Synthesis of functional polyisocyanides using rigid helical structure of the main chain
| Project/Area Number |
21350065
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
OKAMURA Taka-aki 大阪大学, 大学院・理学研究科, 准教授 (90252569)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2011: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2009: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
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| Keywords | らせん / ポリイソシアニド / ポリマー / 機能性ポリマー / スタッキング / 芳香環 / エキシマー / クラウンエーテル / ピレン |
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| Research Abstract |
Integration of functional molecules on the rigid helical structure of polyisocyanides leads to new functional polymers. Addition of suitable alkali metal ions to fit into the crown ether of the side chain on the helical polycyanide resulted in the deformation of the helix by electrostatic repulsion. We also found a new method to detect the helical structure by emission spectra.
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Report
(4 results)
Research Products
(18 results)
