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Study on the Green Energy Ironmaking by utilization of hydrogen

Research Project

Project/Area Number 21310061
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionKyoto University

Principal Investigator

KASHIWAYA Yoshiaki  京都大学, 大学院・エネルギー科学研究, 准教授 (10169435)

Co-Investigator(Kenkyū-buntansha) KINOSHITA Hirosi  北海道大学, 大学院・工学研究科, 助教 (40177895)
NOGAMI Hirosi  室蘭工業大学, 大学院・工学研究科, 教授 (50241584)
AKIYAMA Tomohiro  北海道大学, 大学院・工学研究科, 教授 (50175808)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2011: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2010: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2009: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Keywordsグリーンケミスト / 水素製鉄 / CO2削減 / 水素 / グリーンエネルギー
Research Abstract

The utilization of Green Hydrogen in the ironmaking and steelmaking process is to contribute to the reduction of CO2 emission in Japan. In this study, the main purposes are to clarify the possibilities for two cases, the first case is the use of hydrogen in the present blast furnace processes, and the second case is the future hydrogen furnace without coke.
The mathematical model of the blast furnace was developed for clarifying the effect of hydrogen. Using this simulation model, it was found that the limit of hydrogen injection into blast furnace was about 40%. The hydrogen gas system can inject a larger amount of gas which is important factor for increasing the productivity.
The metallic iron obtained by hydrogen reduction is close to a pure iron with low inclusions, which is predicted by thermodynamic analysis. The experiment was performed to clarify the result of thermodynamics. It was confirmed that high purity iron was obtained.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (45 results)

All 2012 2011 2010 2009 Other

All Journal Article (37 results) (of which Peer Reviewed: 17 results) Presentation (8 results)

  • [Journal Article] Preface to the Special Issue on Green Energy Iron making and Steelmaking-Production of Green Energy and Its Use in Iron making and Steelmaking-2012

    • Author(s)
      Y. Kashiwaya
    • Journal Title

      ISIJ International

      Volume: Vol.52, No.8

    • Related Report
      2011 Final Research Report
  • [Journal Article] Kinetic analysis of the decomposition reaction of CH4 injecting into molten slag2012

    • Author(s)
      Y. Kashiwaya, M. Watanabe
    • Journal Title

      ISIJ International

      Volume: Vol.52, No.8

    • Related Report
      2011 Final Research Report
  • [Journal Article] Nano-structure of Carbons deposited from CH_4 blowing to and injecting into molten slag2012

    • Author(s)
      Y. Kashiwaya, M. Watanabe
    • Journal Title

      ISIJ International

      Volume: Vol.52, No.8

    • NAID

      10031146425

    • Related Report
      2011 Final Research Report
  • [Journal Article] Thermodynamics of impurities in pure iron obtained by hydrogen reduction2012

    • Author(s)
      Y. Kashiwaya, H. Hasegawa
    • Journal Title

      ISIJ International

      Volume: Vol.52, No.8

    • NAID

      130003395101

    • Related Report
      2011 Final Research Report
  • [Journal Article] Simulation of Blast Furnace Operation with Intensive Hydrogen Injection2012

    • Author(s)
      H. Nogami, Y. Kashiwaya, D. Yamada
    • Journal Title

      ISIJ International

      Volume: Vol.52, No.8

    • NAID

      10031146441

    • Related Report
      2011 Final Research Report
  • [Journal Article] Preface to the Special Issue on "Green Energy Ironmaking and Steelmaking-Production of Green Energy and Its Use in Ironmaking and Steelmaking2012

    • Author(s)
      Y.Kashiwaya
    • Journal Title

      ISIJ International

      Volume: 52(accepted)

    • NAID

      10031146421

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetic analysis of the decomposition reaction of CH4 injecting into molten slag2012

    • Author(s)
      Y.Kashiwaya, M.Watanabe
    • Journal Title

      ISIJ International

      Volume: 52(accepted) Pages: 4-4

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nano-structure of Carbons deposited from CH4 blowing to and injecting into molten slag2012

    • Author(s)
      Y.Kashiwaya, M.Watanabe
    • Journal Title

      ISIJ International

      Volume: 52(accepted)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynaniics of impurities in pure iron obtained by hydrogen reduction2012

    • Author(s)
      Y.Kashiwaya, M.Hasegawa
    • Journal Title

      ISIJ International

      Volume: 52(accepted)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simulation of Blast Furnace Operation with Intensive Hydrogen Injection2012

    • Author(s)
      H.Nogami, Y.Kashiwaya, D.Yamada
    • Journal Title

      ISIJ International

      Volume: 52(accepted)

    • NAID

      10031146441

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic Properties of SoIid Solutions between Di-calcium Silicate and Tri-calcium Phosphate2012

    • Author(s)
      M.Hasegawa, Y.Kashiwaya, M.Iwase
    • Journal Title

      International Journal of High Temperature Materials and Processes

      Volume: 31(accepted)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of wood biomass addition on the char making process of waste plastic for controlling the combustion efficiency2012

    • Author(s)
      Y.Ito, M.Hasegawa, T.Kashiwaya, M.Iwase
    • Journal Title

      International Journal of High Temperature Materials and Processes

      Volume: 31(accepted)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Iron making With Ammonia at Low Temperature2011

    • Author(s)
      S. Hosokai, Y. Kashiwaya, K. Matsui, N. Okinaka, T. Akiyama
    • Journal Title

      Environmental Science & Technology

      Volume: 45(2) Pages: 821-826

    • Related Report
      2011 Final Research Report
  • [Journal Article] Binding energy of carbon implanted into hematite and in situ observation of reaction behavior during heating up experiment2011

    • Author(s)
      Y. Kashiwaya, T. Nakamitsu, H. Kinoshita, S. Miura
    • Journal Title

      ISIJ International

      Volume: Vol.51, No.8 Pages: 1204-1212

    • NAID

      130000968573

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of oxides and carbonate on the reaction of hematite and graphite mixture obtained by the mechanical milling2011

    • Author(s)
      Y. Kashiwaya, R. Suzuki and K. Ishii
    • Journal Title

      ISIJ International

      Volume: Vol.51, No.8 Pages: 1213-1219

    • NAID

      130000968574

    • Related Report
      2011 Final Research Report
  • [Journal Article] Atmosphere controlled hot thermocouple method and crystallization, phenomenon of CaO-Al2O3 eutectic slag2011

    • Author(s)
      Y. Kashiwaya, Y. Kusada, R. Suzuki
    • Journal Title

      ISIJ International

      Volume: Vol.51, No.12 Pages: 1966-1972

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of sulfur on the TTT diagram of CaO-Al2O3 slag at eutectic composition2011

    • Author(s)
      Y. Kashiwaya, Y. Kusada, R. Suzuki
    • Journal Title

      ISIJ International

      Volume: Vol.51, No.12 Pages: 1973-1980

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of sulfur on the TTT diagram of CaO-Al2O3 slag at eutectic composition2011

    • Author(s)
      Y.Tashiwaya, Y.Kusada, R.Suzuki
    • Journal Title

      ISIJ International

      Volume: 51 Pages: 1973-1980

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atmosphere controlled hot thermocouple method and crystallization phenomenon of CaO-Al2O3 eutectic slag2011

    • Author(s)
      Y.Kashiwaya, Y.Kusada, R.Suzuki
    • Journal Title

      ISIJ International

      Volume: 51 Pages: 1966-1972

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ETTect of oxides ana carbonate on the reaction of hematite and graphite mixture obtained by the mechanical milling2011

    • Author(s)
      Y.Kashiwaya, R.Suzuki, K.Ishii
    • Journal Title

      ISIJ International

      Volume: 51 Pages: 1213-1219

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Binding energy of carbon implanted into hematite and in situ observation of reaction behavior during heating up experiment2011

    • Author(s)
      Y.Kashiwaya, T.Nakamitsu, H.Kinoshita, S.Miura
    • Journal Title

      ISIJ International

      Volume: 51 Pages: 1204-1212

    • NAID

      130000968573

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ironmaking with Ammonia at Low Temperature2011

    • Author(s)
      Y.kashiwaya, T.Nakamitsu, H.Kinoshita S.Miura
    • Journal Title

      Environmental Science & Technology

      Volume: 45 Pages: 821-826

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reaction behavior of coke with iron oxide catalyst2010

    • Author(s)
      Y. Yamamoto, Y. Kashiwaya, S. Miura, M. Nishimura, K. Kato, S. Nomura, M. Kubota, K. Kunitomo and M. Naito
    • Journal Title

      Tetsu-to-Hagane

      Volume: vol.96, No.5 Pages: 288-296

    • NAID

      130000259060

    • Related Report
      2011 Final Research Report
  • [Journal Article] In situ observation and reaction mechanism of iron oxide catalyst added to coke2010

    • Author(s)
      Y. Yamamoto, Y. Kashiwaya, S. Miura, M. Nishimura, K. Kato, S. Nomura, M. Kubota, K. Kunitomo and M. Naito
    • Journal Title

      Tetsu-to-Hagane

      Volume: vol.96, No.5 Pages: 297-304

    • NAID

      130000259061

    • Related Report
      2011 Final Research Report
  • [Journal Article] Formation Free Energies of Solid Solution between Tri-Calcium Phosphate and Di-Calcium Silicate2010

    • Author(s)
      M. Hasegawa, Y. Kashiwaya and M. Iwase
    • Journal Title

      Steel research int

      Volume: No.2 Pages: 100-104

    • Related Report
      2011 Final Research Report
  • [Journal Article] Activities of FexO in CaO-(Na2O) 0. 1875(K2O) 0. 0625(Al2O3) 0. 25(SiO2) 0. 5-FexO Pseudo-Ternary Slags2010

    • Author(s)
      H. Ozawa, H. Hasegawa, Y. Kashiwaya, M. Iwase
    • Journal Title

      Steel research International

      Volume: vol.81, No.1 Pages: 25-30

    • Related Report
      2011 Final Research Report
  • [Journal Article] Interaction parameter eOC for carbon-saturated liquid iron between 1623K and 1723 K2010

    • Author(s)
      Y. Kashiwaya, M. Hasegawa, H. Niitani, T. Kakinuma and M. Iwase
    • Journal Title

      Steel research International

      Volume: vol.81, No.5 Pages: 333-336

    • Related Report
      2011 Final Research Report
  • [Journal Article] Development of a rotary cylinder atomizing method of slag for the production of amorphous slag particles2010

    • Author(s)
      Y. Kashiwaya, Y. In-nami and T. Akiyama
    • Journal Title

      ISIJ International

      Volume: Vol.50, No9 Pages: 1245-1251

    • NAID

      10028113688

    • Related Report
      2011 Final Research Report
  • [Journal Article] Mechanism of the formation of slag particles by the rotary cylinder atomization2010

    • Author(s)
      Y. Kashiwaya, Y. In-nami and T. Akiyama
    • Journal Title

      ISIJ International

      Volume: Vol.50, No9 Pages: 1252-1258

    • NAID

      10028113698

    • Related Report
      2011 Final Research Report
  • [Journal Article] Latent heat of amorphous slags and the utilization as a high temperature PCM2010

    • Author(s)
      Y. Kashiwaya, T. Akiyama and Y. In-nami
    • Journal Title

      ISIJ International

      Volume: Vol.50, No9 Pages: 1259-1264

    • Related Report
      2011 Final Research Report
  • [Journal Article] Nan crack formation in hematite through the dehydration of goethite and the carbon infiltration from biotar2010

    • Author(s)
      Y. Kashiwaya and T. Akiyama
    • Journal Title

      J. Nanomaterials

      Volume: vol.2010 Pages: 12-12

    • Related Report
      2011 Final Research Report
  • [Journal Article] Reaction behavior of coke with iron oxide catalyst2010

    • Author(s)
      Y.Yamamoto, Y.Kashiwaya, 他
    • Journal Title

      Tetsu-to-Hagane

      Volume: 96 Pages: 288-296

    • NAID

      130000259060

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ observation and reaction mechanism of iron oxide catalyst added to coke2010

    • Author(s)
      Y.Yamamoto, Y.Kashiwaya, 他
    • Journal Title

      Tetsu-to-Hagane

      Volume: 96 Pages: 297-304

    • NAID

      130000259061

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interaction parameter eOC for carbon-saturated liquid iron between 1623K and 1723K2010

    • Author(s)
      Y.Kashiwaya, M.Hasegawa, H.Niitani, T.Kakinuma, M.Iwase
    • Journal Title

      Steel research International

      Volume: 81 Pages: 333-336

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic properties of KCl-CeCl3 binary system2009

    • Author(s)
      T. Nakajima, M. Hasegawa, Y. Kashiwaya, M. Myochin and M. Iwase
    • Journal Title

      High Temperature Materials and Processes

      Volume: vol.28, No.4 Pages: 197-202

    • Related Report
      2011 Final Research Report
  • [Journal Article] Biotar ironmaking using wooden biomass and nano-porous ironore2009

    • Author(s)
      Y.hata, H.Purwant, S.Hosokai, J.Hayashi, Y.Kashiwaya, T.
    • Journal Title

      Journal of Energy and Fuels 23

      Pages: 1128-1131

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 単一気孔内におけるコークス気孔内ガス化反応のシミュレーションのためのセルラーオートマトン法の開発2009

    • Author(s)
      柏谷悦章, 大笹憲一, 福田耕一, 加藤健次, 内藤誠章
    • Journal Title

      鉄と鋼 95

      Pages: 7-16

    • NAID

      110007008518

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 水素還元により生成した高純度鉄の評価2012

    • Author(s)
      柏谷悦章
    • Organizer
      日本鉄鋼協会春季講演大会シンポジウム
    • Related Report
      2011 Final Research Report
  • [Presentation] グリーンエネルギー製鉄研究会最終報告「グリーンエネルギーの製造と製鉄への有効利用」2012

    • Author(s)
      細貝聡, 沖中憲之, 秋山友宏, 柏谷悦章
    • Organizer
      アンモニアによる鉄鉱石還元プロセスの設計とシステム解析日本鉄鋼協会春季講演大会シンポジウム
    • Related Report
      2011 Final Research Report
  • [Presentation] アンモニアによる鉄鉱石還元プロセスの設計とシステム解析

    • Author(s)
      細貝聡・松井耕祐・沖中憲之・秋山友宏, 柏谷悦章
    • Organizer
      CAMP-ISIJ
    • Related Report
      2011 Final Research Report
  • [Presentation] 乾燥ゲーサイト鉱石へのタール蒸気の炭素析出(バイオマス製鉄の可能性調査)

    • Author(s)
      松井耕祐・秋山友宏・林潤一郎・柏谷悦章・細貝聡・秦裕一
    • Organizer
      CAMP-ISIJ
    • Related Report
      2011 Final Research Report
  • [Presentation] 木質系バイオマスによる低品位鉱石の還元技術(バイオマス製鉄の可能性調査)

    • Author(s)
      杉山喬・齋藤通生・上杉浩之, 秋山友宏・柏谷悦章
    • Organizer
      CAMP-ISIJ
    • Related Report
      2011 Final Research Report
  • [Presentation] ゲーサイトによるバイオコーク鉄源の製造(バイオマス製鉄の可能性調査)

    • Author(s)
      杉山喬・齋藤通生・上杉浩之, 秋山友宏・柏谷悦章
    • Organizer
      CAMP-ISIJ
    • Related Report
      2011 Final Research Report
  • [Presentation] 水素吹込みのための四流体高炉シミュレーションモデル

    • Author(s)
      柏谷悦章・山田大祐, 埜上洋
    • Organizer
      CAMP-ISIJ
    • Related Report
      2011 Final Research Report
  • [Presentation] 四流体高炉シミュレーションモデルを用いた水素吹込み操業の解析

    • Author(s)
      柏谷悦章・山田大祐, 埜上洋
    • Organizer
      CAMP-ISIJ
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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