Creation of Metal Nanocluster-Polymer Nanotube Composites and Their Functional Chiral Nanocatalysts
| Project/Area Number |
21350030
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kinki University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
NAKAHODO Tsukasa 近畿大学, 理工学部, 講師 (10375371)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2011: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2010: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2009: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
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| Keywords | 金属ナノクラスター / ポリマーナノチューブ / ナノ複合体 / キラル / 触媒 / 不斉反応 / ナノチューブ / 自己組織化 |
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| Research Abstract |
We have developed a new method for the fabrication of metal nanoparticle/polythiophene nanotube composites, i. e., the template-based electropolymerization of terthiophene-modified palladium nanoparticles in a nanoporous alumina membrane as a template gave the nanotube composites of polythiophene and the Pd nanoparticles. The Pd/polythiophene nanotube composites are recyclable highly effective catalyst for carbon-carbon coupling reaction. New chiral magnetite nanoparticles with a terthiophene produced the hybrid nanotubes of magnetite nanoparticles and polythiophene from their template-based electropolymerization.
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Report
(4 results)
Research Products
(50 results)
