(III)2011

    • Author(s)
      Takashi Ohshima, Kazushi Mashima, ら計5名
    • Journal Title

      Chem.Commun.

      Volume: 47巻 Issue: 29 Pages: 8322-8324

    • DOI

      10.1039/c1cc12760h

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structure and DFT calculation of a hexanuclear mixed-valence copper cluster supported by 2,3-disulfidobenzoate and 3-carboxybenzene-1,2-bis(thiolate)2011

    • Author(s)
      Kuntal Pal, Satoshi Takamizawa, Kazushi Mashima
    • Journal Title

      Inorg.Chim.Acta.

      Volume: 373号1巻 Issue: 1 Pages: 68-72

    • DOI

      10.1016/j.ica.2011.03.055

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidant-Free Dehydrogenative Coupling of Internal Alkynes and 2-Alkylpyridine via Double C-H Activations by Alkylhafnium Complex2011

    • Author(s)
      H.Tsurugi, K.Yamamoto, K.Mashima
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Pages: 732-735

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Tetranuclear-Zinc-Cluster-Catalyzed Practical and Versatile Deprotection of Acetates and Benzoates2010

    • Author(s)
      大嶋 孝志、真島 和志 他4名
    • Journal Title

      Chem. Eur. J

      Volume: 16巻 Issue: 38 Pages: 11567-11571

    • DOI

      10.1002/chem.201000960

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Solvent Dependent Cis/Trans Isomerism at the Paddle-wheel Mo_2 Core of Linear Tetranuclear Clusters of Mo(II) and Cu(I) Supported by Pyphos Ligand (Pyphos = 6-Diphenylphosphino-2-pyridonato)2010

    • Author(s)
      K.Pal, K.Nakao, K.Mashima
    • Journal Title

      Eur.J.Inorg.Chem.

      Pages: 5668-5674

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Tetranuclear Zinc Cluster-Catalyzed Practical and Versatile Deprotection of Acetates and Benzoates2010

    • Author(s)
      T.Iwasaki, K.Agura, Y.Maegawa, Y.Hayashi, T.Ohshima, K.Mashima
    • Journal Title

      Chem.Eur.J

      Volume: 16 Pages: 11567-11571

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions: Ligand and Microwave Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions: Ligand and Microwave2009

    • Author(s)
      大嶋 孝志 、 真島 和志 他 4名
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131巻 Issue: 40 Pages: 14317-14328

    • DOI

      10.1021/ja9046075

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] New Tantalum Ligand-Free Catalyst System for Highly Selective Trimerization of Ethylene Affording 1-Hexene: New Evidence of a Metallacycle Mechanism2009

    • Author(s)
      真島 和志 他 5 名
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131巻 Issue: 15 Pages: 5370-5371

    • DOI

      10.1021/ja8100837

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Simple, General, and Highly Chemoselective Acetylation of Alcohols Using Ethyl Acetate as the Acetyl Donor Catalyzed by a Tetranuclear Zinc Cluster2009

    • Author(s)
      T.Ohshima, K.Mashima, (他3名)
    • Journal Title

      SynLett

      Pages: 1659-1663

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions : Ligand and Microwave Effects, Substrate Scope, and Mechanistic Study2009

    • Author(s)
      T.Ohshima, K.Mashima, (他4名)
    • Journal Title

      Journal of American Chemical Societry 131

      Pages: 14317-14328

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study of Al(III)-Catalyzed Conversion of Glyoxal to GlycolicAcid : Duall Activated 1,2-Hydride Shift Mechanizm by Protonated Al(OH)_3 Species2009

    • Author(s)
      T.Ohshima, K.Mashima, (他4名)
    • Journal Title

      Chemical Communications

      Pages: 2688-2690

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Tetrazinc Clusters as Catalysts for Chemoselective Esterification2012

    • Author(s)
      真 島 和 志
    • Organizer
      The 1st International Conference on Organometallics and Catalysis
    • Place of Presentation
      Beijin(China).
    • Year and Date
      2012-10-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Enhanced Positive Feedback in Asymmetric Hydrogenation of 2-substituted Quinoxalines by Chiral Iridium Complexes: Amine-promoted Bifunctional Mechanism2012

    • Author(s)
      真島和志
    • Organizer
      18th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Toulouse (France)
    • Year and Date
      2012-07-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Asymmetric Hydrogenation of 2-Substituted Quinoxalines by Iridium-chiral Diphosphine Catalysts2011

    • Author(s)
      Kazushi Mashima・Takuto Nagano・Atsuhiro Iimuro・Yusuke Kita
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2011
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] Salt-free Reduction of Group 5 and 6 Metal Halides for Generating Catalytically Active Species2011

    • Author(s)
      Kazushi Mashima
    • Organizer
      The 15^<th> Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry for Renewable Energy Research
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-10-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Asymmetric Hydrogenation of 2-Substituted Quinoxalines by Iridium-Chiral Diphosphine Catalysts2011

    • Author(s)
      Kazushi Mashima
    • Organizer
      4^<th> Aachen-Osaka Joint Symposium
    • Place of Presentation
      RWTH Aachen, Germany
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Salt-free Reduction of Group 5 and 6 Metal Halides for Generating Catalytically Active Species2011

    • Author(s)
      真島和志 他 3 名
    • Organizer
      19th International Symposium on Olefin Metathesis and Related Chemistry
    • Place of Presentation
      Rennes(France).
    • Year and Date
      2011-07-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Salt-free Reduction of Group 5 and 6 Metal Halides for Generating Catalytically Active Species2011

    • Author(s)
      Kazushi Mashima・Teruhiko Saito・Hiromasa Tanahashi・Hayato Tsurugi
    • Organizer
      19^<th> International Symposium on Olefin Metathesis and Related Chemistry
    • Place of Presentation
      Toulouse, France
    • Year and Date
      2011-07-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Direct Amination of Allylic Alcohols by Amines and Ammonia Catalyzed by Platinium Complexes2011

    • Author(s)
      真島和志 他4名
    • Organizer
      19th EuCheMS International Conference on Organometallic Chemistry
    • Place of Presentation
      Toulouse (France)
    • Year and Date
      2011-07-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Direct Amination of Allylic Alcohols by Amines and Ammonia Catalyzed by Platinium Complexes2011

    • Author(s)
      Kazushi Mashima・Yasuhito Nakahara・Kalupatal Das・Takashi Ohshima
    • Organizer
      19^<th> EuCheMS International Conference on Organometallic Chemistry
    • Place of Presentation
      Toulouse, France
    • Year and Date
      2011-07-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions: Ligand and Microwave Effects, Substrate Scope, and Mechanistic Study2010

    • Author(s)
      真島和志 他4名
    • Organizer
      17th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Poznan (Poland).
    • Year and Date
      2010-07-06
    • Related Report
      2012 Final Research Report
  • [Presentation] Salt-Free Methodology for Generating Low Valent Early Transition Metals As Catalysts for Selective Oligomerization and Polymerization2010

    • Author(s)
      真島和志 他 3 名
    • Organizer
      3rd Blue Sky Conference on Catalytic Olefin Polymerization
    • Place of Presentation
      Sorrento(Italy).
    • Year and Date
      2010-06-21
    • Related Report
      2012 Final Research Report
  • [Presentation] Salt-free Methodology for Generating Low Valent Early Transition Metals As Catalysts for Selective Oligomerization and Polymerization2010

    • Author(s)
      K.Mashima
    • Organizer
      3^<rd> Blue Sky Conference on Catalytic Olefin Poly merization
    • Place of Presentation
      Sorrento, Italy(招待講演)
    • Year and Date
      2010-06-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] 多核金属クラスター触媒による環境調和型直接変換反応の開発2010

    • Author(s)
      真島和志
    • Organizer
      第10回グリーン・サステイナブルケミストリー シンポジウム
    • Place of Presentation
      東京.
    • Year and Date
      2010-03-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions2009

    • Author(s)
      T.Ohshima, K.Mashima, (他4名)
    • Organizer
      International Symposium on Catalysis and Fine Cheicals
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2009-12-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Homogeneous Multi-metal Cluster Catalysis

    • Author(s)
      Kazushi Mashima
    • Organizer
      Seleca Symposium
    • Place of Presentation
      アーヘン工科大学 (ドイツ)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 亜鉛触媒による二酸化炭素とエポキシドとの交互共重合におけるウレア添加効果

    • Author(s)
      真島和志、藤井由佳、喜多祐介
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知)
    • Related Report
      2012 Annual Research Report
  • [Presentation] 亜鉛触媒を用いたアミド結合の加アルコール分解反応およびセリン選択的ペプチド結合切断反応

    • Author(s)
      西井 祐二、樋口 貴史、喜多 祐介、真島 和志
    • Organizer
      第38回反応と合成の進歩シンポジウム
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2012 Annual Research Report
  • [Presentation] コバルト触媒を用いた水酸基選択的アシル化反応の反応機構

    • Author(s)
      林結希子・大嶋孝志・真島和志
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学 びわこ・くさつキャンパス (滋賀)
    • Related Report
      2012 Annual Research Report
  • [Presentation] Zinc catalyzed amide-cleaved esterification of β-hydroxyethylamides

    • Author(s)
      Yusuke Kita・Yuji Nishii・Takafumi Higuchi・Kazushi Mashima
    • Organizer
      18th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Toulouse (France)
    • Related Report
      2012 Annual Research Report
  • [Book] Esterification in Kirk-Othmer Encyclopedia of Chemical Technology2012

    • Author(s)
      Takanori Iwasaki, Yusuke Maegawa, Takashi Ohshima, and Kazushi Mashima
    • Publisher
      Wiley
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.organomet.chem.es.osaka-u.ac.jp/

    • Related Report
      2012 Final Research Report
  • [Remarks] 真島研究室 研究内容

    • URL

      http://www.organomet.chem.es.osaka-u.ac.jp/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.organomet.chem.es.osaka-u.ac.jp/index.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.organomet.chem.es.osaka-u.ac.jp/japanese/index.htm

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.organomet.chem.es.osaka-u.ac.jp/japanese/index.htm

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2019-07-29  

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