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Adsorption and Diffusion of Hydrogen Molecule in Crystals of Metal Coordination Complexes

Research Project

Project/Area Number 21350003
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionHokkaido University

Principal Investigator

TAKEDA Sadamu  北海道大学, 大学院・理学研究院, 教授 (00155011)

Co-Investigator(Kenkyū-buntansha) MARUTA Goro  北海道大学, 大学院・理学研究院, 助教 (00333592)
高見澤 聡  横浜市立大学, 国際総合科学研究科, 准教授 (90336587)
Co-Investigator(Renkei-kenkyūsha) TAKAMIZAWA Satoshi  横浜市立大学, 國際総合科学研究科, 教授 (90336587)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2011: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2010: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Fiscal Year 2009: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords水素吸蔵 / 分子吸蔵・脱着 / 結晶界面・内部水素拡散 / キラル結晶 / ランタノイド錯体 / 分子吸蔵と発光 / 固体NMR / 中性子回折 / 分子吸蔵脱着 / 結晶内水素拡散 / マイクロコイルNMR / 光異性化
Research Abstract

For utilizing hydrogen gas as a clean energy, hydrogen gas must be stored as a condensed phase under moderate pressure and at temperatures not so far from room temperature. Adsorption of the hydrogen molecule in porous metal coordination compounds is a good candidate. However, basic molecular mechanism of the adsorption phenomena is not clear. In this research project, we have clarified hydrogen adsorbed structures, quantum effects on the hydrogen motion, mechanism of diffusion of hydrogen into deformable metal-coordination crystals and chiral-channel structured crystals, etc. Adsorbed state of CO2 molecules near room temperatures was also investigated.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (30 results)

All 2012 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (17 results) Remarks (2 results)

  • [Journal Article] Homo-chiral self-assemblies and magnetic studies of M(II)-2,2-bipyridine-4,4-dicarboxylate coordination polymers2011

    • Author(s)
      Pei-Zhou Li, Naoki Muramatsu, Goro Maruta, Sadamu Takeda, Qiang Xu
    • Journal Title

      Inorganic Chemistry Communications

      Volume: 14 Pages: 411-414

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Solid State Structural Conversion between Three-dimensional Network and One-dimensional Chain of Cu(II) Triazole Coordination Polymers in Acidic/Basic-Suspensions or Vapors2011

    • Author(s)
      T. Yamada, G. Maruta, S. Takeda
    • Journal Title

      Chemical Communications

      Volume: 47 Pages: 653-655

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Homo-chiral self-assemblies and magnetic studies of M(11)-2,2-bipyridine-4,4-dicarboxylate coordination polymers2011

    • Author(s)
      Pei-Zhou Li
    • Journal Title

      Inorganic Chemistry Communications

      Volume: 14 Pages: 411-414

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Solid State Structural Conversion between Three-dimensional Network and One-dimensional Chain of Cu(II) Triazole Coordination Polymers in Acidic/Basic- Suspensions or Vapors2011

    • Author(s)
      T.Yamada
    • Journal Title

      Chemical Communications

      Volume: 47 Pages: 653-655

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] [18]Crown-6 rotator in spin-ladder compound of m-aminoanilinium([18]crown-6)[Ni(dmit)2]-2010

    • Author(s)
      T. Akutagawa, D. Sato, Q. Ye, T. Endo, S. Noro, S. Takeda and T. Nakamura
    • Journal Title

      Dalton Trans.

      Volume: 39 Pages: 8219-8227

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Transformation and Host Molecular Motions in CO2 Adsorption Process of a Metal Benzoate Pyrazine (MII ) Rh, Cu)2010

    • Author(s)
      S. Takamizawa, E. Nataka, T. Akatsuka, R. Miyake, Y. Kakizaki, H. Takeuchi, G. Maruta, and S. Takeda
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 132(11) Pages: 3783-3792

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Porous metal-organic framework of manganese(II) 4,4'-biphenyldicarboxylate with open nano channels and rare cem net topology2010

    • Author(s)
      R-Q. Zhong, R-Q. Zou, M. Du, T. Yamada, G. Maruta, S. Takeda, and Q. Xu
    • Journal Title

      Cryst Eng Comm

      Volume: 12 Pages: 677-681

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Porous metal-organic framework of manganese(II)4, 4'-biphenyldicarboxylate with open nano channels and rare cem net topology2010

    • Author(s)
      R-Q.Zhong
    • Journal Title

      CrystEngComm 12

      Pages: 677-681

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Transformation and Host Molecular Motions in CO2 Adsorption Process of a Metal Benzoate Pyrazine(MII)Rh, Cu)2010

    • Author(s)
      S.Takamizawa
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 3783-3792

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Gas Adsorption in One-Dimensional, Flexible CuII Coordination Polymers with Polar Units2009

    • Author(s)
      S. Noro, D. Tanaka, H. Sakamoto, S. Shimomura, S. Kitagawa, S. Takeda, K. Uemura, H. Kita, T. Akutagawa, and T. Nakamura
    • Journal Title

      Chem. Mater.

      Volume: 21 Pages: 3346-3355

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective Gas Adsorption in One-Dimensional, Flexible CuII Coordination Polymers with Polar Units2009

    • Author(s)
      S.Noro
    • Journal Title

      Chem.Mater. 21

      Pages: 3346-3355

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 配位高分子型ランタノイド錯体の吸蔵特性及び発光性挙動2012

    • Author(s)
      村松直樹
    • Organizer
      日本化学会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(横浜市)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 気体分子を吸蔵した配位高分子型遷移金属錯体およびランタノイド錯体の物性2011

    • Author(s)
      村松直樹、丸田悟朗、武田定
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Final Research Report
  • [Presentation] 気体分子を吸蔵した配位高分子型遷移金属錯体およびランタノイド錯体の物性2011

    • Author(s)
      村松直樹
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] 配位高分子型ランタノイド錯体の吸蔵特性及び発光性挙動2011

    • Author(s)
      村松直樹、丸田悟朗、武田定
    • Organizer
      日本化学会
    • Place of Presentation
      慶應義塾大学日吉キャンパス(横浜)
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 中性子回折による配位高分子錯体の水素吸蔵状態について2010

    • Author(s)
      柿崎圭紀、丸田悟朗、武田定
    • Organizer
      分子科学討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2010-09-17
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 固体高分解能NMRでみた[Cu(NH2trz)3](NO3)2・H2Oのスピン密度分布2010

    • Author(s)
      丸田悟朗
    • Organizer
      分子科学討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 配位高分子型金属錯体における「分子」の吸脱着制御の試み2010

    • Author(s)
      村松直樹、丸田悟朗、武田定
    • Organizer
      分子科学討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2010-09-14
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Control of Molecular Adsorption and Desorption in Metal Coordination Polymers2010

    • Author(s)
      村松直樹、丸田悟朗、武田定
    • Organizer
      Pacifichem
    • Place of Presentation
      ハワイ・ホノルル
    • Related Report
      2011 Final Research Report
  • [Presentation] 光異性化による金属錯体への「分子」の吸脱着制御の試み2010

    • Author(s)
      村松直樹、丸田悟朗、武田定
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2011 Final Research Report
  • [Presentation] 中性子散乱による配位高分子錯体の水素吸蔵状態の解明2010

    • Author(s)
      柿崎圭紀、丸田悟朗、武田定
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Related Report
      2011 Final Research Report
  • [Presentation] Control of Molecular Adsorption and Desorption in Metal Coordination Polymers2010

    • Author(s)
      村松直樹
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      ホノルルUSA
    • Related Report
      2010 Annual Research Report
  • [Presentation] Peculiar magnetism of antiferromagnetic nanoparticles AMnF3 (A=NH4 and Na) : Surface states and memory effect as studied by solid-state multinuclear NMR andmagenetic susceptibility2010

    • Author(s)
      武田定
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      ホノルルUSA 招待講演
    • Related Report
      2010 Annual Research Report
  • [Presentation] 中性子散乱による配位高分子錯体の水素吸蔵状態の解明2010

    • Author(s)
      柿崎圭紀
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学 本部キャンパス
    • Related Report
      2009 Annual Research Report
  • [Presentation] 光異性化による金属錯体への「分子」の吸脱着制御の試み2010

    • Author(s)
      村松直樹
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学 本部キャンパス
    • Related Report
      2009 Annual Research Report
  • [Presentation] 一次元金属錯体結晶に吸蔵されたH2、D2分子の挙動:固体NMRおよび中性子非弾性散乱による研究2009

    • Author(s)
      武田定
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Year and Date
      2009-09-27
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 銅を中心に持つ配位高分子錯体のH2、D2吸蔵状態:固体NMRおよび中性子非弾性散乱による研究2009

    • Author(s)
      柿崎圭紀、丸田悟朗、武田定
    • Organizer
      分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Solid-State NMR of Magnetic Systems and Nuclear Polarization by use of Conventional CW-ESR Equipment and Micro-coil NMR2009

    • Author(s)
      武田定
    • Organizer
      2nd Dynamic Nuclear Polarization Symposium 2009
    • Place of Presentation
      Goethe University, Frankfurt
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://barato.sci.hokudai.ac.jp/~ekitai/index.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://barato.sci.hokudai.ac.jp/~ekitai/index.html

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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