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Design of conductive molecule-based magnets by the precise control of electronic states of charge-transferring nano-composites

Research Project

Project/Area Number 21350032
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionKanazawa University (2011)
Tohoku University (2009-2010)

Principal Investigator

MIYASAKA Hitoshi  金沢大学, 物質化学系, 教授 (50332937)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2009: ¥12,090,000 (Direct Cost: ¥9,300,000、Indirect Cost: ¥2,790,000)
Keywords電荷移動 / ナノコンポジット / 導電性分子磁石 / 電子供与体 / 電子受容体
Research Abstract

Metal-organic frameworks(MOFs) comprised of electron-donors(D) and. acceptors(A), i. e. D/A-MOFs, are intriguing candidates toward magnetic, conducting, and their synergistic materials, because the charge transfer(CT) of D^0A^0→D^<.+> A<.-> in MOFs is not only involves an electron transfer from D to A, but also generates a new spin set of S=1/2 spins with an exchange interaction. The D : A=2 : 1(or 1 : 2) system, which allows to construct multi-dimensional MOFs as ladder, 2D, and 3D networks, is the most fascinating target because this formula can possibly create a mixed-valence network system with one-electron transfer. Covalent-bonded assemblies of paddlewheel diruthenium(II, II) complexes[ Ru_2^<II, II>] and TCNQ/DCNQI demonstrate such materials, in which both magnetic and conducting properties are tuned by intra-lattice CTs.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (92 results)

All 2012 2011 2010 2009 Other

All Journal Article (64 results) (of which Peer Reviewed: 64 results) Presentation (23 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster2011

    • Author(s)
      Akihiro Hashikawa, Makiko Fujimoto, Yoshihito Hayashi, and Hitoshi Miyasaka
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 12361-12363

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Expansion of Supercubane Cores in Manganese Oxo Clusters with Tricarboxylate Ligands2011

    • Author(s)
      Yayoi Okui, Florina Aurelia Catusanu, Ryoko Kubota, Bunsho, Kure, Takayuki Nakajima, Tomoaki Tanase, Takashi Kajiwara, Masahiro Mikuriya, Hitoshi Miyasaka, and Masahiro Yamashita
    • Journal Title

      Eur. J. Inorg. Chem

      Pages: 4325-4330

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Paramagnetic-Diamagnetic PhaseTransition Accompanied by Coordination Bond Formation-Dissociation in the Dithiolate Complex Na[ Ni(pdt)_2]・2H_2O2011

    • Author(s)
      Shinya Takaishi, Nozomi Ishihara, Kazuya Kubo, Keiichi Katoh, Brian K. Breedlove, Hitoshi Miyasaka, and Masahiro Yamashita
    • Journal Title

      Inorg. Chem

      Volume: 50 Pages: 6405-6407

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stepwise Neutral-Ionic Phase Transitions in a Covalently-Bonded Donor/Acceptor Chain Compound2011

    • Author(s)
      Hitoshi Miyasaka, Natsuko Motokawa, Tamiko Chiyo, Miho Takemura, MasahiroYamashita, Hajime Sagayama, and Taka-hisa Arima
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Pages: 5338-5345

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copper(II)-terbium(III) Single-Molecule Magnets linked by photochromic ligan2011

    • Author(s)
      Takuya Shiga, Hitoshi Miyasaka, Masahiro Yamashita, Masakazu Morimoto, and Masahiro Irie
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 2275-2282

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Real time and space observation of domain wall migration in a MX-chain complex with a quasi-2D CDW state by using STM2011

    • Author(s)
      Shinya Takaishi, Hashen Wu, Takashi Kajiwara, Brian K. Breedlove, Hitoshi Miyasaka, and Masahiro Yamashita
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 2160-2162

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tuning of the ionization potential of paddlewheel diruthenium(II, II) complexes with fluorine atoms on the benzoate ligands2011

    • Author(s)
      Hitoshi Miyasaka, Natsuko Motokawa, Ryo Atsuumi, Hiromichi Kamo, Yuichiro Asai, and Masahiro Yamashita
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 673-682

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A three-dimensional network of two-electron-transferred[ Ru_2]_2TCNQ exhibiting anomalous conductance due to charge fluctuations2011

    • Author(s)
      Hitoshi Miyasaka, Takaumi Morita, and Masahiro Yamashita
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 271-273

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations2011

    • Author(s)
      H. Miyasaka, T. Morita, and M. Yamashita
    • Journal Title

      Chem. Commun.

      Volume: 47 Issue: 1 Pages: 271-273

    • DOI

      10.1039/c0cc02031a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning of the ionization potential of paddlewheel diruthenium(II,II) complexes with fluorine atoms on the benzoate ligands2011

    • Author(s)
      Hitoshi Miyasaka, et al
    • Journal Title

      Dalton Trans.

      Volume: 40 Issue: 3 Pages: 673-682

    • DOI

      10.1039/c0dt00956c

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Real time and space observation of domain wall migration in a MX-chain complex with a quasi-2D CDW state by using STM2011

    • Author(s)
      Shinya Takaishi, et al
    • Journal Title

      Dalton Trans.

      Volume: 40 Issue: 10 Pages: 2160-2162

    • DOI

      10.1039/c0dt01051k

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper-Terbium Single-Molecule Magnets Linked by Photochromic Ligands2011

    • Author(s)
      T. Shiga, H. Miyasaka, M. Yamashita, M. Morimoto, and M. Irie
    • Journal Title

      J. Chem. Soc., Dalton Trans.

      Volume: 40 Issue: 10 Pages: 2275-2282

    • DOI

      10.1039/c0dt01119c

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stepwise Neutral-Ionic Phase Transitions in a Covalently Bonded Donor/Acceptor Chain Compound2011

    • Author(s)
      H.Miyasaka
    • Journal Title

      J.Am.Chem.Soc

      Volume: 133, (No.14) Issue: 14 Pages: 5338-5345

    • DOI

      10.1021/ja110007u

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Paramagnetic-Diamagnetic Phase Transition Accompanied by Coordination Bond Formation-Dissociation in the Dithiolate Complex Na[Ni(pdt)_2]-2H_2O2011

    • Author(s)
      Shinya Takaishi, et al
    • Journal Title

      Inorg.Chem.

      Volume: 50 Issue: 14 Pages: 6405-6407

    • DOI

      10.1021/ic2003172

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Expansion of Supercubane Cores in Manganese Oxo Clusters with Tricarboxylate Ligands2011

    • Author(s)
      Yayoi Okui, et al
    • Journal Title

      Eur.J.Inorg.Chem.

      Volume: 2011 Issue: 28 Pages: 4325-4330

    • DOI

      10.1002/ejic.201100781

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster2011

    • Author(s)
      Akihiro Hashikawa, et al
    • Journal Title

      Chem.Commun.

      Volume: 47 Issue: 45 Pages: 12361-12363

    • DOI

      10.1039/c1cc15439g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature heat capacity ofSr_8Ga_<16> Ge_<30> and Ba_8Ga_<16> Ge_<30>: Tunneling states and electron-phono ninteraction in clathrates2010

    • Author(s)
      Jingtao Xu, Jun Tang, Kazumi Sato, Yoichi Tanabe, Hitoshi Miyasaka, Masahiro Yamashita, Satoshi Heguri, and Katsumi Tanigaki
    • Journal Title

      Phys. Rev. B

      Volume: 82

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic/Conducting Bifunctionality due to p/s Conjugated Functional Moieties in a Stacked Ferrimagnetic Chain2010

    • Author(s)
      Hitoshi Miyasaka, Yuichiro Asai, Natsuko Motokawa, Kazuya Kubo and Masahiro Yamashita
    • Journal Title

      Inorg. Chem

      Volume: 49 Pages: 9116-9118

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ac field-switchable magneticproperties of two-dimensional networked nano-size magnets2010

    • Author(s)
      Masaki Mito, Masashi Ogawa, Hiroyuki Deguchi, Masahiro Yamashita, and Hitoshi Miyasaka
    • Journal Title

      J. Appl. Phys

      Volume: 107

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Magnetism between an Antiferromagnet and a FerromagnetRelated to Solvation/Desolvation in a Robust Layered[ Ru_2]_2TCNQCharge-Transfer System2010

    • Author(s)
      Natsuko Motokawa, Satoshi Matsunaga, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita, and Kim R. Dunbar
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Pages: 11943-11951

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hybridized molecular materials basedon[ Mn^<III>_2] single molecule magnets with molecular conductors[ Ni(dmit)_2]^<n->2010

    • Author(s)
      Kazuya Kubo, Hitoshi Miyasaka, Masahiro Yamashita
    • Journal Title

      Physica B

      Volume: 405

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structure and electrical conductivity of a'''-[ BEDT-TTF]_<12>[ Cu_2Br_4]_3(BEDT-TTF=bis(ethylenedithio) tetrathiafulvalene)2010

    • Author(s)
      Kazuya Kubo, Hitoshi Miyasaka, Masahiro Yamashita
    • Journal Title

      Physica B

      Volume: 405

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pressure effect on the three-dimensional charge-transfer ferromagnet[{ Ru_2(m-FPhCO_2)_4}_2(BTDA-TCNQ)]2010

    • Author(s)
      Natsuko Motokawa, Hitoshi Miyasaka, and Masahiro Yamashita
    • Journal Title

      Dalton Trans

      Volume: 39 Pages: 4724-4726

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural Study of Electronic Statesin Quasi-One-Dimensional Halogen-Bridged Mixed-Metal Complexes[ Ni_<1-x> Pd_x(chxn)_2Br] Br_22010

    • Author(s)
      Shinya Takaishi, Hashen Wu, Jimin Xie, Takashi Kajiwara, Brian K. Breedlove, Hitoshi Miyasaka, and MasahiroYamashita
    • Journal Title

      Inorg. Chem

      Volume: 49 Pages: 3694-369

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Three-Dimensional Antiferromagnetic Order of Single-Chain Magnets : A NewApproach to Design Molecule-Based Magnets2010

    • Author(s)
      Hitoshi Miyasaka, KarinTakayama, Ayumi Saitoh, SachieFurukawa, Masahiro Yamashita, and Rodolphe Clerac
    • Journal Title

      Chem. Eur. J

      Volume: 16 Pages: 3656-3662

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing ferrocenyl group at 5-position2010

    • Author(s)
      Tohru Nishinaga, Tomoshi Aono, Eigo Isomura, Sayaka Watanabe, Yoshihiro Miyake, Akira Miyazaki, Toshiaki Enoki, Hitoshi Miyasaka, Hiroyuki Otani, and Masahiko Iyoda
    • Journal Title

      Dalton Trans

      Volume: 39 Pages: 2293-2300

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Control of Charge-Transfer in a Series of Ru_2^<II, II>/TCNQ Two-Dimensional Networks by Tuning the Electron-Affinity of TCNQ Units : A Route to Synergistic Magnetic/Conducting Materials2010

    • Author(s)
      Hitoshi Miyasaka, Natsuko Motokawa, Satoshi Matsunaga, Masahiro Yamashita, Kunihisa Sugimoto, Tatsuya Mori, Naoki Toyota, and Kim R. Dunbar
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Pages: 1532-1544

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mn^<III> Salen-type Single-Molecule Magnet Fixed in a Two-dimensional Network2010

    • Author(s)
      Chihiro Kachi-Terajima, Erina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, TakafumiKitazawa, and Hitoshi Miyasaka
    • Journal Title

      Chem. Lett

      Volume: 39 Pages: 94-95

    • NAID

      10027176953

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Water-Vapor-Induced ReversibleSwitching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity2010

    • Author(s)
      Hiroaki Iguchi, Shinya Takaishi, Hitoshi Miyasaka, MasahiroYamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, and Shin-ichi Kuroda Angew
    • Journal Title

      Chem. Int. Ed

      Volume: 49 Pages: 552-555

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature heat capacity of Sr_8Ga_<16>Ge_<30> and Ba_8Ga_<16>Ge_<30> : Tunneling states and electron-phonon interaction in clathrates2010

    • Author(s)
      Jingtao Xu, et al.
    • Journal Title

      Phys.Rev.B

      Volume: 82

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic/Conducting Bifunctionality due to π/σ Conjugated Functional Moieties in a Stacked Fertimagnetic Chain2010

    • Author(s)
      Hitoshi Miyasaka, et al.
    • Journal Title

      Inorg.Chem.

      Volume: 49 Pages: 9116-9118

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ac field-switchable magnetic properties of two-dimensional networked nano-size magnets2010

    • Author(s)
      Masaki Mito, et al.
    • Journal Title

      J.Appl.Phys.

      Volume: 107

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru_2]_2TCNQ Charge-Transfer System2010

    • Author(s)
      Natsuko Motokawa, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 11943-11951

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hybridized molecular materials based on [Mn^m_2] single molecule magnets with molecular conductors [Ni(dmit)_2]^<n->2010

    • Author(s)
      Kazuya Kubo, et al.
    • Journal Title

      Physica B

      Volume: 405

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structure and electrical conductivity of a'-[BEDT-TTF]_<12>[Cu_2Br_4]_3 (BEDT-TTF=bis(ethylenedithio) tetrathiafulvalene)2010

    • Author(s)
      Kazuya Kubo, et al.
    • Journal Title

      Physica B

      Volume: 405

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru_2(m-FPhCO_2)_4}_2(BTDA-TCNQ)]2010

    • Author(s)
      Natsuko Motokawa, et al.
    • Journal Title

      Dalton Trans.

      Volume: 39 Pages: 4724-4726

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Study of Electronic States in Quasi-One-Dimensional Halogen-Bridged Mixed-Metal Complexes [Ni_<1-x>Pd_x(chxn)_2Br]Br_22010

    • Author(s)
      Shinya Takaishi, et al.
    • Journal Title

      Inorg.Chem.

      Volume: 49 Pages: 3694-3696

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Three-Dimensional Antiferromagnetic Order of Single-Chain Magnets : A New Approach to Design Molecule-Based Magnets2010

    • Author(s)
      Hitoshi Miyasaka, et al.
    • Journal Title

      Chem.Fur.J.

      Volume: 16 Pages: 3656-3662

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing ferrocenyl group at 5-position2010

    • Author(s)
      Tohru Nishinaga, et al.
    • Journal Title

      Dalton Trans.

      Volume: 39 Pages: 2293-2300

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Control of Charge-Transfer in a Series of Ru_2^<n.n>/TCNQ Two-Dimensional Networks by Tuning the Electron-Affinity of TCNQ Units : A Route to Synergistic Magnetic/Conducting Materials2010

    • Author(s)
      Hitoshi Miyasaka, et al.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 1532-1544

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mn^m Salen-type Single-Molecule Magnet Fixed in a Two-dimensional Network2010

    • Author(s)
      Chihiro Kachi-Terajima, et al.
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 94-95

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water-Vapor-Induced Reversible Switching of Electronic States in an MMX-Type Chain Complex with Retention of Single Crystallinity2010

    • Author(s)
      Hiroaki Iguchi, et al.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 49 Pages: 552-555

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge-transfer two-dimensionallayers constructed from a 2 : 1 assemblyof paddlewheel diruthenium(II, II) complexes and bis[ 1, 2, 5] thiadiazolotetracyanoquin odimethane : bulk magnetic behavior as a function of inter-layer interactions2009

    • Author(s)
      Natsuko Motokawa, Tomomi Oyama, Satoshi Matsunaga, Hitoshi Miyasaka, Masahiro Yamashita and Kim R. Dunbar
    • Journal Title

      CrystEngComm

      Volume: 11 Pages: 2121-2130

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electroconductive Porous Coordination Polymer Cu[ Cu(pdt)_2] Composed of Donor and Acceptor Building Units2009

    • Author(s)
      Shinya Takaishi, Miyuki Hosoda, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Yasuyuki Nakanishi, Yasutake Kitagawa, Kizashi Yamaguchi, Atsushi Kobayashi, Hiroshi Kitagawa
    • Journal Title

      Inorg. Chem

      Volume: 82 Pages: 816-818

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Assemblies Composed of Mn^<III> Salen-Type Complexes and aTripodal Fe^<III> Complex with an Imidazolate Bridge2009

    • Author(s)
      Ryuta Ishikawa, Hitoshi Miyasaka, and Masahiro Yamashita
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 82 Pages: 816-818

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of an In-Plane Ligand on the Electronic Structures of Bromo-Bridged Nano-Wire Ni-Pd Mixed-Metal Complexes2009

    • Author(s)
      Mari Sasaki, Hashen Wu, Daisuke Kawakami, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Brian K. Breedlove, Masahiro Yamashita, Hideo Kishida, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, and Shinichi Kuroda
    • Journal Title

      Inorg. Chem

      Volume: 48 Pages: 7446-7451

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Coordination Assemblies of[ Mn_4] Single-Molecule Magnets Linked by Photochromic Ligands : Photochemical Control of the Magnetic Properties Masakazu Morimoto2009

    • Author(s)
      Masakazu Morimoto, Hitoshi Miyasaka, Masahiro Yamashita, Masahiro Irie
    • Journal Title

      J. Am. Chem. Soc

      Volume: 131 Pages: 9823-9835

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Low-Temperature Scanning Tunneling Microscope Investigation of a Nonplanar Dysprosium-PhthalocyanineAdsorption on Au(111)2009

    • Author(s)
      Y. Zhang, H. Isshiki, K. Katoh, Y. Yoshida, M. Yamashita, H. Miyasaka, B. K. Breedlove, T. Kajiwara, S. Takaishi, and T. Komeda
    • Journal Title

      J. Phys. Chem. C

      Volume: 113 Pages: 14407-14410

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-Temperature Scanning Tunneling Microscopy Investigation of Bis(phthalocyaninato) yttrium Growth on Au(111)2009

    • Author(s)
      Yan Feng Zhang, Hironari Isshiki, Keiichi Katoh, Yusuke Yoshida, Masahiro Yamashita, Hitoshi Miyasaka, Brian K. Breedlove, Takashi Kajiwara, Shinya Takaishi, and Tadahiro Komeda
    • Journal Title

      J. Phys. Chem. C

      Volume: 113 Pages: 9826-9830

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Realization of a Magnet Using an Antiferromagnetic Phase of Single Chain Magnets2009

    • Author(s)
      Claude Coulon, Rodolphe Clerac, Wolfgang Wernsdorfer, Thierry Colin, and Hitoshi Miyasaka
    • Journal Title

      Phys. Rev. Lett

      Volume: 102

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Slow dynamics of the magnetization in one-dimensional coordination polymers : Single-Chain Magnets2009

    • Author(s)
      Hitoshi Miyasaka, Miguel Julve, Masahiro Yamashita, Rodolphe Clerac
    • Journal Title

      Inorg. Chem

      Volume: 48 Pages: 3420-3437

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] [M^<III>(dmit)_2]^-Coordinated Mn^<III> Salen-Type Dimers(M^<III>=Ni^<III>, Au^<III>; dmit^<2->=1, 3-Dithiol-2-thione-4, 5-dithiolate): Design of Single-Component Conducting Single-Molecule Magnet-Based Materials2009

    • Author(s)
      Hiroki Hiraga, Hitoshi Miyasaka, Rodolphe Clerac, Marc Fourmigue, and Masahiro Yamashita
    • Journal Title

      Inorg. Chem

      Volume: 48 Pages: 2887-2898

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis and Crystal Structure of Dehydrated State in Vapochromic MMX-type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes2009

    • Author(s)
      Hiroaki Iguchi, Shinya Takaishi, Takashi Kajiwara, Hitoshi Miyasaka, Masahiro Yamashita, Hiroyuki Matsuzaki, Hiroshi Okamoto
    • Journal Title

      J. Inorg. Organomet. Polym

      Volume: 19 Pages: 85-90

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis and Crystal Structure of Dehydrated State in Vapochromic MMX-type Quasi-One-Dimensional Iodide-Bridged Platinum Complexes2009

    • Author(s)
      Hiroaki Iguchi, et al.
    • Journal Title

      J.Inorg.Organomet.Polym. 19

      Pages: 85-90

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] [M^<III>(dmit)_2]^--Coordinated Mn^<III> Salen-Type Dimers (M^<III>=Ni^<III>, Au^<III> ; dmit^<2->=1,3-Dithiol-2-thione-4,5-dithiolate) : Design of Single-Component Conducting Single-Molecule Magnet Based Materials2009

    • Author(s)
      Hiroki Hiraga, et al.
    • Journal Title

      Inorg.Chem. 48

      Pages: 2887-2898

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Slow dynamics of the magnetization in one-dimensional coordination polymers : Single-Chain Magnets2009

    • Author(s)
      Hitoshi Miyasaka, et al.
    • Journal Title

      Inorg.Chem. 48

      Pages: 3420-3437

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Realization of a Magnet Using an Antiferromagnetic Phase of Single Chain Magnets2009

    • Author(s)
      Claude Coulon, et al.
    • Journal Title

      Phys.Rev.Lett. 102

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-Temperature Scanning Tunneling Microscopy Investigation of Bis(phthalocyaninato)yttrium Growth on Au(111) : From Individual Molecules to Two-Dimensional Domains2009

    • Author(s)
      Yan Feng Zhang, et al.
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 9826-9830

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Low-Temperature Scanning Tunneling Microscope Investigation of a Nonplanar Dysprosium-Phthalocyanine Adsorption on Au(111)2009

    • Author(s)
      Y.Zhang, et al.
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 14407-14410

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination Assemblies of[Mn_4]Single-Molecule Magnets Linked by Photochromic Ligands : Photochemical Control of the Magnetic Properties2009

    • Author(s)
      Masakazu Morimoto, et al.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 9823-9835

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of an In-Plane Ligand on the Electronic Structures of Bromo-Bridged Nano-Wire Ni-Pd Mixed-Metal Complexes, [Ni_<1-x>Pd_x(bn)_2Br]Br_2 (bn=2S,3S-Diaminobutane)2009

    • Author(s)
      Mari Sasaki, et al.
    • Journal Title

      Inorg.Chem. 48

      Pages: 7446-7451

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Assemblies Composed of Mn^<III> Salen-Type Complexes and a Tripodal Fe^<III> Complex with an Imidazolate Bridge2009

    • Author(s)
      Ryuta Ishikawa, et al.
    • Journal Title

      Bull.Chem.Soc.Jpn. 82

      Pages: 816-818

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electroconductive Porous Coordination Polymer Cu[Cu(pdt)_2]Composed of Donor and Acceptor Building Units2009

    • Author(s)
      Shinya Takaishi, et al.
    • Journal Title

      Inorg.Chem. 48

      Pages: 9048-9050

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge-transfer two-dimensional layers constructed from a 2:1 assembly of paddlewheel diruthenium(II,II)complexes and bis[1,2,5]thiadiazolotetracyanoquinodimethane : bulk magnetic behavior as a function of inter-laver interactions2009

    • Author(s)
      Natsuko Motokawa, et al.
    • Journal Title

      CrystEngComm 11

      Pages: 2121-2130

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 金属錯体における次元性制御-新規機能を目指して-2012

    • Author(s)
      宮坂等
    • Organizer
      物理学会2012年春季大会
    • Place of Presentation
      西宮・関西学院大学(シンポジウム)(依頼講演)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] ドナー・アクセプター格子での電荷移動制御とナノ細孔内での分子活性化2012

    • Author(s)
      宮坂等
    • Organizer
      生物物質科学フォーラム
    • Place of Presentation
      石川・北陸先端大(招待講演)
    • Year and Date
      2012-03-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] ドナー・アクセプター格子での電荷移動制御2012

    • Author(s)
      宮坂等
    • Organizer
      第5回東北大学G-COE研究会[金属錯体の固体物性最前線-金属錯体と固体物性物理と生物物性の連携新領域をめざして-」
    • Place of Presentation
      仙台、東北大学(依頼講演)
    • Year and Date
      2012-01-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属錯体における次元性制御.新規機能を目指して-2012

    • Organizer
      物理学会2012年春季大会(シンポジウム)
    • Place of Presentation
      関西学院大学、兵庫
    • Related Report
      2011 Final Research Report
  • [Presentation]2012

    • Organizer
      生物物質科学フォーラム
    • Place of Presentation
      北陸先端大、石川
    • Related Report
      2011 Final Research Report
  • [Presentation] 金属錯体の固体物性最前線-金属錯体と固体物性物理と生物物性の連携新領域をめざして-2012

    • Organizer
      第5回東北大学G-COE研究会
    • Place of Presentation
      東北大学、宮城
    • Related Report
      2011 Final Research Report
  • [Presentation] フロンティア機能物質創製センターシンポジウム2011

    • Organizer
      機能性物質の最前線-物質科学の新展開を目指して-
    • Place of Presentation
      姫路じばさんビル、兵庫
    • Year and Date
      2011-12-18
    • Related Report
      2011 Final Research Report
  • [Presentation] ドナー・アクセプター格子での電荷移動制御:新しい機能性分子材料を目指して2011

    • Author(s)
      宮坂等
    • Organizer
      フロンティア機能物質創製センターシンポジウム機能性物質の最前線-物質科学の新展開を目指して-
    • Place of Presentation
      姫路、じばさんビル(招待講演)
    • Year and Date
      2011-12-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 共有結合ドナー・アクセプター鎖における中性-イオン性転移2011

    • Author(s)
      宮坂等
    • Organizer
      理研シンポジウム「分子アンサンブル2011」
    • Place of Presentation
      和光、理化学研究所(招待講演)
    • Year and Date
      2011-11-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Control of Charge-Transfer in Covalently-Bonded Donor/Acceptor Assemblies2011

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      3^<rd> Asian Conference on Coordination Chemistry
    • Place of Presentation
      India Habitate Center, New Delhi, India(招待講演)
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Control of Charge-Transfer in Covalently-Bonded Donor/Acceptor Assemblies2011

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      94^<th> Canadian Chemistry Conference and Exhibition ; Symposium on Metallosupramolecular Assemblies-Structures, Properties and Applications (IN3)
    • Place of Presentation
      Palais des congres de Montreal, Canada(招待講演)
    • Year and Date
      2011-06-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] 凝縮系金属錯体で電子・スピンを操る2010

    • Author(s)
      宮坂, 等
    • Organizer
      分子研所長招聘研究会
    • Place of Presentation
      岡崎、分子研
    • Year and Date
      2010-12-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] 分子ドナー/アクセプターの共有結合集積体における電荷移動制御と機能創発2010

    • Author(s)
      宮坂, 等
    • Organizer
      北海道大学グローバルCOEプログラム-触媒が先導する物質化学イノベーション-シンポジウム-"協同現象を誘発する錯体化学の新パラダイム"
    • Place of Presentation
      札幌、北海道大学学術交流会館小講堂
    • Year and Date
      2010-05-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Neutral-Ionic Transition in Covalently-Bonded Donor/Acceptor Assemblies2010

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      39^<th> International Conference on Coordination Chemistry (ICCC 39)
    • Place of Presentation
      Adelaide, Australia
    • Related Report
      2010 Annual Research Report
  • [Presentation] Covalently-Bonded Donor/Acceptor Assemblies : Control of Charge-Transfer for the Design of Syncrgistic Magnetic/Conducting Materials2010

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      8^<th> China-Japan Joint Symposium on Metal Cluster Compounds
    • Place of Presentation
      Xi'an, China
    • Related Report
      2010 Annual Research Report
  • [Presentation] Covalently-Bonded Donor/Acceptor Assemblies : Control of Charge-Transfer for the Design of Synergistic Magnetic/Conducting Materials2010

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      International Symposium on Advanced Soft Materials~Physics and Chemistry~
    • Place of Presentation
      隈本、熊本大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 分子ドナー/アクセプター凝縮系における機能創発2010

    • Author(s)
      宮坂, 等
    • Organizer
      第4回大学G-COE研究会「金属錯体の固体物性科学最前線-錯体化学と固体物性物理と生物物性の連携新領域創成をめざして-」
    • Place of Presentation
      仙台、東北大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] Covalently-bonded donor/acceptor assemblies : Control of charge-transfer for the design of synergistic magnetic/conducting materials2010

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      2010環太平洋国際化学会議(PACIFICHEM2010) Session Title : Functional Molecule-Based Magnets (#25)
    • Place of Presentation
      Hawaii,USA
    • Related Report
      2010 Annual Research Report
  • [Presentation] ドナー/アクセプター精密集積による導電性分子磁石の設計2010

    • Author(s)
      宮坂等
    • Organizer
      分子研研究会「分子集合系におけるポテンシャル空間の制御~その錯体化学的アプローチ~」
    • Place of Presentation
      分子研、岡崎
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属錯体で電子・スピンを操る2009

    • Author(s)
      宮坂等
    • Organizer
      京都大学グローバルCOEシンポジウム 低温合成法による新機能材料の創製(第8回)
    • Place of Presentation
      京都大学
    • Year and Date
      2009-10-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] Coordination Frameworks Undergoing Charge-Transfers that Mediate Spin Order and Electron Transport2009

    • Author(s)
      宮坂等
    • Organizer
      Tohoku University G-COE International Conference on Perspectives in Organic-Inorganic Hybrid Conductors and Molecule-Based Magnets
    • Place of Presentation
      Tohoku University
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] What is SCM and What is Non-SCM? : Antiferromagnetic Phase of Single-Chain Magnets2009

    • Author(s)
      宮坂等
    • Organizer
      2^<nd> Asian Conference on Coordination Chemistry(ACCC)
    • Place of Presentation
      Nanjing, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] D/A一次元共有結合鎖におけるN-I転移制御2009

    • Author(s)
      宮坂等
    • Organizer
      第3回G-COE研究会「金属錯体の固体物性科学最前線-錯体化学と固体物性物理の連携新領域創成をめざして-」
    • Place of Presentation
      東北大学
    • Related Report
      2009 Annual Research Report
  • [Book] 配位空間の化学-最新技術と応用-Chemistry and Application of Coordination Space2009

    • Author(s)
      宮坂等
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Final Research Report
  • [Book] 超分子サイエンス & テクノロジー-基礎からイノベーションまで-2009

    • Author(s)
      宮坂等
    • Publisher
      エヌ・ティー・エス(NTS)
    • Related Report
      2011 Final Research Report
  • [Book] 超分子サイエンス&テクノロジー-基礎からイノベーションまで-2009

    • Author(s)
      国武豊喜 監修
    • Total Pages
      1244
    • Publisher
      エヌ・ティー・エス(NTS)
    • Related Report
      2009 Annual Research Report
  • [Book] 配位空間の化学-最新技術と応用-Chemistry and Application of Coordination Space2009

    • Author(s)
      北川進 監修
    • Total Pages
      345
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://chem.s.kanazawa-u.ac.jp/inorg/miyasaka_laboratory/Top_page.html

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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