Real-time wave-packet engineering of molecular vibrational dynamics excited with femtoseocnd shaped pulses

• Project/Area Number: 21340079
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Condensed matter physics I
• Research Institution: Tokyo University of Agriculture and Technology
• Principal Investigator: MISAWA Kazuhiko 東京農工大学, 大学院・工学研究院, 教授 (80251396)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000); Fiscal Year 2011: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000); Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2009: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
• Keywords: 波形整形パルス / 異性化ダイナミクス / 量子波束制御 / シアニン系色素 / 振動選択励起

Research Abstract

Open-loop wave-packet engineering was demonstrated by full capture of the phase-controlled vibrational motions by means of our newly developed wave-packet spectrometer. Optimal parameters of tailored femtosecond pulses from a pulse shaper were obtained for selective excitation of either twisting or bending motion in two different cyanine dye molecules. Mode-selective wave-packet generation by chirped pulse sequences was found to be commonly effective for DTTCI, DNTTCI and SMP-39. These results suggest a promising step toward triggering chemical reactions to a desired target by guiding the wave-packet motions associated with conformational changes in the substances.

Research Products

• [Journal Article] Efficient heterodyne CARS measurement by combining spectral phase modulation with temporal delay technique (2011)
  • Author(s): Takayuki Suzuki and Kazuhiko Misawa
  • Journal Title: Opt. Express Volume: 19 Pages: 11463-11470
  • Peer Reviewed
• [Journal Article] In vivo molecular labeling of halogenated volatile anesthetics via intrinsic molecular vibrations using nonlinear Raman spectroscopy (2011)
  • Author(s): Yu Nagashima, Takayuki Suzuki, Sumio Terada, Shoji Tsuji, and Kazuhiko Misawa
  • Journal Title: J. Chem. Phys Volume: 134 Pages: 24525-24525
  • Peer Reviewed
• [Journal Article] Efficient heterodyne CAES measurement by combining spectral phase modulation with temporal delay technique (2011)
  • Author(s): Takayuki Suzuki, Kazuhiko Misawa
  • Journal Title: Opt.Express Volume: 19 Issue: 12 Pages: 11463-11470
  • DOI: 10.1364/oe.19.011463
  • Peer Reviewed
• [Journal Article] In vivo molecular labeling of halogenated volatile anesthetics via intrinsic molecular vibrations using nonlinear Raman spectroscopy (2011)
  • Author(s): Yu Nagashima, Takayuki Suzuki, Sumio Terada, Shoji Tsuji, Kazuhiko Misawa
  • Journal Title: J.Chem.Phys. Volume: 134 Issue: 2 Pages: 24525-24525
  • DOI: 10.1063/1.3526489
  • Peer Reviewed
• [Journal Article] In vivo molecular labeling of halogenated volatile anesthetics via intrinsic molecular vibrations using nonlinear Raman spectroscopy (2011)
  • Author(s): Y.Nagashima, T.Suzuki, S.Terada, S.Tsuji, K.Misawa
  • Journal Title: J.Chem.Phys. Volume: 134 Pages: 0245251-9
  • Peer Reviewed
• [Journal Article] Full control of polarization shaped pulses using a phase-locked Mach-Zehnder interferometer (2011)
  • Author(s): Masaaki Sato, Takayuki Suzuki, Kazuhiko Misawa
  • Journal Title: Ultrafast Phenomena Volume: XVII Pages: 844-846
  • Peer Reviewed
• [Journal Article] Full control of polarization shaped pulses using a phase-locked Mach-Zehnder interferometer (2010)
  • Author(s): Masaaki Sato, Takayuki Suzuki, and Kazuhiko Misawa
  • Journal Title: Ultrafast Phenomena XVII Pages: 844-846
  • Peer Reviewed
• [Journal Article] Improved signal extraction method for single-pulse heterodyne CARS spectroscopy (2010)
  • Author(s): Yu Nagashima, Takayuki Suzuki, Sumio Terada, Shoji Tsuji, and Kazuhiko Misawa
  • Journal Title: SPIE Proceedings Volume: 7376 Pages: 73760-73760
  • Peer Reviewed
• [Journal Article] Vibrational wave-packet engineering by rapid-scanning wave-packet spectroscopy (2010)
  • Author(s): Kazuhiko Misawa and Kengo Horikoshi
  • Journal Title: Review of Laser Engineering Volume: 38(2)
  • NAID: 10026196320
  • Peer Reviewed
• [Journal Article] Improved signal extraction method for single-pulse heterodyne CARS spectroscopy (2010)
  • Author(s): Y.Nagashima, T.Suzuki, S.Terada, S.Tsuji, K.Misawa
  • Journal Title: SPIE Proceedings Volume: 7376
  • Peer Reviewed
• [Journal Article] Vibrational wave-packet engineering by rapid-scanning wave-packet spectroscopy (2010)
  • Author(s): Kazuhiko Misawa, Kengo Horikoshi
  • Journal Title: Review of Laser Engineering 38 Pages: 125-129
  • NAID: 10026196320
  • Peer Reviewed
• [Journal Article] Interferometric Polarization Pulse Shaper Stabilized by an External Laser Diode for Arbitrary Vector Field Shaping (2009)
  • Author(s): M. Sato, T. Suzuki, and K. Misawa
  • Journal Title: Rev. Sci. Instrum Volume: 80 Pages: 123107-123107
  • Peer Reviewed
• [Journal Article] Interferometric Polarization Pulse Shaper Stabilized by an External Laser Diode for Arbitrary Vector Field Shaping (2009)
  • Author(s): M.Sato, T.Suzuki, K.Misawa
  • Journal Title: Rev.Sci.Instrum. 80 Pages: 1231071-6
  • Peer Reviewed
• [Journal Article] Vibrational wave-packet control in cyanine dye molecules with free and restricted conjugated backbones (2009)
  • Author(s): Kengo Horikoshi, Tomotaka Tsukamoto, Kazuhiko Misawa
  • Journal Title: Technical Digest of CLEO/Europe-EQEC (EG2.2(CD-ROM))
  • Peer Reviewed
• [Presentation] Extreme Nonresonant Background Reduction for Rapid Phase-modulation CARS Spectroscopy by Phase Sensitive Detection (2011)
  • Author(s): Takayuki Suzuki, and Kazuhiko Misawa
  • Organizer: CLEO Pacific-Rim 2011
  • Place of Presentation: Sydney, Australia
  • Year and Date: 2011-08-28
• [Presentation] Heterodyne CARS Measurement of Inhalational Anesthetic Molecules Using Adaptively Phase-Modulated Femtosecond Pulses (2011)
  • Author(s): Kazuhiko Misawa, Yu Nagashima, Takayuki Suzuki, and Sumio Terada
  • Organizer: CLEO Europe-EQEC 2011
  • Place of Presentation: Munich, Germany
  • Year and Date: 2011-05-24
• [Presentation] Heterodyne CAES Measurement of Inhalational Anesthetic Molecules Using Adaptively Phase-Modulated Femtosecond Pulses (2011)
  • Author(s): Kazuhiko Misawa, Yu Nagashima, Takayuki Suzuki, Sumio Terada
  • Organizer: CLEO/Europe-EQEC 2011
  • Place of Presentation: Munich, Germany
  • Year and Date: 2011-05-22
• [Presentation] Rapid motion capture and phase control of vibrational wave-packets (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: Pacifichem 2010
  • Place of Presentation: Honolulu, USA
  • Year and Date: 2010-12-18
• [Presentation] Rapid motion capture and phase control of vibrational wave packets (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: Pacifichem
  • Place of Presentation: Honolulu, USA 招待講演
  • Year and Date: 2010-12-18
• [Presentation] Nonlinear spectroscopy using tailored femtosecond pulses (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: International Symposium on General Aspects of Graphene, Carbon Nanotube and Ultrafast Phenomena of Nanomaterials
  • Place of Presentation: Taipei, Taiwan
  • Year and Date: 2010-11-16
• [Presentation] Nonlinear spectroscopy using tailored femtosecond pulses (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: International Symposium on General Aspects of Graphene, Carbon Nanotube and Ultrafast Phenomena of Nanomaterials
  • Place of Presentation: Taipei, Taiwan 招待講演
  • Year and Date: 2010-11-16
• [Presentation] 超短光パルスの内部位相制御とその応用 (2010)
  • Author(s): 三沢和彦
  • Organizer: 超高速フォトニクスシンポジウム
  • Place of Presentation: 早稲田大学西早稲田
  • Year and Date: 2010-11-04
• [Presentation] Rapid motion capture of phase-controlled vibrational wave-packets associated with free and bridged molecular backbones (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: Symposium on the development of ultrafast pulse lasers and ultrafast spectroscopy
  • Place of Presentation: Tokyo, September
  • Year and Date: 2010-09-17
• [Presentation] Rapid motion capture of phase-controlled vibrational wave-packets associated with free and bridged molecular backbones (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: Symposium on the development of ultrafast pulselasers and ultrafast spectroscopy
  • Place of Presentation: Chofu, Japan 招待講演
  • Year and Date: 2010-09-17
• [Presentation] Full Control of Polarization Shaped Pulses Using a Phase-Locked Mach-Zehnder Interferometer (2010)
  • Author(s): Masaaki Sato, Takayuki Suzuki, Kazuhiko Misawa
  • Organizer: 17th International Conference on Ultrafast Phenomena
  • Place of Presentation: Snowmass, USA
  • Year and Date: 2010-07-19
• [Presentation] Full Control of Polarization Shaped Pulses Using a Phase-Locked Mach-Zehnder Interferometer (2010)
  • Author(s): Masaaki Sato, Takayuki Suzuki, and Kazuhiko Misawa
  • Organizer: 17th International Conference on Ultrafast Phenomena
  • Place of Presentation: Snowmass Village, USA
  • Year and Date: 2010-07-18
• [Presentation] 時空間光波束の位相制御と物性研究への応用 (2010)
  • Author(s): 三沢和彦
  • Organizer: 物性研短期研究会「外部場の時間操作と実時間物理現象」
  • Place of Presentation: 東京大学柏キャンパス
  • Year and Date: 2010-06-22
• [Presentation] Nonlinear Raman spectrometry of halogenated volatile anesthetics (2010)
  • Author(s): Y. Nagashima, T. Suzuki, S. Terada, A. Iwata, S. Tsuji, and K. Misawa
  • Organizer: XII International Conference on Laser Applications in Life Sciences 2010
  • Place of Presentation: Oulu, Finland
  • Year and Date: 2010-06-11
• [Presentation] Nonlinear Raman spectrometry of halogenated volatile anesthetics (2010)
  • Author(s): Y.Nagashima, T.Suzuki, S.Terada, A.Iwata, S.Tsuji, K.Misawa
  • Organizer: XII International Conference on Laser Application s in Life Sciences
  • Place of Presentation: Oulu, Finland
  • Year and Date: 2010-06-11
• [Presentation] Phase-Contrast CARS Spectroscopy with Rapid Phase Modulation (2010)
  • Author(s): Takayuki Suzuki, Kazuhiko Misawa
  • Organizer: CLEO/QELS 2010
  • Place of Presentation: San Jose, USA
  • Year and Date: 2010-05-20
• [Presentation] Phase-Contrast CARS Spectroscopy with Rapid Phase Modulation (2010)
  • Author(s): Takayuki Suzuki and Kazuhiko Misawa
  • Organizer: CLEO QELS 2010
  • Place of Presentation: San Jose, USA
  • Year and Date: 2010-05-16
• [Presentation] Sensitive detection of inhalational anesthetic molecules by heterodyne-detected single-beam CARS using adaptively phase-modulated femtosecond pulses (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: The 40th Winter Colloquium on the Physics of Quantum Electronics
  • Place of Presentation: Snowbird, USA
  • Year and Date: 2010-01-06
• [Presentation] Sensitive detection of inhalational anesthetic molecules by heterodynedetected single-beam CARS using adaptively phase-modulated femtosecond pulses (2010)
  • Author(s): Kazuhiko Misawa
  • Organizer: The 40th Winter Colloquium on the Physics of Quantum Electronics
  • Place of Presentation: Snowbird, Utah
  • Year and Date: 2010-01-06
• [Presentation] 量子波束制御エンジニアリング (2009)
  • Author(s): 三沢和彦
  • Organizer: 第6回電通大・農工大合同シンポジウム
  • Place of Presentation: 東京農工大学
  • Year and Date: 2009-12-05
• [Presentation] 時空間波形制御技術の開拓 (2009)
  • Author(s): 三沢和彦
  • Organizer: ワークショップ「超高速過程における量子コヒーレンスの観測と制御」
  • Place of Presentation: 東北大学
  • Year and Date: 2009-12-04
• [Presentation] Arbitrary Vector Shaping of Femtosecond Pulses by a Phase-locked Mach-Zehnder Interferometer (2009)
  • Author(s): Masaaki Sato, Takayuki Suzuki, and Kazuhiko Misawa
  • Organizer: CLEO Pacific-Rim 2009
  • Place of Presentation: Shanghai, China
  • Year and Date: 2009-08-30
• [Presentation] Vibrational wave-packet control in cyanine dye molecules with free and restricted conjugated backbones (2009)
  • Author(s): Kengo Horikoshi, Tomotaka Tsukamoto, Kazuhiko Misawa
  • Organizer: CLEO/Europe-EQEC 2009
  • Place of Presentation: Munich, Germany
  • Year and Date: 2009-06-14
• [Remarks]
  • URL: http://www.femto.tuat.ac.jp/jp/
• [Remarks]
  • URL: http://www.tuat.ac.jp/~lmlab/
• [Remarks]
  • URL: http://www.tuat.ac.jp/~lmlab/
• [Remarks]
  • URL: http://www.tuat.ac.jp/~lmlab/