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Development of structure inhomogeneity of metallic glasses analyzed by X-ray diffraction, inelastic X-ray scattering and viscoelatsic

Research Project

Project/Area Number 21246094
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionKyoto University

Principal Investigator

MATSUBARA Eiichiro  京都大学, 大学院・工学研究科, 教授 (90173864)

Co-Investigator(Kenkyū-buntansha) ICHITSUBO Tetsu  京都大学, 大学院・工学研究科, 准教授 (40324826)
SAIDA Junji  東北大学, 学際科学国際高等研究センター, 准教授 (20359540)
HIRATA Akihiko  東北大学, 原子分子材料化学高等研究機構, 准教授 (90350488)
YAGI Shunsuke  大阪府立大学, 21 世紀科学研究機構, 講師 (60452273)
Project Period (FY) 2009 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥40,690,000 (Direct Cost: ¥31,300,000、Indirect Cost: ¥9,390,000)
Fiscal Year 2012: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2011: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2010: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
Fiscal Year 2009: ¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Keywords拡散 / 相変態 / 状態図 / 金属ガラス / アモルファス構造 / X線回折 / 粘弾性 / アモルファス金属 / 構造緩和 / 局所構造 / フラジリティー / ガラス転移 / 構造解析
Research Abstract

We discussed their physical properties, such as the thermal stability, the structure relaxation, the glass transition and the fragility , by constructing the structural model based on the three fundamental structures, i.e. the area (P) where the local atomic arrangements are similar with those of the crystals precipitated in the amorphous matrix, the area (I) consisting of densely packed icosahedral clusters, and the area (W) belonging to neither of them.

Report

(5 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (54 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (36 results) (of which Peer Reviewed: 36 results) Presentation (8 results) (of which Invited: 1 results) Remarks (10 results)

  • [Journal Article] Primary transformation kinetics in Zr-Al-Ni-Cu-Pd bulk metallic glass correlated with relaxation, State2013

    • Author(s)
      J.Saida and A.D.Setyawan
    • Journal Title

      Met. Mater. Trans. A

      Volume: Vol.44A Issue: 5 Pages: 1998-2003

    • DOI

      10.1007/s11661-012-1321-3

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study on Correlation between Complex Relaxation Phenomena and Elastic Heterogeneity in Metallic Glasses2013

    • Author(s)
      市坪 哲、雪谷 俊介、松原 英一郎、加藤 秀実
    • Journal Title

      Journal of the Society of Materials Science, Japan

      Volume: 62 Issue: 3 Pages: 167-171

    • DOI

      10.2472/jsms.62.167

    • NAID

      130003367145

    • ISSN
      0514-5163, 1880-7488
    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of compressive deformation behavior of Zr_55Al_10Ni_5Cu_30 bulk metallic glass containing ZrC particles by synchrotron X-ray diffraction2012

    • Author(s)
      H. Suzuki, J. Saida, T. Shobu, J. Katsuyama, H. Kato, M. Imafuku and S. Sato
    • Journal Title

      Scripta Mater.

      Volume: Vol.55 Issue: 10 Pages: 801-804

    • DOI

      10.1016/j.scriptamat.2012.02.016

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Change in local environment upon quasi-crystallization of Zr-Cu glassy alloys by addition of Pd and Pt2011

    • Author(s)
      J.Saida, T.Sanada, S.Sato, M.Imafuku, M. Ohnuma, T. Ohkubo, K. Hono and E. Matsubara
    • Journal Title

      J. Phys.: Condensed Matter

      Volume: Vol.23 Issue: 17 Pages: 175303-175303

    • DOI

      10.1088/0953-8984/23/17/175303

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic structure of nanoscale quasicrystal-forming Zr-noble metal binary metallic glasses2011

    • Author(s)
      J.Saida, K.Itoh, T.Sanada, S.Sato, M.Imafuku, M. Ohnuma, and A. Inoue
    • Journal Title

      J. Alloys Compound

      Volume: Vol.509S Pages: S27-S33

    • DOI

      10.1016/j.jallcom.2010.12.076

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooling Process and Cast Structure of Zr-Al-Ni-Cu-Based Bulk Metallic Glasses Produced in Various Atmospheres2011

    • Author(s)
      J.Saida, A.D.Setyawan, H.Kato and A.Inoue
    • Journal Title

      Met. Mater. Trans. A

      Volume: Vol.42A Issue: 6 Pages: 1450-1455

    • DOI

      10.1007/s11661-010-0444-7

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of relaxation state on nucleation and grain growth of nanoscale quasicrystal in Zr-based bulk metallic glasses prepared under various cooling rates2011

    • Author(s)
      J.Saida, A.D.Setyawan and E.Matsubara
    • Journal Title

      Appl. Phys. Lett.

      Volume: Vol.99 Issue: 6

    • DOI

      10.1063/1.3622117

    • NAID

      120004920350

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Static heterogeneity in metallic glasses and its correlation to physical properties2011

    • Author(s)
      T. Ichitsubo, H. Kato, E. Matsubara, S. Biwa, S. Hosokawa, K. Matsuda, H. Uchiyama, A. Q. R. Baron
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: Vol.357 Issue: 2 Pages: 494-500

    • DOI

      10.1016/j.jnoncrysol.2010.06.056

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Static heterogeneity in metallic glasses and its correlation to physical properties2011

    • Author(s)
      Ichitsubo T, Kato H, Matsubara E, Biwa S, Hosokawa S, Matsuda K, Uchiyama H, Baron AQR
    • Journal Title

      JOURNAL OF NON-CRYSTALLINE SOLIDS

      Volume: Vol.357 Pages: 494-500

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elastic inhomogeneity and acoustic phonons in Pd-, Pt-, and Zr-based metallic glasses2010

    • Author(s)
      Ichitsubo T, Itaka W, Matsubara E, Kato H, Biwa S, Hosokawa S, Matsuda K, Saida J, Haruyama O, Yokoyama Y, Uchiyama H, Baron AQR
    • Journal Title

      PHYSICAL REVIEW B

      Volume: Vol.81 Pages: 172201-172201

    • NAID

      120002576617

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Plastic deformation by glassy structure control in Zr-Al-Ni-Cu-based BMGs2010

    • Author(s)
      J.Saida, A.D.Setyawan, H.Kato, M. Matsushita, A. Inoue
    • Journal Title

      J. Alloys and Compounds

      Volume: Vol.504 Pages: S52-S55

    • DOI

      10.1016/j.jallcom.2010.02.049

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deformation-induced structural transformation leading to compressive plasticity in Zr65Al7.5Ni10Cu12.5M5 (M=Nb, Pd) glassy alloys2010

    • Author(s)
      A.D. Setyawan, J. Saida, H. Kato, M. Matsushita, A. Inoue
    • Journal Title

      J. Materials Research

      Volume: Vol.25 Pages: 1149-1158

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Nb on transformation kinetics and mechanical properties in Zr-Al-Ni-Cu metallic glasses2010

    • Author(s)
      J . Saida, A.D. Setyawan, M. Matsushita, A. Inoue
    • Journal Title

      Mater. Trans

      Volume: Vol.51 Pages: 1188-1193

    • NAID

      10027018512

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparing the origin of ductility in the Zr-Al-Ni-Cu-M (M=Nb, Pd) metallic glasses2010

    • Author(s)
      A. D. Setyawan, J. Saida, H. Kato, M. Matsushita, A. Inoue
    • Journal Title

      Intermetallics

      Volume: Vol.18 Pages: 1884-1888

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Plastic deformation by glassy structure control in Zr-Al-Ni-Cu-based BMGs2010

    • Author(s)
      J. Saida, A.D. Setyawan, H. Kato, M. Matsushita, A. Inoue
    • Journal Title

      J. Alloys andCompounds

      Volume: Vol. 5045

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deformation-induced structural transformation leading to ductility inZr65Al7.5Ni10Cu12.5M5 (M=Nb, Pd) glassy alloys2010

    • Author(s)
      A.D. Setyawan, J. Saida, , H. Kato, M. Matsushita, A. Inoue
    • Journal Title

      J. Materials Research

      Volume: Vol.25 Issue: 6 Pages: 1149-1158

    • DOI

      10.1557/jmr.2010.0153

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Plastic deformation by glassy structure control in Zr-Al-Ni-Cu-based BMGs2010

    • Author(s)
      J.Saida, A.D.Setyawan, H.Kato, M.Matsushita, A.Inoue
    • Journal Title

      J.Alloys and Compounds

      Volume: 504 suppl.

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deformation-induced structural transformation leading to compressive plasticity in Zr65A17.5Ni10Cu12.5M5 (M=Nb, Pd) glassy alloys2010

    • Author(s)
      A.D.Setyawan, J.Saida, H.Kato, M.Matsushita, A.Inoue
    • Journal Title

      J.Materials Research

      Volume: 25 Pages: 1149-1158

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Nb on transformation kinetics and mechanical properties in Zr-Al-Ni-Cu metallic glasses2010

    • Author(s)
      J.Saida, A.D.Setyawan, M.Matsushita, A.Inoue
    • Journal Title

      Mater.Trans.

      Volume: 51 Pages: 1188-1193

    • NAID

      10027018512

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparing the origin of ductility in the Zr-Al-Ni-Cu-M (M=Nb, Pd) metallic glasses2010

    • Author(s)
      A.D.Setyawan, J.Saida, H.Kato, M.Matsushita, A.Inoue
    • Journal Title

      Intermetallics

      Volume: 18 Pages: 1884-1888

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooling process and cast structure of Zr-Al-Ni-Cu-based bulk metallic glasses produced in various atmospheres.2010

    • Author(s)
      J.Saida, A.D.Setyawan, H.Kato, A.Inoue
    • Journal Title

      Met.Mater.Trans.A

      Volume: 10(In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic structure of Zr-Cu-Al and Zr-Ni-Al amorphous alloys2010

    • Author(s)
      J.Antonowicz, DV.Louzguine-Luzgin, AR.Yavari, K.Georgarakis, M.Stoica, G.Vaughan, E.Matsubara, A.Inoue
    • Journal Title

      J. Alloys and Compunds 471

      Pages: 70-73

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Plastic deformation by glassy structure control in Zr-Al-Ni-Cu-based BMGs2010

    • Author(s)
      J.Saida, A.D.Setyawan, H.Kato, M.Matsushita, A.Inoue
    • Journal Title

      J. Alloys and Compunds (In press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deformation-induced structural transformation Ieading to ductility inZr65Al7.5Ni10Cu12.5M5 (M=Nb, Pd) glassy alloys2010

    • Author(s)
      A.D.Setyawan, J.Saida, H.Kato, M.Matsushita, A.Inoue
    • Journal Title

      J. Materials Research (In press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Proposal for the New Concept of Structures of Metallic Glasses2009

    • Author(s)
      松原英一郎
    • Journal Title

      Journal of the Japan Society of Powder and Powder Metallurgy

      Volume: 56 Issue: 11 Pages: 679-682

    • DOI

      10.2497/jjspm.56.679

    • NAID

      10026345800

    • ISSN
      0532-8799, 1880-9014
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Inhomogeneity and glass-forming ability in the bulk metallic glass Pd42.5Ni7.5Cu30P20 as seen via x-ray spectroscopies2009

    • Author(s)
      S. Hosokawa, H. Sato, T. Ichitsubo, M. Nakatake, N. Happo, JF. Berar, N. Boudet, T. Usuki, WC. Pilgrim, E. Matsubara, N. Nishiyama
    • Journal Title

      Physical Rev. B

      Volume: Vol.80 Issue: 17 Pages: 174204-174204

    • DOI

      10.1103/physrevb.80.174204

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural inhomogeneity of metallic glass observed by ultrasonic and inelastic X-ray scattering measurements2009

    • Author(s)
      T. Ichitsubo, E. Matsubara
    • Journal Title

      Mater. Sci. & Eng. A

      Volume: Vol.521, No.22 Pages: 236-242

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization Behavior and Structural Stability of Zr<SUB>50</SUB>Cu<SUB>40</SUB>Al<SUB>10</SUB> Bulk Metallic Glass2009

    • Author(s)
      S. Zhang, T. Ichitsubo, Y. Yokoyama, T. Yamamoto, E. Matsubara, A. Inoue
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 50 Issue: 6 Pages: 1340-1345

    • DOI

      10.2320/matertrans.MBW200833

    • NAID

      10024815806

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization behaviours around the glass transition temperature in an amorphous Fe-Nb-B alloy2009

    • Author(s)
      A. Hirata, Y. Hirotsu, E. Matsubara
    • Journal Title

      Intermetallics

      Volume: Vol.17 Issue: 10 Pages: 796-801

    • DOI

      10.1016/j.intermet.2009.03.007

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atomic structure of Zr-Cu-Al and Zr-Ni-Al amorphous alloys2009

    • Author(s)
      J. Antonowicz, DV. Louzguine-Luzgin, AR. Yavari, K. Georgarakis, M. Stoica, G. Vaughan, E. Matsubara, A.Inoue
    • Journal Title

      J. Alloys and Compounds

      Volume: Vol.471 Pages: 70-73

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Heating Rate Dependence of Tg and Tx in Zr-based BMGs with Characteristic Structure2009

    • Author(s)
      E. Matsubara, T. Ichitsubo, K. Itoh, T. Fukunaga, J. Saida, N. Nishiyama, H. Kato, A. Inioue
    • Journal Title

      J. Alloys and Compounds

      Volume: Vol.483 Pages: 8-13

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] 金属ガラスの構造に関する新しい概念の提案2009

    • Author(s)
      松原英一郎
    • Journal Title

      粉体および粉末冶金 56

      Pages: 679-682

    • NAID

      10026345800

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inhomogeneity and glass-forming ability in the bulk metallic glass Pd42.5Ni7.5Cu30P20 as seen via x-ray spectroscopies2009

    • Author(s)
      S.Hosokawa, H.Sato, T, Ichitsubo, M.Nakatake, N.Happo, JF.Berar, N.Boudet, T.Usuki, WC.Pilgrim, E.Matsubara, N.Nishiyama
    • Journal Title

      Physical Rev. B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural inhomogeneity of metallic glass observed by ultrasonic and inelastic X-ray scattering measurements2009

    • Author(s)
      T.Ichitsubo, E.Matsubara
    • Journal Title

      Mater. Sci. & Eng. A 521-22

      Pages: 236-242

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization Behavior and Structural Stability of Zr50Cu40Al10 Bulk Metallic Glass2009

    • Author(s)
      S.Zhang, T.Ichitsubo, Y.Yokoyama, T.Yamamoto, E.Matsubara, A.Inoue
    • Journal Title

      Mater. Trans. 50

      Pages: 1340-1345

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization behaviours around the glass transition temperature in an amorphous Fe-Nb-B alloy2009

    • Author(s)
      A.Hirata, Y.Hirotsu, E.Matsubara
    • Journal Title

      Intermetallics 17

      Pages: 796-801

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Preparation and transformation behaviors of relaxation-controlled Zr-based metallic glasses2012

    • Author(s)
      J. Saida, A.D. Setyawan, H. Kato and M. Wakeda
    • Organizer
      IUMRS International Conference in Asia 2012(招待講演)
    • Place of Presentation
      Pusan(Korea)
    • Related Report
      2012 Final Research Report
  • [Presentation] Preparation and transformation behaviors of relaxation-controlled Zr-based metallic glasses2012

    • Author(s)
      J. Saida, A.D. Setyawan, H. Kato and M. Wakeda
    • Organizer
      IUMRS International Conference in Asia 2012
    • Place of Presentation
      Pusan(Korea)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] コヒーレント回折による金属ガラス構造緩和の実験的測定2010

    • Author(s)
      松原英一郎
    • Organizer
      第54回日本学術会議材料工学連合講演会
    • Place of Presentation
      ハートピア京都
    • Year and Date
      2010-10-26
    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Presentation] フェイズフィールド法による金属ガラスのドメイン形成シミュレーション2009

    • Author(s)
      劉 斐、市坪 哲、松原 英一郎
    • Organizer
      日本鉄鋼協会・日本金属学会 関西支部, 材料物性工学談話会
    • Place of Presentation
      大阪大学
    • Year and Date
      2009-12-18
    • Related Report
      2012 Final Research Report
  • [Presentation] フェイズフィールド法による金属ガラスのドメイン形成シミュレーション2009

    • Author(s)
      劉斐、市坪哲、松原英一郎
    • Organizer
      (社)日本鉄鋼協会・(社)日本金属学会関西支部材料物性工学談話会
    • Place of Presentation
      大阪大学
    • Year and Date
      2009-12-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属ガラスの特徴的構造2009

    • Author(s)
      松原英一郎、渋谷陽二、東 健司
    • Organizer
      第53回日本学術会議材料工学連合講演会
    • Place of Presentation
      京大会館
    • Year and Date
      2009-10-20
    • Related Report
      2012 Final Research Report 2009 Annual Research Report
  • [Presentation] X線非弾性散乱を用いた過冷却状態におけるアモルファス金属の緩和現象2009

    • Author(s)
      雪谷俊介、位高渉、市坪哲、松原英一郎
    • Organizer
      第53回日本学術会議材料工学連合講演会
    • Place of Presentation
      京大会館
    • Year and Date
      2009-10-20
    • Related Report
      2012 Final Research Report 2009 Annual Research Report
  • [Presentation] 急速加熱・冷却によりZr基金属ガラス中に析出するB2相とC11b相の格子定数2009

    • Author(s)
      山本篤史郎、横山嘉彦、市坪哲、木村久道、松原英一郎、井上明久
    • Organizer
      (社)日本金属学会秋期大会
    • Place of Presentation
      京都大学
    • Year and Date
      2009-09-16
    • Related Report
      2012 Final Research Report 2009 Annual Research Report
  • [Remarks] 京都大学教育研究活動データベース

    • URL

      https://www.tam2.adm.kyoto-u.ac.jp/kyouindb/j/fW3bV

    • Related Report
      2012 Final Research Report
  • [Remarks] 市坪哲のページ

    • URL

      https://www.tam2.adm.kyoto-u.ac.jp/kyouindb/j/fW3bV

    • Related Report
      2012 Final Research Report
  • [Remarks] 研究者紹介

    • URL

      http://db.tohoku.ac.jp/whois/detail/5b425fc3f01f3154b0fb2ff3184a4800.html

    • Related Report
      2012 Final Research Report
  • [Remarks] 研究者詳細AIMR

    • Related Report
      2012 Final Research Report
  • [Remarks] 京都大学教育研究活動データベース

    • URL

      https://www.tam2.adm.kyoto-u.ac.jp/kyouindb/j/fW3bV

    • Related Report
      2012 Annual Research Report
  • [Remarks] 市坪哲のページ

    • URL

      https://www.tam2.adm.kyoto-u.ac.jp/kyouindb/j/fW3bV

    • Related Report
      2012 Annual Research Report
  • [Remarks] 研究者紹介

    • URL

      http://db.tohoku.ac.jp/whois/detail/5b425fc3f01f3154b0fb2ff3184a4800.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] 研究者詳細AIMR

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/jp/research/researcher/a-hirata.html

    • Related Report
      2012 Annual Research Report
  • [Remarks] yagi laboratory

    • URL

      http://www.nanosq.21c.osakafu-u.ac.jp/ttsl_lab/s_yagi/

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://www.mdsgn.mtl.kyoto-u.ac.jp/page3.html

    • Related Report
      2011 Annual Research Report

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Published: 2009-04-01   Modified: 2019-07-29  

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