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PRECISE SYNTHESIS AND APPLICATION OF HIGH-GENERATION DENDRIMER-LIKE HYPERBRANCHED MEGAMOLECULES

Research Project

Project/Area Number 21350060
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

HIRAO Akira  東京工業大学, 大学院・理工学研究科, 教授 (00111659)

Co-Investigator(Kenkyū-buntansha) SUGIYAMA Kenji  法政大学, 工学部, 教授 (20282840)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2009: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Keywords高分子合成 / 精密合成 / 樹木状多分岐高分子 / リビングアニオン重合 / 樹木状多分岐ブロック共重合体 / 機能性ポリマー / 分子重合体 / 樹木状多分岐ポリマー / 樹木状多分岐ブロックポリマー / 世代 / 分子量分布
Research Abstract

We have successfully synthesized high-generation dendrimer-like hyper branched mega molecules with well-defined structures by developing a novel iterative methodology based on living anionic polymerization. Furthermore, the synthesis of block polymers consisting of different polymer segments introduced in each generation and the introduction of useful functional groups are also successful, resulting in new precisely designed functional polymers with hyper branched structures. In multiphase block polymers, it is expected to create quite novel nanosupramolecules and assemblies by molecular level phase-separation of each polymer segment, followed by self-organizing and assembling. Some new results have been obtained.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (115 results)

All 2012 2011 2010 2009

All Journal Article (49 results) (of which Peer Reviewed: 26 results) Presentation (59 results) Book (7 results)

  • [Journal Article] Precise Synthesis of Dendrimer-Like Star-Branched Poly(tert-butyl methacrylate) s and Their Block Copolymers by a Methodology Combiningα-Terminal-Functionalized Living Anionic Polymers with a Specially Designed Linking Reaction in an Iterative Fashion2012

    • Author(s)
      H-S. Yoo, T. Watanabe, Y. Matsunaga, A. Hirao
    • Journal Title

      Macromolecules

      Volume: 45 Pages: 100-112

    • Related Report
      2011 Final Research Report
  • [Journal Article] Precise synthesis of dendrimer-like star-branched PTBMAs and their block copolymers by a methodology combining alpher-terminal-functionalized living anionic polymers with a specially designed linking reaction in an iterative fashion2012

    • Author(s)
      H.-S.Yoo, T.Watanabe, Y.Matsunaga, A.Hirao
    • Journal Title

      Macromolecules

      Volume: 45 Issue: 1 Pages: 100-112

    • DOI

      10.1021/ma202367e

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Side-chain controlled self-assembly of PS-polypeptide miktoarm star copolymers2012

    • Author(s)
      S.Junila, N.Houbenov, A.Karatzas, N.Hadjichristidis, A.Hirao, H.Iatrou, O.Ikkala
    • Journal Title

      Macromolecules

      Volume: 45 Issue: 6 Pages: 2850-2856

    • DOI

      10.1021/ma202747h

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis of Thermo-Responsive and Water-Soluble Star-Branched Polymers and Star-Block Copolymers by Living Anionic Polymerization2011

    • Author(s)
      A. Hirao, R. Inushima, T. Nakayama, T. Watanabe, H-S. Yoo, T. Ishizone, K. Sugiyama, T. Kakuchi, S. Carlotti, A. Deffieux
    • Journal Title

      Eur. Polym. J.

      Volume: 47 Pages: 713-722

    • Related Report
      2011 Final Research Report
  • [Journal Article] Review Article : Dendrimer-Like Star-Branched Polymers ; Novel Structurally Well-Defined Hyperbranched Polymers2011

    • Author(s)
      A. Hirao, H-S. Yoo
    • Journal Title

      Polymer. J.

      Volume: 43 Pages: 2-17

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis of Well-Defined Star-branched polymers by Stepwise Iterative Methodology Using Living Anionic Polymerization2011

    • Author(s)
      T. Higashihara, M. Hayashi, A. Hirao
    • Journal Title

      Prog. Polym. Sci.

      Volume: 36 Pages: 323-375

    • Related Report
      2011 Final Research Report
  • [Journal Article] Review : Chain-End-and In-Chain-Functionalized AB Block Copolymers as Key Building Blocks in the Synthesis of well-defined Architectural Polymers2011

    • Author(s)
      A. Hirao, K. Murano, T. Oie, M. Uematsu, R. Goseki, Y. Matsuo
    • Journal Title

      Polym. Chem.

      Volume: 2 Pages: 1219-1233

    • Related Report
      2011 Final Research Report
  • [Journal Article] A Supramolecular Approach on Using PFLS-b-P2VP, PCRM Composite Thin Films for Non-Volatile Memory Device Applications2011

    • Author(s)
      J-C. Hsu, C-L. Liu, W-C. Chen, K. Sugiyama, A. Hirao
    • Journal Title

      Macromol. Rapid Commun.

      Volume: 32 Pages: 528-533

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis of Well-Defined miktoarm Star-Branched Polymers Consisting of Perfluorinated Segments by a Novel Methodology Using Soluble-in-Chain-BnBr-Functionalized AB Diblock Copolymers as Key Building Blocks2011

    • Author(s)
      A. A. Elmagd, K. Sugiyama, A. Hirao
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 826-834

    • Related Report
      2011 Final Research Report
  • [Journal Article] Facile Synthetic Route for Well-Defined Poly(3-hexylthiophene)-b-PMMA Copolymer by Anionic Coupling Reaction2011

    • Author(s)
      H-C. Moon, A. Anthonysamy, J-K. Kim, A. Hirao
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 1894-1899

    • Related Report
      2011 Final Research Report
  • [Journal Article] General and Facile Approach to Exact Graft Copolymers by Iterative Methodology Using Living Anionic In-Chain-Functionalized AB Diblock Copolymers as Key Building Blocks2011

    • Author(s)
      A. Hirao, K. Murano, A. A. Elmagd, M. Uematsu, S. Ito, R. Goseki, T. Ishizone
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 3302-3311

    • Related Report
      2011 Final Research Report
  • [Journal Article] Facile Synthetic Approach to Exact graft(Co) polymers and Double-Tailed PS2011

    • Author(s)
      A. Hirao, M. Uematsu, R. Kurokawa, T. Ishizone, K. Sugiyama
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 5638-5649

    • Related Report
      2011 Final Research Report
  • [Journal Article] Facile Synthesis of Triblock Co-and Terpolymers of Styrene, 2VP, and MMA by a New Methodology Combining Living Anionic Diblock Copolymers with a Specially Designed Linking Reaction2011

    • Author(s)
      A. Hirao, Y. Matsuo, T. Oie, R. Goseki, T. Ishizone, K. Sugiyama, A. H. Groeschel, A. H. E. Mueller
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 6345-6355

    • Related Report
      2011 Final Research Report
  • [Journal Article] Hot Topics : Precise Synthesis and Molecular Shapes of Megamolecules called "Dendrimer-LikeStar-Branched Polymers"2011

    • Author(s)
      平尾明
    • Journal Title

      高分子

      Volume: 59 Pages: 566-566

    • Related Report
      2011 Final Research Report
  • [Journal Article] A supramolecular approach on using poly(fluorenylstyrene)-b-P2VP : PCRM composite thin film for non-volatile memory device applications2011

    • Author(s)
      J.-C.Hsu, C.-L.Liu, W.-C.Chen, K.Sugiyama, A.Hirao
    • Journal Title

      Macromol.Rapid Commun.

      Volume: 32 Pages: 528-533

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of well-defined miktoarm star-branched polymers consisting of perfluorinated segments by a novel methodology using soluble in-chain-BnBr-functionalized AB diblock copolymers as key building blocks2011

    • Author(s)
      A.A.Magd, K.Sugiyama, A.Hirao
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 4 Pages: 826-834

    • DOI

      10.1021/ma102748x

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthetic route for well-defined poly(3-hexylthiophene)-b-PMMA copolymer by anionic coupling reaction2011

    • Author(s)
      H.-C.Moon, A.Anthonysamy, J.-K.Kim, A.Hirao
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 7 Pages: 1894-1899

    • DOI

      10.1021/ma200171m

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] General and facile approach to exact graft copolymers by iterative methodology using living anionic in-chain-functionalized AB diblock copolymers as key building blocks2011

    • Author(s)
      A.Hirao, K.Murano, A.A.Magd, M.Uematsu, S.Ito, R.Goseki, T.Ishizone
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 9 Pages: 3302-3311

    • DOI

      10.1021/ma200186p

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Living anionic polymerization of 1,4-divinylbenzene2011

    • Author(s)
      A.Hirao, S.Tanaka, R.Goseki, T.Ishizone
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 4579-4582

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and morphology of new asymmetric star polymers of poly(4-(9,9-dihexylfloren-2-yl)-b-P2VP and their non-volatile memory device applications2011

    • Author(s)
      J.-C.Hsu, C.Li, K.Sugiyama, R.Mezzenga, A.Hirao, W.-C.Chen
    • Journal Title

      Soft Matter

      Volume: 7 Pages: 8440-8449

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthetic approach to exact graft copolymers and double-tailed PS2011

    • Author(s)
      A.Hirao, M.Uematsu, R.Kurokawa, T.Ishizone, K.Sugiyama
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 5638-5649

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective ring-opening polymerization of glycidyl methacrylate2011

    • Author(s)
      A.Labbe, A-L. Brocas, E.Ibarboure, T.Ishizone, A.Hirao, A.deffieux, S.Carlotti
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 16 Pages: 6356-6364

    • DOI

      10.1021/ma201075n

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise synthesis of thermo-responsive and water-soluble star-branched polymers and star-block copolymers by living anionic polymerization2011

    • Author(s)
      A.Hirao, R.Inushima, T.Nakayama, T.Watanabe, H.-S.Yoo, T.Ishizone, K.Sugiyama, T.Kakuchi, S.Carlotti, A.Deffieux
    • Journal Title

      Eur.Polym.J.

      Volume: 47 Issue: 4 Pages: 713-722

    • DOI

      10.1016/j.eurpolymj.2010.11.003

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis of triblock co- and terpolymers of styrene, 2VP, and MMA by a new methodology combining living anionic polymers with a specially designed linking reaction2011

    • Author(s)
      A.Hirao, Y.Matsuo, T.Oie, R.Goseki, T.Ishizone, K.Sugiyama, A.H.Groeschel, A.H.E.Mueller
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 16 Pages: 6346-6355

    • DOI

      10.1021/ma201352z

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-volatile memory based on pentacene organic field-effect transistors with PS p-substituted oligofluorene moieties as polymer electrets2011

    • Author(s)
      J.-C.Hsu, W.-Y. Lee, H.-C. Wu, K.Sugiyama, A.Hirao, W.-C.Chen
    • Journal Title

      J.Materials Chem.

      Volume: 22 Issue: 12 Pages: 5820-5827

    • DOI

      10.1039/c2jm16039k

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of well-defined star-branched polymers by stepwise iterative methodology using living anionic polymerization2011

    • Author(s)
      T.Higashihara, M.Hayashi, A.Hirao
    • Journal Title

      Prog.Polym.Sci.

      Volume: 36 Pages: 323-375

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Review : Chain-end-and in-chain-functionalized AB diblock copolymers as key building blocks in the synthesis of well-defined architectural polymers2011

    • Author(s)
      A.Hirao, K.Murano, T.Oie, M.Uematsu, R.Goseki, Y.Masuo
    • Journal Title

      Polymer Chemistry

      Volume: 2 Issue: 6 Pages: 1219-1233

    • DOI

      10.1039/c0py00344a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Feature Article : Combining Living Anionic Polymerization with Branching reaction in an Iterative Fashion to Design Branched polymers2010

    • Author(s)
      T. Higashihara, K. Sugiyama, H-S. Yoo, A. Hirao
    • Journal Title

      Macromol. Rapid Commun.

      Volume: 37 Pages: 1031-1059

    • Related Report
      2011 Final Research Report
  • [Journal Article] 樹木状多分岐ポリマーの分子設計と精密合成2010

    • Author(s)
      平尾明
    • Journal Title

      高分子

      Volume: 59 Pages: 4-4

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis of Well-Defined(AB) n Multiblock Copolymers Composed of PS and PMMA Segments Using Specially Designed Living AB Diblock Copolymer Anion2010

    • Author(s)
      K. Sugiyama, T. Oie, A. El-Magd Ahmed, A. Hirao
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 1403-1410

    • Related Report
      2011 Final Research Report
  • [Journal Article] Viscoelasticity and Extensional Rheology of Model Caley-tree Polymers of Different Generation2010

    • Author(s)
      E. van Ruymbeke, E. B. Muliawan, S. G. Hatziriakos, T. Watanabe, A. Hirao, D. Vlassopoulos
    • Journal Title

      J. Rheology

      Volume: 54 Pages: 643-662

    • Related Report
      2011 Final Research Report
  • [Journal Article] Hierarchical Self-Assembly and Dynamics of a Miktoarm Star Chimera Composed of Poly(γ-benzyl-L-glutamate), PS, and PI2010

    • Author(s)
      G. Floudas, M. Mondeshki, I. Lieberwirth, H. Spiess, H. Iatrou, N. Hadjichristidis, A. Hirao, A. Gistas
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 9071-9076

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synchrotron X-Ray Scattering Characterization of the Molecular Structure of Star PSs with Varying Numbers of Arms2010

    • Author(s)
      S-W. Jin, T. Higashihara, K-S. Jin, J-W. Yoon, Y. Rho, B-G. Ann, J. Kim, A. Hirao, M. Ree
    • Journal Title

      J. Phys. Chem., B

      Volume: 114 Pages: 6247-6257

    • Related Report
      2011 Final Research Report
  • [Journal Article] Precise Synthesis of Novel Ferrocene-Based Star-Branched Polymers by Using Specially designed DPE Derivatives in Conjunction with Living Anionic Polymerization2010

    • Author(s)
      T. Hirano, H-S. Yoo, Y. Ozama, A. A. El-Magd, K. Sugiyama, A. Hirao
    • Journal Title

      J. Inorg. Organomet. Polym. Mat.

      Volume: 20 Pages: 445-456

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis of well-defined (AB)n multiblock copolymers composed of polys tyrene and poly (methyl methacrylate) segments using specially designed living AB diblock copolymer anion2010

    • Author(s)
      Kenji Sugiyama, Toshiyuki Oie, Abou El-Magd Ahmed, Akira Hirao
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 1403-1410

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Combining living anionic polymerization with branching reaction in an iterative fashion to design branched polymers2010

    • Author(s)
      Tomoya Higashihara, Kenji Sugiyama, Hee-Soo Yoo, Mayumi Hayashi, Akira Hirao
    • Journal Title

      Macromol.Rapid Commun.

      Volume: 37 Pages: 1031-1059

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelasicity and extensional rheology of model cayley-tree polymers of different generations2010

    • Author(s)
      E.van Ruymbeke, E.B.Muliawan, S.G.Hatziriakos, Takumi Watanabe, Akira Hirao, D.Vlassopoules
    • Journal Title

      J.Rheology

      Volume: 54 Pages: 643-662

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Successive synthesis of well-defined star-branched polymers by convergent iterative methodology using core-functionalized 3-arm star-branched polymers and a specially designed 1, 1-diphenylethylene derivative2010

    • Author(s)
      Tomoya Higashihara, Koichi Inoue, Akira Hirao
    • Journal Title

      Macromol. Symposia

      Volume: 296 Pages: 53-62

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of new star-shaped polymers with styrene-fluorene conjugated moieties and their multicolor luminescent ordered microporous films2010

    • Author(s)
      J-C.Hsu, Kenji Sugiyama, Y-C.Chiu, Akira Hirao, W-C.Chen
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 7151-7158

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hierarchical self-assembly and dynamics of a miktoarm star chimera composed of PLBG, PS, and PI2010

    • Author(s)
      G.Floudas, M.Mondeshki, I.Lieberwirth, H.Spiese, H.Iatrou, N.Hadjichristidis, Akira Hirao, A.Gitsas
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 9071-9076

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synchrotron X-ray scattering characterization of the molecular structure of star polystyrenes with varying number of arms2010

    • Author(s)
      S-W.Jin, Tomoya Higashihara, K-S.Jin, J.Yoon, Y-H.Rho, B-G.Ann, J.Kim, Akira Hirao, M-H.Ree
    • Journal Title

      J.Phys.Chem.B

      Volume: 114 Pages: 6247-6257

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise synthesis of novel ferrocence based star-branched polymers by using specially designed 1, 1-DPE derivatives in conjunction with living anionic polymerization2010

    • Author(s)
      Tomoya Hirano, Hee-Soo Yoo, Yohko Ozama, Ahmed Abou El-Magd, Kenji Sugiyama, Akira Hirao
    • Journal Title

      J.Inorg.Organomeet. Polym.Materials

      Volume: 20 Pages: 445-456

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis and Characterization of 4G Dendrimer-Like Star-branched PMMAs and Block Copolymers by Iterative Methodology Based on Living Anionic Polymerization2009

    • Author(s)
      A. Hirao, T. Watanabe, K. Ishizu, M. Ree, S-W. Jin, K-S. Jin, A. Deffieux, M. Schappacher, S. Carlotti
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 683-692

    • Related Report
      2011 Final Research Report
  • [Journal Article] 樹木状多分岐ポリマーの精密合成2009

    • Author(s)
      平尾明、渡部拓海、H-S. Yoo
    • Journal Title

      有機合成協会誌

      Volume: 67 Pages: 1033-1043

    • Related Report
      2011 Final Research Report
  • [Journal Article] Precise Synthesis of Dendrimer-Like Star-Branched PSs and Block Copolymers Composed of PS and PMMA Segments by an Iterative Methodology Using Living Anionic Polymerization2009

    • Author(s)
      H-S. Yoo, T. Watanabe, A. Hirao
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 4558-4570

    • Related Report
      2011 Final Research Report
  • [Journal Article] Precise Synthesis of Exact Graft Copolymers, PMMA-graft-PS, by Iterative Methodology Using a Specially Designed In-Chain-Functionalized AB Diblock Copolymer Anion2009

    • Author(s)
      A. Hirao, K. Murano, R. Kurokawa, T. Watanabe, K. Sugiyama
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 7820-7827

    • Related Report
      2011 Final Research Report
  • [Journal Article] Synthesis and self-Assembly Behavior of Poly (fluorenyl styrene)-block-Poly(2-vinylpyridine) Block Copolymers and Their Blends with Single Wall Carbon Nanotubes (SWCNTs)2009

    • Author(s)
      Chaoxu Li, Jung-Ching Hsu ; Kenji Sugiyama, Akira Hirao, Wen-Chang Chen, Raffaele Mezzenga
    • Journal Title

      Macromolecules 42

      Pages: 5793-5801

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis of Exact Graft Copolymers, Poly (methyl methacrylate)-exact graft-Polystyrene, by Iterative methodology Using a Specially Designed In-Chain-Functionalized AB Diblock Copolymer Anion2009

    • Author(s)
      Akira Hirao, Kohta Murano, Ryosuke Kurokawa, Takumi Watanabe, Kenji Sugiyama
    • Journal Title

      Macromolecules 42

      Pages: 7820-7827

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precise Synthesis of Dendrimer-Like Star-Branched Polystyrenes and Block Copolymers Composed of Polystyrene and Poly (Methyl methacrylate) Segments by an Iterative Methodology Using Living Anioic Polymerization2009

    • Author(s)
      Hee-Soo, Yoo, Takumi Watanabe, Akira Hirao
    • Journal Title

      Macromolecules 42

      Pages: 4558-4570

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Precise Synthesis of Sequentially Different Block Polymers by Living Anionic Polymerization in Conjunction with Specially Designed Linking Reactions2011

    • Author(s)
      A. Hirao
    • Organizer
      The 12^<th> Pacific Polymer
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-11-14
    • Related Report
      2011 Final Research Report
  • [Presentation] p-ジビニルベンゼンのアニオン重合2011

    • Author(s)
      田中俊介、後関頼太、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] アダマンチルエチニル基を有するスチレン誘導体のアニオン重合2011

    • Author(s)
      金井那矢、荘司秀夫、平尾明、石曽根隆
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 様々なポリメタクリル酸誘導体セグメントより形成される非対称星型ポリマーの精密合成2011

    • Author(s)
      後関頼太、小座間洋子、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 特別に分子設計した結合反応とリビングアニオン重合を組み合わせた方法を用いた非対称トリブロック共重合体の精密合成2011

    • Author(s)
      松尾悠里、後関頼太、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 新規二官能性ジフェニルエチレンを用いた非対称星型ポリマーの精密合成2011

    • Author(s)
      伊藤祥太郎、後関頼太、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 鎖末端と鎖中に異なる官能基を有するABジブロック共重合体を鍵とする構造が厳密に制御されたグラフト共重合体の精密合成2011

    • Author(s)
      上松正弘、後関頼太、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 様々なポリメタクリル酸誘導体セグメントより構成される非対称星型ポリマーの精密合成2011

    • Author(s)
      後関頼太、小座間洋子、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 新規2官能性ジフェニルエチレンを用いた非対称星型ポリマーの精密合成2011

    • Author(s)
      伊藤祥太郎、後関頼太、平尾明
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Precise Synthesis of Alternate Multiblock and Asymmetric Triblock Co(ter) polymers by a Methodology Utilizingα-Chain-End-Multifunctionalized Living Anionic AB Diblock Copolymers as Key Building Blocks2011

    • Author(s)
      A. Hirao
    • Organizer
      The 3^<rd> Taiwan-Japan Bilateral Polymer Symposium
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Sequentially Different Block Polymers with Well-Defined Structures by Means of Living Anionic Polymerization2011

    • Author(s)
      A. Hirao
    • Organizer
      2011 International Symposium on Ionic Polymerization
    • Place of Presentation
      Akron, USA
    • Year and Date
      2011-07-11
    • Related Report
      2011 Final Research Report
  • [Presentation] p-ジビニルベンゼンのアニオン重合2011

    • Author(s)
      田中俊介、後関頼太、平尾明
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] アダマンチルエチニル基を有するアルファーメチルスチレン誘導体のアニオン重合2011

    • Author(s)
      金井那矢、荘司秀夫、平尾明、石曽根隆
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] リビングアニオン重合を用いた構造が厳密に制御されたグラフトPMMAの精密合成2011

    • Author(s)
      伊藤祥太郎、後関頼太、平尾明
    • Organizer
      第60回高分子年次会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] リビングアニオン重合を用いたABA'型非対称トリブロック共重合体の精密合成2011

    • Author(s)
      松尾悠里、尾家俊行、後関頼太、平尾明
    • Organizer
      第60回高分子年次会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] ABジブロック共重合体を鍵とする構造が厳密に制御されたグラフト共重合体の合成2011

    • Author(s)
      村野耕太、後関頼太、平尾明
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] リビングアニオン重合を用いた構造が厳密に制御されたグラフトPMMAの精密合成2011

    • Author(s)
      伊藤祥太郎、後関頼太、平尾明
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Methodology using chain-functionalized AB diblock copolymers as building blocks in the synthesis of architectural polymers2011

    • Author(s)
      A.A.Magd, R.Goseki, A.Hirao
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] リビングアニオン重合法を用いたABA'型非対称トリブロック共重合体の精密合成2011

    • Author(s)
      松尾悠里、尾家俊行、後関頼太、平尾明
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 鎖末端にアルファーフェニルアクリレートを導入したポリマーとリビングポリマーの結合反応を用いた新規シークエンシャルトリブロック共重合体の精密合成2011

    • Author(s)
      尾家俊行、松尾悠里、後関頼太、平尾明
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 鎖末端と鎖中に異なる官能基を有するABブロック共重合体アニオンを利用したグラフト共重合体の精密合成2011

    • Author(s)
      上松正弘、平尾明
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] ABジブロック共重合体を鍵とする構造が厳密に制御されたグラフト共重合体の精密合成2011

    • Author(s)
      村野耕太、後関頼太、平尾明
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Synthesis of Architectural Polymers by Using Chain-Functionalized Diblock Copolymer Anion(s)2010

    • Author(s)
      A. Hirao
    • Organizer
      2010 International Chemical Congress on Pacific Basin Societies
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Chain-End-Functionalized AB Diblock Copolymers as Efficient Building Blocks for the Synthesis of Well-Defined Architectural Polymers2010

    • Author(s)
      A. Hirao
    • Organizer
      The 8^<th> Greek Polymer Society Symposium on Polymer Science and Technology
    • Place of Presentation
      Hersonissos, Greece
    • Year and Date
      2010-10-25
    • Related Report
      2011 Final Research Report
  • [Presentation] リビングアニオン重合法を用いた新規のシークエンシャルトリブロック共重合体の精密合成2010

    • Author(s)
      尾家俊行、杉山賢次、松尾悠里、平尾明
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] m-(ヒドロキシ(t-ブチル)アミノスチレンの保護とアニオン重合2010

    • Author(s)
      田中俊資、杉山賢次、平尾明
    • Organizer
      日本高分子学会、第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] リビングアニオン重合法を用いた新規のシークエンシャルトリブロック共重合体の精密合成2010

    • Author(s)
      尾家俊行、杉山賢次、松尾悠里、平尾明
    • Organizer
      日本高分子学会、第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] リビングアニオン重合を用いた構造が厳密に制御されたグラフト共重合体の精密合成2010

    • Author(s)
      村野耕太、黒川良介、上松正弘、平尾明
    • Organizer
      日本高分子学会、第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precise Synthesis of Architectural Polymers by Using Chain-Functionalized AB Diblock Copolymers2010

    • Author(s)
      Ahmed Abou El-Magd, Kenji Sugiyama, Kota Murano, Toshiyuki Oie, Akira Hirao
    • Organizer
      日本高分子学会、第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 樹木状多分岐ポリマーの分子設計と精密合成(高分子学会賞受賞講演)2010

    • Author(s)
      平尾明
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Precise synthesis of exact graft copolymers via new methodology based on living anionic polymerization2010

    • Author(s)
      Ahmed Abou El-Magd, Kota, Murano, Kenji Sugiyama, Akira Hirao
    • Organizer
      日本高分子学会、第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precise Synthesis of Graft Copolymers via New Methodology Based on Living Anionic Polymerization2010

    • Author(s)
      A. A. Elmagd, K. Murano, K. Sugiyama, A. Hirao
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 高分子学会賞受賞講演、樹木状多分岐ポリマーの分子設計と精密合成2010

    • Author(s)
      平尾明
    • Organizer
      日本高分子学会、第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Dendrimer-Like Star-branched Block Copolymers Composed of P^tBMA and PS Segments Based on Living Anionic Polymerization2010

    • Author(s)
      H-S. Yoo, A. Hirao
    • Organizer
      第59回高分子年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 構造が厳密に制御されたグラフト共重合体の合成と溶液挙動2010

    • Author(s)
      村野耕太、上松正弘、黒川良介、杉山賢次、平尾明
    • Organizer
      日本高分子学会、第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリ(フェロセニルメチルメタクリレート)セグメントを含むスターポリマーの精密合成2010

    • Author(s)
      平野智之、小座間洋子、杉山賢次、平尾明
    • Organizer
      日本高分子学会、第59回高分子年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Precise Synthesis of Architectural Polymers by Novel Iterative Strategy Using Chemistry of DPE in Conjunction with Living Anionic Polymerization2010

    • Author(s)
      A. Hirao
    • Organizer
      Frontiers in Polymer Chemistry
    • Place of Presentation
      Akron, USA
    • Year and Date
      2010-05-14
    • Related Report
      2011 Final Research Report
  • [Presentation] Precise Synthesis of Exact Graft(Co) polymers by Iterative Methodology Using Living Anionic Polymerization2010

    • Author(s)
      A. Hirao
    • Organizer
      The Spring 2010 ACS National Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-03-22
    • Related Report
      2011 Final Research Report
  • [Presentation] Precise synthesis of exact graft copolymers by nover iterative methodologies using living anionic polymerization2010

    • Author(s)
      平尾明
    • Organizer
      APMT 2010
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2009 Annual Research Report
  • [Presentation] Precise Synthesis of Exact Graft Copolymers by Iterative Methodology Based on Living Anionic Polymerization2009

    • Author(s)
      A. Hirao
    • Organizer
      IUPAC 5^<th> International Symposium on Novel Materials and Synthesis
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2009-10-19
    • Related Report
      2011 Final Research Report
  • [Presentation] リビングアニオン重合を基とした構造が厳密に制御されたグラフトポリマーの精密合成2009

    • Author(s)
      黒川良介、杉山賢次、平尾明
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] 鎖中に官能基を有するポリマーアニオンを用いたグラフト共重合体の精密合成2009

    • Author(s)
      村野耕太、黒川良介、杉山賢次、平尾明
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Well-Defined Dendrimer-Like Star-Branched Poly(^tBMA) s by Living Anionic Polymerization2009

    • Author(s)
      H.-S. Yoo, A. Hirao
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] フェロセニルメチルメタクリレートのリビングアニオン重合2009

    • Author(s)
      平野智之、杉山賢次、平尾明
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Precise Synthesis of Asymmetric Star-Branched Polymers by Iterative Approach Based on Living Anionic Polymerization2009

    • Author(s)
      A. Hirao
    • Organizer
      13^<th> Asian Chemical Congress
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Successive Synthesis of Well-Defined Miktoarm Star-Branched Polymers by Iterative Methodology Based on Living Anionic Polymerization2009

    • Author(s)
      A. Hirao
    • Organizer
      European Chemical Congress
    • Place of Presentation
      Graz, Austria
    • Year and Date
      2009-07-12
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] フェロセニルメチルメタクリレートのリビングアニオン重合2009

    • Author(s)
      平野智之、杉山賢次、平尾明
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-28
    • Related Report
      2011 Final Research Report
  • [Presentation] α-フェニルアクロイル基とアニオンリビングポリマーを用いた新規繰り返し法による星型PMMAの合成2009

    • Author(s)
      井上享一、江原清登、杉山賢次、平尾明
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] リビングアニオン重合を用いた新規水溶性非対称スターポリマーの精密合成2009

    • Author(s)
      中山貴文、犬島玲子、杉山賢次、平尾明、A. Deffieux
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] 分子量及び分岐点間距離が厳密に制御されたグラフト共重合体の合成2009

    • Author(s)
      村野耕太、黒川良介、杉山賢次、平尾明
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] AB二元ブロック共重合体を用いた多段(AB)_nブロック共重合体の精密合成2009

    • Author(s)
      尾家俊行、Abou El-Magd Ahmed、杉山賢次、平尾明
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] リビングアニオン重合を基とした構造が制御されたグラフトポリマーの精密合成2009

    • Author(s)
      黒川良介、杉山賢次、平尾明
    • Organizer
      第58回高分子年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2009-05-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Well-Defined Exact Graft PSs Having up to Five Graft Chains by Iterative Methodology Based on Living Anionic Polymerization2009

    • Author(s)
      A. Hirao
    • Organizer
      Taiwan-Japan Bilateral Polymer Symposium
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2009-04-23
    • Related Report
      2011 Final Research Report
  • [Presentation] Successive Synthesis of Well-Defined Regular and Asymmetric Star-Branched Polymers by Iterative methodology Based on Living Anionic Polymerization2009

    • Author(s)
      A. Hirao
    • Organizer
      Taiwan Chemical Society Meeting
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2009-01-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of well-defined exact graft polystyrenes having up to five graft chains by iterative methodology based on living anionic polymerization2009

    • Author(s)
      平尾明
    • Organizer
      Taiwan-Japan Bilateral Symposium
    • Place of Presentation
      Taipei, Taiwan
    • Related Report
      2009 Annual Research Report
  • [Presentation] Precise synthesis of dendrimer-like star-branched polymers by iterative methodology based on living anionic polymerization2009

    • Author(s)
      平尾明
    • Organizer
      1^<st> International Symposium on Polymer Materials Science and Technology
    • Place of Presentation
      Harbin, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] Precise Synthesis of Asymmetric Star-Branched Polymers by Iterative Approach Using Living Anionic Polymerization2009

    • Author(s)
      平尾明
    • Organizer
      13^<th> Asian Chemical Congress
    • Place of Presentation
      Shanghai, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] PRECISE SYNTHESIS OF EXACT GRAFT (CO) POLYMERS BY NOVEL STEPWISE ITERATIVE METHODOLOGY USING LIVING ANIONIC POLYMERIZATION2009

    • Author(s)
      平尾明
    • Organizer
      2009 International Symposium on Nano Structures : Synthesis, Characterization and Application
    • Place of Presentation
      Gwangju, Korea
    • Related Report
      2009 Annual Research Report
  • [Presentation] PRECISE SYNTHESIS OF EXACT GRAFT COPOLYMERS BY ITERATVE METHODOLOGY BASED ON LIVING ANIONIC POLYMERIZATION2009

    • Author(s)
      平尾明
    • Organizer
      IUPAC 5th International Symposium on Novel materials and Synthesis (NMS-V) & 19th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XIX)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2009 Annual Research Report
  • [Book] Polymer Science : A Comprehensive References2012

    • Author(s)
      A. Hirao, et al.
    • Publisher
      Elsevier
    • Related Report
      2011 Final Research Report
  • [Book] Polymer Science : A comprehensive reference2012

    • Author(s)
      平尾明(著者、分担)
    • Publisher
      Elsevier(未定)
    • Related Report
      2011 Annual Research Report
  • [Book] Synthesis of Polymers : New Structures and Methods2011

    • Author(s)
      A. Hirao, et al.
    • Publisher
      Wiley-VCH
    • Related Report
      2011 Final Research Report
  • [Book] Complex Macromolecular Architectures2011

    • Author(s)
      A. Hirao, et al.
    • Publisher
      John Wiley & Sons(Asia)
    • Related Report
      2011 Final Research Report
  • [Book] Complex Macromolecular Architectures2011

    • Author(s)
      平尾明(編集者、著者)
    • Total Pages
      832
    • Publisher
      John Wiley & Sons (Asia)
    • Related Report
      2011 Annual Research Report
  • [Book] Synthesis of Polymers : New Structures and Methods2011

    • Author(s)
      平尾明(著者,分担)
    • Total Pages
      1177
    • Publisher
      Wiley-VCH
    • Related Report
      2011 Annual Research Report
  • [Book] 高分子の合成(上)2010

    • Author(s)
      平尾明、杉山賢次
    • Total Pages
      468
    • Publisher
      講談社
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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