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Creation of Multi-dimensionally Extended Hetero-π Conjugate Molecules

Research Project

Project/Area Number 21350025
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionGakushuin University (2010-2012)
The University of Tokyo (2009)

Principal Investigator

KAWASHIMA Takayuki  学習院大学, 理学部, 教授 (80011766)

Co-Investigator(Kenkyū-buntansha) MOCHIDA Kunio  学習院大学, 理学部, 教授 (20118722)
KANO Naokazu  東京大学, 大学院・理学系研究科, 准教授 (00302810)
KOBAYASHI Junji  国際基督教大学, 教養学部, 准教授 (90334242)
AGOU Tomohiro  京都大学, 化学研究所, 助教 (90466798)
持田 邦夫  学習院大学, 理学部, 教授 (20118772)
Project Period (FY) 2009 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2011: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2009: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Keywords合成化学 / 光物性 / 複合材料・物性 / 典型元素化学 / ヘテロ-π共役分子 / ヘテロ-π共役分子 / トリシラスマネン / トリヘテラスマネン / 青色発光特性 / スターバースト型分子 / ヘテローπ共役分子 / スピロビシラフルオレン / スピロビホスホニアフルオレン / 二光子吸収 / Horner-Emmons反応 / ラジカル環化反応 / ヘテロール / スマネン
Research Abstract

Triheterasumanenes, which are heteroatom analogues of bowl-shaped sumanene, containing heteroatoms such as Si, Sn, and P atoms were synthesized as disc-shaped hetero π -conjugate molecules. As starburst-type hetero π -conjugate molecules, oligo(phenylenevinylene)- substituted spirobiheterafluorenes bearing Si or P at the molecular centers were synthesized. These multi-dimensionally extended hetero π -conjugate molecules were found to show interesting properties such as intense blue-light emission and two-photon absorption.

Report

(4 results)
  • 2012 Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (62 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (28 results) (of which Peer Reviewed: 27 results) Presentation (28 results) (of which Invited: 3 results) Book (4 results) Remarks (2 results)

  • [Journal Article] Different Coordination Modes of 2-(Diphenylphosphino)azobenzenes in Complexation with Hard and Soft Metals2012

    • Author(s)
      N. Kano, M. Yamamura, X. Meng, T. Yasuzuka, and T. Kawashima
    • Journal Title

      Dalton Trans

      Volume: 41 Issue: 37 Pages: 11491-11496

    • DOI

      10.1039/c2dt31494k

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination of a Chiral Tin(II) Cation Bearing a Bis(oxazoline) Ligand with Tetrahydrofuran Derivatives2012

    • Author(s)
      H. Arii, M. Matsuo, F. Nakadate, K. Mochida, and T. Kawashima
    • Journal Title

      Dalton Trans

      Volume: 41 Issue: 36 Pages: 11195-11200

    • DOI

      10.1039/c2dt31187a

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Reactivity of Phosphine Imides by Intramolecular Coordination with an Organoboryl Group2012

    • Author(s)
      N. Kano, K. Yanaizumi, X. Meng, and T. Kawashima
    • Journal Title

      Heteroat. Chem

      Volume: 23 Issue: 5 Pages: 429-434

    • DOI

      10.1002/hc.21033

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-Coordinated Germanium(II) Centers Within Distorted Axially Chiral Seven-Membered Chelates: Setero- and Enantioselective Cycloadditions2012

    • Author(s)
      H. Arii, T. Amari, J. Kobayashi, K. Mochida, and T. Kawashima
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 51 Issue: 27 Pages: 6738-6741

    • DOI

      10.1002/anie.201201566

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 2'-Diborylazobenzenes with Double N-B Coordination: Control of Fluorescent Properties by Substituents and Redox Reactions2012

    • Author(s)
      N. Kano, A. Furuta, T. Kambe, J. Yoshino, Y. Shibata, T.Kawashima, N. Mizorigi, S. Nagase
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: 2012 Issue: 10 Pages: 1584-1587

    • DOI

      10.1002/ejic.201200069

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of the Equilibrium between 2-Phosphinoazobenzenes and Inner Phosphonium Salts by Heat, Solvent, Acid, and Photoirradiation2012

    • Author(s)
      M. Yamamura, N. Kano, and T. Kawashima
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 85 Issue: 1 Pages: 110-123

    • DOI

      10.1246/bcsj.20110259

    • NAID

      130004152977

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Water-soluble Fluorescent 2-Borylazobenzenes Bearing Ionic Functional Group2012

    • Author(s)
      H. Itoi. T. Kambe, N. Kano, and T. Kawashima
    • Journal Title

      Inorg. Chim. Acta.

      Volume: 381 Pages: 117-123

    • DOI

      10.1016/j.ica.2011.07.053

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantiomeric Germanium(II) Cations Functionalized by Bis(oxazoline) Derivatives Coordinative to a Lewis Base2011

    • Author(s)
      H. Arii, F. Nakadate, K. Mochida, and T. Kawashima
    • Journal Title

      Organometallics

      Volume: 30 Issue: 17 Pages: 4471-4474

    • DOI

      10.1021/om200149a

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of a Cyclic Bis(iminophos phorane) from a 2,2'-Bis(phosphino)-azobenzene via N=N Bond Cleavage2011

    • Author(s)
      M. Yamamura, N. Kano, and T. Kawashima
    • Journal Title

      Heteroat. Chem

      Volume: 22 Issue: 3-4 Pages: 301-306

    • DOI

      10.1002/hc.20680

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemistry of Four-membered Ring Compounds Containing a Hypervalent Sulfur Atom and a Heteroatom at the Neighbor Positions2011

    • Author(s)
      T. Kawashima
    • Journal Title

      Phosphorus, Sulfur Silicon Relat. Elem.

      Volume: 186 Issue: 5 Pages: 1046-1054

    • DOI

      10.1080/10426507.2010.508293

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Synthesis, Optical Properties, and Theoretical Investigation of Silafluorenes and Spirobisilafluorenes Bearing Electron-Donating Aminostyryl Arms around a Silafluorene Core2010

    • Author(s)
      T. Agou, Md. Delwar Hossain, and T. Kawashima
    • Journal Title

      Chem. Eur. J

      Volume: 16 Issue: 1 Pages: 368-375

    • DOI

      10.1002/chem.200901481

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Properties of a Dinaphthoazaborine2010

    • Author(s)
      T. Agou, H. Arai, and T. Kawashima
    • Journal Title

      Chem. Lett

      Volume: 39 Issue: 6 Pages: 612-613

    • DOI

      10.1246/cl.2010.612

    • NAID

      10027181603

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Application of the Sila-Friedel-Crafts Reaction to the Synthesis of η-Extended Silole Derivatives and Their Properties2010

    • Author(s)
      S. Furukawa, J. Kobayashi, and T. Kawashima
    • Journal Title

      Dalton Trans

      Volume: 39 Issue: 39 Pages: 9329-9336

    • DOI

      10.1039/c0dt00136h

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stepwise Synthesis and Properties of a 9,10-Dihydro-9,10-diboraanthracene2010

    • Author(s)
      T. Agou, M. Sekine, and T. Kawashima
    • Journal Title

      Tetrahedron Lett

      Volume: 51 Issue: 38 Pages: 5013-5015

    • DOI

      10.1016/j.tetlet.2010.07.068

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence Color Change of a Boron-substituted Diarylazomethine by Reaction with a Cyanide Ion2010

    • Author(s)
      J.Yoshino, N.Kano, T.Kawashima
    • Journal Title

      Bull.Chem.Soc.Jpn.

      Volume: 83 Pages: 1185-1187

    • NAID

      10026699147

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of the Silc-Friedel-Crafts Reaction to the Synthesis of π-Extended Silole Derivatives and Their Properties2010

    • Author(s)
      S.Furukawa, J.Kobayashi, T.Kawashima
    • Journal Title

      Dalton Trans.

      Volume: 39 Pages: 9329-9336

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stepwise Synthesis and Properties of a 9,10-Dihydro-9,10-diboraanthracene2010

    • Author(s)
      T.Agou, M.Sekine, T.Kawashima
    • Journal Title

      Tetrahedron Lett.

      Volume: 51 Pages: 5013-5015

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structure of a Heptacoordinate Trichlorostannane Bearing a Triarylmethyl-Type Tetradentate Ligand2010

    • Author(s)
      J.Kobayashi, K.Iwanaga, T.Kawashima
    • Journal Title

      Organometallics

      Volume: 29 Pages: 5725-5727

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Optical of a Bis(Benzothiaborino)carbazole, a Thiaborin-Carbazole Mixed Ladder-Type π-Conjugated Molecule2010

    • Author(s)
      T.Agou, J.Kobayashi, T.Kawashima
    • Journal Title

      Phosphorus, Sulfur and Silicon and the Related Elements

      Volume: 185 Pages: 947-951

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, structure, and properties of a dinaphthoazaborine2010

    • Author(s)
      T.Agou, H.Arai, T.Kawashima
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 612-613

    • NAID

      10027181603

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of the Fluorescent Properties of a Divalent Tin-Dipyromethene2009

    • Author(s)
      J. Kobayashi, T. Kushida, and T. Kawashima
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131 Issue: 31 Pages: 10836-10837

    • DOI

      10.1021/ja904470m

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence Properties of Simple N-Substituted Aldimines with a B-N Interaction and Their Fluorescence Quenching by a Cyanide Ion2009

    • Author(s)
      J. Yoshino, N. Kano, and T. Kawashima
    • Journal Title

      J. Org. Chem

      Volume: 74 Issue: 19 Pages: 7496-7503

    • DOI

      10.1021/jo901769c

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of a Sila-Friedel-Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives2009

    • Author(s)
      S. Furukawa, J. Kobayashi, and T. Kawashima
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131 Issue: 40 Pages: 14192-14193

    • DOI

      10.1021/ja906566r

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-photon Absorption Properties of Heterafluorenes and Spirobiheterafluorenes Bearing Aminostyryl Arms2009

    • Author(s)
      T. Agou, Md. Delwar Hossain, T. Kawashima, K. Kamata, and K. Ohta
    • Journal Title

      Chem. Commun

      Issue: 44 Pages: 6762-6764

    • DOI

      10.1039/b912745c

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of η-Conjugated Dendrimers Based on Azaborines2009

    • Author(s)
      T. Agou, T. Kojima, J. Kobayashi, and T. Kawashima
    • Journal Title

      Org. Lett

      Volume: 11 Issue: 16 Pages: 3534-3537

    • DOI

      10.1021/ol901035d

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of a Sila-Friedel-Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives2009

    • Author(s)
      S.Furukawa, J.Kobayashi, T.Kawashima
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 14192-14193

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence Properties of Simple N-Substituted Aldimines with a B-N Interaction and Their Fluorescence Quenching by a Cyanide Ion2009

    • Author(s)
      J.Yoshino, N.Kano, T.Kawashima
    • Journal Title

      J.Org.Chem. 74

      Pages: 7496-7503

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reversible Control of the Fluorescent Properties of a Divalent Tin-Dipyrromethene2009

    • Author(s)
      J.Kobayashi, T.Kushida, T.Kawashima
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 10836-10837

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Synthesis and Optical Properties of Heavier Group 14 Element Analogues of Sumanene2012

    • Author(s)
      J. Kobayashi, S. Furukawa, M. Shirokawa, and T. Kawashima
    • Organizer
      The 4th Asian Silicon Symposium (ASiS-4)
    • Place of Presentation
      つくば
    • Year and Date
      2012-10-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Umpolung of a Hydrogen Atom of Water Utilizing Hexacoordinated Dihydrophosphates2012

    • Author(s)
      T. Kawashima
    • Organizer
      2012 Zhengzhou Chemistry Workshop (VI)
    • Place of Presentation
      Zhengzhou, China
    • Year and Date
      2012-09-17
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis, Structures, and Reactions of tert-Butyliminodiphenyl-(2-silylphenyl)phosphoranes2012

    • Author(s)
      T. Kawashima, K. Yanaizumi, X. Meng, and N. Kano
    • Organizer
      The 19th International Conference on Phosphorus Chemistry (ICPC-2012)
    • Place of Presentation
      Rotterdam, The Netherlands
    • Year and Date
      2012-07-12
    • Related Report
      2012 Final Research Report
  • [Presentation] Formation and Electrondonating Ability of a Cyclic Amino(Sulfur Ylide)Carbene2012

    • Author(s)
      T. Kawashima, S.-y. Nakafuji, A. Yatabe, and J. Kobayashi
    • Organizer
      The 25th International Symposium on the Organic Chemistry of Sulfur (ISOCS-25)
    • Place of Presentation
      Czestochowa, Poland
    • Year and Date
      2012-06-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and Optical Properties of Water-soluble Fluorescent Azobenzenes2012

    • Author(s)
      N. Kano, H. Itoi, T. Kambe, and T. Kawashima
    • Organizer
      The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
    • Place of Presentation
      京都
    • Year and Date
      2012-05-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Heteroatom Chemistry in Asia; Past, Present and Future2012

    • Author(s)
      T. Kawashima
    • Organizer
      The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
    • Place of Presentation
      京都
    • Year and Date
      2012-05-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Stereoselective Cycloaddition of a 7-Membered Germylene with a Diaminobiphenyl Backbone2012

    • Author(s)
      H. Arii, T. Amari, T. Kawashima, and K. Mochida
    • Organizer
      The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
    • Place of Presentation
      京都
    • Year and Date
      2012-05-21
    • Related Report
      2012 Final Research Report
  • [Presentation] Chemistry of Highly Coordinated Silicon Compounds2012

    • Author(s)
      T. Kawashima
    • Organizer
      The First Annual Meeting of the Korean Silicon Society
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2012-02-23
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Umpolung of a Hydrogen Atom of Water Utilizing Hexacoordinated Dihydrophosphates and Its Application to One-pot Deuteride Reduction of Carbonyl Compounds2011

    • Author(s)
      T. Kawashima
    • Organizer
      International Congress on Organic Chemistry dedicated to the 150th Anniversary of the Butlerov's Theory of Chemical Structure of Organic Compounds
    • Place of Presentation
      Kazan, Russia
    • Year and Date
      2011-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and Structures of Anionic Iron Complexes Bearing a Pentacoordinated Silicon and Germanium Atom2011

    • Author(s)
      N. Kano, N. Yoshinari, T. Kawashima, M. Enomoto, A. Okazawa, N. Kojima, J.-D. Guo, and S. Nagase
    • Organizer
      16th International Symposium on Silicon Chemistry (ISOS-XVI)
    • Place of Presentation
      Hamilton, Canada
    • Year and Date
      2011-08-16
    • Related Report
      2012 Final Research Report
  • [Presentation] Creation of Functional Molecules Utilizing Characteristics of Boron2010

    • Author(s)
      T. Kawashima
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Creation of Functional Molecules Utilizing Characteristics of Boron2010

    • Author(s)
      T.Kawashima
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Hawaii, USA(招待講演)
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] ホウ素の特性を活用した機能性典型元素化合物の創製2010

    • Author(s)
      川島隆幸
    • Organizer
      第7回有機元素化学セミナー
    • Place of Presentation
      京都
    • Year and Date
      2010-11-01
    • Related Report
      2012 Final Research Report
  • [Presentation] ホウ素の特性を活用した機能性典型元素化合物の創製2010

    • Author(s)
      川島隆幸
    • Organizer
      第7回有機元素化学セミナー
    • Place of Presentation
      京都(招待講演)
    • Year and Date
      2010-11-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] Development of a Sila-Friedel-Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives2010

    • Author(s)
      T. Kawashima
    • Organizer
      The 3rd Asian Silicon Symposium (ASiS-3)
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      2010-10-18
    • Related Report
      2012 Final Research Report
  • [Presentation] Development of a Sila-Friedel-Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives2010

    • Author(s)
      T.Kawashima
    • Organizer
      The 3rd Asian Silicon Symposium
    • Place of Presentation
      Hangzhou, China(招待講演)
    • Year and Date
      2010-10-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Chemistry of Fourmembered Ring Compounds Containing a Hypervalent Sulfur Atom and a Heteroatom at the Neighbor Positions2010

    • Author(s)
      T. Kawashima
    • Organizer
      The 24th International Symposium on the Organic Chemistry of Sulfur (ISOCS-24)
    • Place of Presentation
      Florence, Italy
    • Year and Date
      2010-07-28
    • Related Report
      2012 Final Research Report
  • [Presentation] Chemistry of Four-memebered Ring Compounds Containing a Hypervalent Sulfur Atom and a Heteroatom at the Neighbor Positions2010

    • Author(s)
      T.Kawashima
    • Organizer
      24th International Symposium on the Organic Chemistry of Sulfur
    • Place of Presentation
      Florence, Italy(招待講演)
    • Year and Date
      2010-07-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] ホウ素の特性を活用した機能性分子の創製2009

    • Author(s)
      川島隆幸
    • Organizer
      第20回基礎有機化学討論会
    • Place of Presentation
      桐生
    • Year and Date
      2009-09-29
    • Related Report
      2012 Final Research Report 2009 Annual Research Report
  • [Presentation] Synthesis and Structures of Anionic Iron Complexes Bearing a Pentacoordinated Silicon and Germanium Atom

    • Author(s)
      N. Kano, N. Yoshinari, T. Kawashima, M. Enomoto, A. Okazawa, N. Kojima, J.-D. Guo, and S. Nagase
    • Organizer
      16th International Symposium on Silicon Chemistry (ISOS-XVI)
    • Place of Presentation
      Hamilton, Canada
    • Related Report
      2011 Annual Research Report
  • [Presentation] Umpolung of a Hydrogen Atom of Water Utilizing Hexacoordinated Dihydrophosphates and Its Application to One-pot Deuteride Reduction of Carbonyl Compounds

    • Author(s)
      T. Kawashima
    • Organizer
      International Congress on Organic Chemistry dedicated to the 150th anniversary of the Butlerov’s Theory of Chemical Structure of Organic Compounds
    • Place of Presentation
      Kazan, Russia
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Heteroatom Chemistry in Asia; Past, Present and Future

    • Author(s)
      T. Kawashima
    • Organizer
      The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
    • Place of Presentation
      京都
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Stereoselective Cycloaddition of a 7-Membered Germylene with a Diaminobiphenyl Backbone

    • Author(s)
      H. Arii, T. Amari, T. Kawashima, and K. Mochida
    • Organizer
      The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
    • Place of Presentation
      京都
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis and Optical Properties of Water-soluble Fluorescent Azobenzenes

    • Author(s)
      N. Kano, H. Itoi, T. Kambe, and T. Kawashima
    • Organizer
      The 10th International Conference on Heteroatom Chemistry (ICHAC-10)
    • Place of Presentation
      京都
    • Related Report
      2011 Annual Research Report
  • [Presentation] Formation and Electron-donating Ability of a Cyclic Amino(Sulfur Ylide)Carbene

    • Author(s)
      T. Kawashima, S.-y. Nakafuji, A. Yatabe, and J. Kobayashi
    • Organizer
      The 25th International Symposium on the Organic Chemistry of Sulfur (ISOCS-25)
    • Place of Presentation
      Czestochowa, Poland
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis, Structures, and Reactions of tert-Butyliminodiphenyl(2-silylphenyl)phosphoranes

    • Author(s)
      T. Kawashima, K. Yanaizumi, X. Meng, and N. Kano
    • Organizer
      The 19th Internatinal Conference on Phosphorus Chemistry (ICPC-2012)
    • Place of Presentation
      Rotterdam, The Netherlands
    • Related Report
      2011 Annual Research Report
  • [Presentation] Umpolung of a Hydrogen Atom of Water Utilizing Hexacoordinated Dihydrophosphates

    • Author(s)
      T. Kawashima
    • Organizer
      2012 Zhengzhou Chemistry Workshop (VI)
    • Place of Presentation
      Zhengzhou, China
    • Related Report
      2011 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Optical Properties of Heavier Group 14 Element Analogues of Sumanene

    • Author(s)
      J. Kobayashi, S. Furukawa, M. Shirokawa, and T. Kawashima
    • Organizer
      The 4th Asian Silicon Symposium in Tsukuba, Japan (ASiS-4)
    • Place of Presentation
      つくば
    • Related Report
      2011 Annual Research Report
  • [Book] 高次π空間の創発と機能開発2013

    • Author(s)
      小林潤司
    • Total Pages
      245
    • Publisher
      シーエムシー出版
    • Related Report
      2012 Final Research Report
  • [Book] 高次π空間の創発と機能開発2013

    • Author(s)
      小林潤司(分担執筆)
    • Total Pages
      245
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Annual Research Report
  • [Book] ヘテロ元素の特性を活かした新機能材料2010

    • Author(s)
      狩野直和,川島隆幸
    • Publisher
      シーエムシー出版
    • Related Report
      2012 Final Research Report
  • [Book] ヘテロ元素の特性を活かした新機能材料2010

    • Author(s)
      狩野直和, 川島隆幸
    • Total Pages
      8
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/hetero/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/hetero/index.html

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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