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Key Role of Pore Volume of Zeolite for Selective Production of Propylene from Olefins

Research Project

Project/Area Number 21246120
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionTokyo Institute of Technology

Principal Investigator

BABA Toshihide  東京工業大学, 大学院・総合理工学研究科, 教授 (50165057)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥47,190,000 (Direct Cost: ¥36,300,000、Indirect Cost: ¥10,890,000)
Fiscal Year 2011: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2010: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2009: ¥30,030,000 (Direct Cost: ¥23,100,000、Indirect Cost: ¥6,930,000)
Keywords触媒反応 / 触媒 / プロピレン合成 / ゼオライト / オレフィン / 反応機構 / プロピレン / β切断 / 細孔空洞容積 / 細孔入り口径 / エチレン / ブテン / オクテン
Research Abstract

A plausible reaction mechanism for propylene (C_3H_6) production from ethylene (C_2H_4) was investigated, based on the amounts of effluent hydrocarbons and hydrocarbons produced in the pores of various zeolites. Propylene was produced via an oligomerization-cracking mechanism. On the basis of this mechanism, the conversions of C_2H_4, pentenes, and hexenes were examined. The catalytic performance was compared, in order to investigate the role of the pore volume of zeolites with 8-, 10-, and 12-membered rings in the selective production of C_3H_6 . The selectivity for C_3 H_6 was crucially dependent upon the pore volume of the zeolite. Highly selective production of C_3H_6 from olefins (C_2H_4 , pentenes, and hexenes) can be accomplished by employing a new concept: adjusting the pore volume of a zeolite to accommodate the volume of an olefin and/or its carbenium cations, as opposed to a conventional molecular sieve approach. For example, an unimolecular cracking of pentenes into C_3 H_6 and C_2 H_4 involving primary cations can be controlled by the pore volume of a zeolite.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (31 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (20 results) (of which Peer Reviewed: 12 results) Presentation (9 results) Book (2 results)

  • [Journal Article] Selective production of ethylene andpropylene via monomolecular cracking of pentene over proton-exchanged zeolitesy cations can be controlled by the pore volume of a zeolite.2013

    • Author(s)
      Yasuharu Sakamoto, Yasuyoshi Iwase, Tatsuaki Yashima, Ryutaro Koide, Ken Motokura
    • Journal Title

      Toshihide Baba*Journal of Catalysis

      Volume: 302 Pages: 101-114

    • Related Report
      2011 Final Research Report
  • [Journal Article] Proton exchange reaction between hydroxyl groups in the supercage and those in the sodalitecage of Y zeolite as studied by variabletemperature 1^H MAS NMR2012

    • Author(s)
      Naoki Asakawa, Ken Motokura, Tatsuaki Yashima, To-ru Koyama
    • Journal Title

      Toshinori O-nuki, Akimitsu Miyaji, Toshihide Baba*The Journal of Physical Chemistry C

      Volume: 116 Pages: 17734-17738

    • Related Report
      2011 Final Research Report
  • [Journal Article] Temperature effect on 1H chemical shift of hydroxyl groups in zeolites and their catalytic activities as solid acidsHajime Munakata2012

    • Author(s)
      To-ru Koyama, Tatsuaki Yashima, Naoki Asakawa, Toshinori O-nuki, Ken Motokura, Akimitsu Miyaji
    • Journal Title

      Toshihide Baba*The Journal of Physical Chemistry C

      Volume: 116 Pages: 14551-14560

    • Related Report
      2011 Final Research Report
  • [Journal Article] Shape-selective catalysis determined by the volume of a zeolite cavity and the reaction mechanism for propylene production by the conversion of butene using a proton-exchanged zeoliteYasuyoshi Iwase, Yasuharu Sakamoto2012

    • Author(s)
      Akinobu Shiga, Akimitsu Miyaji, Ken Motokura, To-ru Koyama
    • Journal Title

      Toshihide Baba*The Journal of Physical Chemistry C

      Volume: 116 Pages: 5182-5196

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of morphology and particle size of ZSM-5 on catalytic performance for ethylene conversion and heptane crackingKrishna Reddy Jakkidi2012

    • Author(s)
      Ken Motokura, To-ru Koyama, Akimitsu Miyaji
    • Journal Title

      Toshihide Baba* Journal of Catalysis

      Volume: 289 Pages: 53-61

    • Related Report
      2011 Final Research Report
  • [Journal Article] Shape-Selective Catalysis Determined by the Volume of a Zeolite Cavityand the Reaction Mechanism for Propylene Production by the Conversionof Butene Using a Proton-Exchanged Zeolite2012

    • Author(s)
      Yasuyoshi Iwase, Yasuharu Sakamoto, Akinobu Shiga, Akimitsu Miyaji, Ken Motokura, To-ru Koyama, Toshihide Baba
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 116 Issue: 8 Pages: 5182-5196

    • DOI

      10.1021/jp212549j

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of morphology and particle size of ZSM-5 on catalytic performance for ethylene conversion and heptane cracking2012

    • Author(s)
      Krishna Reddy Jakkidi, Ken Motokura, To-ru Koyama, Akimitsu Miyaji, and Toshihide Baba*
    • Journal Title

      Journal of Catalysis

      Volume: 289 Pages: 53-61

    • DOI

      10.1016/j.jcat.2012.01.014

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Key role of the pore volume of zeolite for selective production of propylene from olefins2010

    • Author(s)
      To-ru Koyama, Yoshihiro Hayashi, Hironori Horie, Susumu Kawauchi, Akihiko, Matsumoto,Yasuyoshi Iwase, Yasuharu Sakamoto, AkimitsuMiyaji, Ken Motokura, Baba
    • Journal Title

      Toshihide*Phys. Chem. Chem. Phys

      Volume: 12 Pages: 2541-2554

    • NAID

      10026055555

    • Related Report
      2011 Final Research Report
  • [Journal Article] Key role of the pore volume of zeolite for selective production of propylene from olefins2010

    • Author(s)
      Koyama, To-ru, Hayashi, Yoshihiro, Horie, Hironori, Kawauchi, Susumu, Matsumoto, Akihiko, Iwase, Yasuyoshi, Sakamoto, Yasuharu, Miyaji, Akimitsu, Motokura, Ken, Baba, Toshihide
    • Journal Title

      Phys.Chem.Chem.Phys.

      Volume: 12 Pages: 2541-2554

    • NAID

      10026055555

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Changes in concentration levels of polycyclic aromatic compounds associated with airborne particulate matter in downtown Tokyo after introducing government diesel vehicle controls2010

    • Author(s)
      Yuki Kojima, Koji Inazu, Yoshiharu Hisamatsu, Hiroshi Okochi, Toshihide, Baba, Toshio Nagoya
    • Journal Title

      Asian Journal of Atmospheric Environment

      Volume: 4 Pages: 1-8

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of secondary formation on atmospheric occurrences of oxygenated polycyclic aromatic hydrocarbons in airborne particles2010

    • Author(s)
      Yuki Kojima, Koji Inazu, Yoshiharu Hisamatsu, Hiroshi Okochi, Toshihide, Baba, Toshio Nagoya
    • Journal Title

      Atmospheric Environment

      Volume: 44 Pages: 2873-2880

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of PAHs, nitro-PAHs and oxy-PAHs associated with airborne particulate matter at roadside and urban background sites in downtown Tokyo, Japan2010

    • Author(s)
      Yuki Kojima, Koji Inazu, Yoshiharu Hisamatsu, Hiroshi Okochi, Toshihide, Baba, Toshio Nagoya
    • Journal Title

      Polycyclic Aromatic Compounds

      Volume: 30 Pages: 321-333

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic ring-opening allylation of cyclic acetals with allylsilanes using silica-alumina2010

    • Author(s)
      Motokura, Ken, Yoneda, Hirokazu, Miyaji, Akimitsu, Baba, Toshihide
    • Journal Title

      Green Chemistry

      Volume: 12 Pages: 1373-1375

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inverse electron demand asymmetric cycloadditions of cyclic carbonyl ylides catalyzed by chiral Lewis acids-Scope and limitations of diazo and olefinic substrates2010

    • Author(s)
      Suga, Hiroyuki, Higuchi, Satoshi, Ohtsuka, Motoo, Ishimoto, Daisuke, Arikawa, Tadashi, Hashimoto, Yuta, Misawa, Shunta, Tsuchida, Teruko, Kakehi, Akikazu, Baba, Toshihide
    • Journal Title

      Tetrahedron

      Volume: 66 Pages: 3070-3089

    • NAID

      120007104986

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heterogeneous Allylsilylation of Aromatic and Aliphatic Alkenes Catalyzed by Proton-Exchanged Montmorillonite2010

    • Author(s)
      Motokura, Ken, Matsunaga, Shigekazu, Miyaji, Akimitsu, Sakamoto, Yasuharu, Baba, Toshihide
    • Journal Title

      Organic Letters

      Volume: 12 Pages: 1508-1511

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] バイオマス燃料はエネルギー問題を救うか バイオマス燃料に期待されている新しい固体触媒の開発2010

    • Author(s)
      馬場俊秀, 宮地輝光
    • Journal Title

      化学

      Volume: 65 Pages: 47-49

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Influence of Si distribution in framework of SAPO-34 and its particle size on propylene selectivity and production rate for conversion of ethylene to propylene2009

    • Author(s)
      Yasuyoshi IwaseKen Motokura, To-ru Koyamaya, Akimitsu Miyaji
    • Journal Title

      Toshihide Baba* Phys. Chem. Chem. Phys.

      Volume: 11 Pages: 9268-9277

    • Related Report
      2011 Final Research Report
  • [Journal Article] Influence of Si Distribution in Framework of SAPO-34 and Its Particle Size on Propylene Selectivity and production rate for Conversion of Ethylene to Propylene2009

    • Author(s)
      Yasuyoshi Iwase, Ken Motokura, To-ru Koyamaya, Akimitsu Miyaji, Toshihide Baba
    • Journal Title

      Phys.Chem.Chem.Phys. 11

      Pages: 9268-9277

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stability of Silver Cluster in Zeolite A and Y Catalysts2009

    • Author(s)
      Yamamoto Takashi, Takenaka Sakae, Tanaka Tsunehiro, Toshihdie Baba.
    • Journal Title

      J.Phys. 190

      Pages: 1271-1276

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of Sulfo-functionalized Mesoporous Silica with Strong Acidityi by Temperature-controlled Calcination2009

    • Author(s)
      Fei-Yee Yeoh, Akihiko Matsumoto, Toshihide Baba
    • Journal Title

      J.Porous.Mater 16

      Pages: 283-289

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] production by the conversion of lower olefins using a H^+-exchanged zeolite2012

    • Author(s)
      Yasuyoshi Iwase, Akimitsu Miyaji, Ken Motokura To-ru Koyama Toshihide Baba
    • Place of Presentation
      ZMPC, Hiroshima
    • Year and Date
      2012-07-30
    • Related Report
      2011 Final Research Report
  • [Presentation] Crucial role of volume of zeolite cavity for selective production of propylene from lower olefins2012

    • Author(s)
      Yasuyoshi Iwase, To-ru Koyama, Akimitsu Miyaji, Ken Motokura,Toshihide Baba
    • Place of Presentation
      ICC, Germany
    • Year and Date
      2012-07-04
    • Related Report
      2011 Final Research Report
  • [Presentation] エチレン,ブテンからの選択的プロピレン生成に果たすゼオライト細孔構造の役割とその生成機構2012

    • Author(s)
      岩瀬安慶,坂本康治,志賀昭信,小山徹,宮地輝光,本倉健,馬場俊秀
    • Organizer
      触媒討論会B
    • Place of Presentation
      東京
    • Year and Date
      2012-03-29
    • Related Report
      2011 Final Research Report
  • [Presentation] Crucial role of volume of zeolite cavity for selective production of propylene from lower olefins2011

    • Author(s)
      Yasuyoshi Iwase, To-ru Koyama, Hajime Munakata, Akimitsu Miyaji, Ken Motokura, Toshihide Baba
    • Place of Presentation
      IZA, Italy
    • Year and Date
      2011-09-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Selective production propylene from olefins over zeolites2010

    • Author(s)
      Yasuyoshi Iwase, Akimitsu Miyaji, Ken Motokura, To-ru Koyama, Toshihide Baba
    • Organizer
      North American Meeting
    • Place of Presentation
      Detroit
    • Year and Date
      2010-06-09
    • Related Report
      2011 Final Research Report
  • [Presentation] オレフィンからの選択的プロピレン合成に果たすゼオライト細孔の役割2010

    • Author(s)
      岩瀬安慶,小山徹,宮地輝光,本倉健,馬場俊秀
    • Organizer
      触媒討論会B
    • Place of Presentation
      京都
    • Year and Date
      2010-03-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Key pore structure of zeolite for selective production of C_3H_6 from C_2H_42009

    • Author(s)
      Yasuyoshi Iwase, To-ru Koyama, Akimitsu Miyaji, Ken Motokura, Toshihide Baba
    • Organizer
      MRS Meeting
    • Place of Presentation
      Boston
    • Year and Date
      2009-11-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Key Catalysis of Metal Cation-exchanged ZSM-5 Zeolites for Conversion of CH_4 in the Presence of C_2H_42009

    • Author(s)
      Toshihide Baba, Koji Inazu
    • Organizer
      ACS Meeting
    • Place of Presentation
      Salt Lake
    • Year and Date
      2009-03-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] エチレン,ブテンからの選択的プロピレン生成に果たすゼオライト細孔構造の役割とその生成機構

    • Author(s)
      岩瀬安慶,坂本康治,志賀昭信,小山 徹,宮地輝光,本倉 健,馬場俊秀
    • Organizer
      触媒討論会 B
    • Place of Presentation
      東京工業大学
    • Related Report
      2011 Annual Research Report
  • [Book] SAPO-34を触媒とするエチレンまたはエタノールからの選択的プロピレン合成2010

    • Author(s)
      馬場俊秀, 稲津晃司, 小山徹(分担)
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Annual Research Report
  • [Book] エネルギー触媒技術 軽油系バイオマス燃料2010

    • Author(s)
      馬場俊秀 (分担)
    • Publisher
      サイエンス&テクノロジー
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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