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Construction of polymers with high environmental performance by using dynamic bonds

Research Project

Project/Area Number 21350083
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

YOSHIE Naoko  東京大学, 生産技術研究所, 教授 (20224678)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,890,000 (Direct Cost: ¥15,300,000、Indirect Cost: ¥4,590,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2009: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
Keywordsリサイクル化学 / 長寿命材料 / 可逆反応 / 環境高分子材料 / リサイクル / 機械的特性変換 / 自己修復材料 / 機械的性質変換
Research Abstract

Polymers with novel environmental functions are developed by using dynamic bonds such as reversible covalent bonds and hydrogen bonds. By coordinating phase transition behavior(crystallization/melt) with reversibility of the dynamic bond, we have developed self-mendable, thermo-mendable, and photo-mendable polymers and polymers with soft-hard conversion properties.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (62 results)

All 2012 2011 2010 2009 Other

All Journal Article (14 results) (of which Peer Reviewed: 11 results) Presentation (40 results) Book (4 results) Remarks (4 results)

  • [Journal Article] Photoinduced mendable network polymer from poly(butylene adipate) end-functionalized with cinnamoyl groups2012

    • Author(s)
      Nobuhiro Oya, Petty Sukarsaatmadja, Kazuki Ishida, Naoko Yoshie
    • Journal Title

      Polym. J.

      Volume: (in press) Issue: 7 Pages: 724-729

    • DOI

      10.1038/pj.2012.18

    • NAID

      10030772579

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical Property Tuning of Semicrystalline Network Polymers by Controlling Rates of Crystallization and Crosslinking2012

    • Author(s)
      Nobuhiro Oya, Shunsuke Saitoh, Yukiko Furuhashi and Naoko Yoshie
    • Journal Title

      J. Polym. Sci. A, Polym. Chem

      Volume: 50 Issue: 10 Pages: 1926-1932

    • DOI

      10.1002/pola.25966

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 動的結合を利用した修復性高分子材料-自己修復性のための分子運動性制御2012

    • Author(s)
      吉江尚子
    • Journal Title

      化学と工業

      Volume: 65(4) Pages: 311-313

    • NAID

      10030545305

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 反応速度論から見た動的結合による修復性高分子材料2012

    • Author(s)
      吉江尚子
    • Journal Title

      高分子

      Volume: 61(4) Pages: 207-210

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A thermally-stable self-mending polymer networked by Diels-Alder cycloaddition2011

    • Author(s)
      Naoko Yoshie, Shunsuke Saito, Nobuhiro Oya
    • Journal Title

      Polymer

      Volume: 52 Issue: 26 Pages: 6074-6079

    • DOI

      10.1016/j.polymer.2011.11.007

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Substituent effect on structure and physical properties of semicrystaline Diels-Alder network polymers2011

    • Author(s)
      Kazuki Ishida, Violaine Weibel, Naoko Yoshie
    • Journal Title

      Polymer

      Volume: 52 Issue: 13 Pages: 2877-2882

    • DOI

      10.1016/j.polymer.2011.04.038

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] プロピレングリコールを主成分とする自己修復性ポリマー2011

    • Author(s)
      吉江尚子, 荒木ひとみ
    • Journal Title

      塗装工学

      Volume: 46 Pages: 146-150

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermo-responsive mending of polymers crosslinked by thermally reversible covalent bond : Polymers from bisfuranic terminated poly(ethylene adipate) and tris-maleimide2010

    • Author(s)
      Naoko Yoshie, Mariko Watanabe, Hitomi Araki, Kazuki Ishida
    • Journal Title

      Polymer Degradation and Stability

      Volume: 95 Issue: 5 Pages: 826-829

    • DOI

      10.1016/j.polymdegradstab.2010.01.032

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hard-Soft Conversion in Network Polymers : Effect of Molecular Weight of Crystallizable Prepolymer2010

    • Author(s)
      Kazuki Ishida, Yoshitake Nishiyama, Yuta Michimura, Nobuhiro Oya and Naoko Yoshie
    • Journal Title

      Macromolecules

      Volume: 43 Issue: 2 Pages: 1011-1015

    • DOI

      10.1021/ma901994v

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hard-Soft Conversion in Network Polymers : Effect of Molecular Weight of Crystallizable Prepolymer2010

    • Author(s)
      K.Ishida, Y.Nishiyama, Y.Michimura, N.Oya, N.Yoshie
    • Journal Title

      Macromolecules 43

      Pages: 1011-1015

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] アントラセンを側鎖または末端に持つプレポリマーの光可逆反応性2010

    • Author(s)
      吉江尚子, 渡辺茜, 石田一樹, 小林光一
    • Journal Title

      ネットワークポリマー 31

      Pages: 68-73

    • NAID

      130004991195

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 可逆反応を利用した修復性高分子材料技術2010

    • Author(s)
      吉江尚子
    • Journal Title

      機能材料 30

      Pages: 22-27

    • Related Report
      2009 Annual Research Report
  • [Journal Article] 可逆的架橋反応を利用したバイオベース高分子の機能化2009

    • Author(s)
      吉江尚子
    • Journal Title

      バイオサイエンスとインダストリー 67

      Pages: 205-209

    • NAID

      10026194657

    • Related Report
      2009 Annual Research Report
  • [Journal Article] 可逆反応性テレケリックプレポリマーから合成したネットワークポリマーの機能2009

    • Author(s)
      吉江尚子
    • Journal Title

      日本接着学会誌 45

      Pages: 399-403

    • NAID

      10026297863

    • Related Report
      2009 Annual Research Report
  • [Presentation] 分子運動性の高い部位を持つ結晶性ネットワークポリマーの合成および自己修復性2012

    • Author(s)
      藤田健弘, 大矢延弘, 池崎旅人, 吉江尚子
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 動的結合で架橋した結晶性ポリマーの修復性2012

    • Author(s)
      吉江尚子
    • Organizer
      11-6ポリマーフロンティア21
    • Place of Presentation
      東京
    • Year and Date
      2012-03-02
    • Related Report
      2011 Final Research Report
  • [Presentation] 動的結合で架橋した結晶性ポリマーの修復性2012

    • Author(s)
      吉江尚子
    • Organizer
      11-6ポリマーフロンティア21
    • Place of Presentation
      東京(招待講演)
    • Year and Date
      2012-03-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 可逆反応を利用した自己修復性高分子材料2011

    • Author(s)
      吉江尚子
    • Organizer
      第20回ポリマー材料フォーラム
    • Place of Presentation
      東京(招待講演)
    • Year and Date
      2011-11-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 自己修復性を持つ結晶性ポリマーの合成および物性2011

    • Author(s)
      藤田健弘, 大矢延弘, 吉江尚子
    • Organizer
      第61回ネットワークポリマー講演討論会
    • Place of Presentation
      大阪
    • Year and Date
      2011-10-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水素結合部位を持つ結晶性ポリマーの室温下における修復性2011

    • Author(s)
      大矢延弘, 吉江尚子
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] 自己修復性を持つ結晶性ポリマーの合成および物性2011

    • Author(s)
      藤田健弘, 大矢延弘, 吉江尚子
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Crystalline Polymers with Self-mendability at Room Temperature2011

    • Author(s)
      N.Yoshie
    • Organizer
      Taiwan-Japan Bilateral Polymer Symposium
    • Place of Presentation
      新竹(台湾)(招待講演)
    • Year and Date
      2011-09-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Crystalline Polymers with Mending Ability2011

    • Author(s)
      N.Oya, K.Ishida, M.Watanabe, H.Araki, N.Yoshie
    • Organizer
      BAEKELAND 2011
    • Place of Presentation
      豊橋
    • Year and Date
      2011-09-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] A self-mending network polymer cross-linked by thermally stable Diels-Alder adducts2011

    • Author(s)
      N. Oya, S. Saito, N. Yoshie
    • Organizer
      BAEKELAND 2011
    • Place of Presentation
      豊橋
    • Year and Date
      2011-09-12
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Synthesis and characterization of a self-mendable crystalline polymer based on poly(butylene succinate)2011

    • Author(s)
      T.Fujita, N.Oya, N.Yoshie
    • Organizer
      BAEKELAND 2011
    • Place of Presentation
      豊橋
    • Year and Date
      2011-09-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] A self-healing material formed from a crystalline polymer end-functionalized with hydrogen bonding units2011

    • Author(s)
      N.Oya, N.Yoshie
    • Organizer
      3rd International conference on self healing materials
    • Place of Presentation
      Bath(英国)
    • Year and Date
      2011-06-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] Crystalline Polymers With Mendability2011

    • Author(s)
      N. Yoshie
    • Organizer
      3rd International conference on self healing materials
    • Place of Presentation
      Bath(英国)
    • Year and Date
      2011-06-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Crystalline Polymers With Mendability2011

    • Author(s)
      N.Yoshie
    • Organizer
      3rd International conference on self-healing materials
    • Place of Presentation
      Bath(英国)
    • Year and Date
      2011-06-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 結晶化速度制御による結晶性ポリマーの自己修復性2011

    • Author(s)
      大矢延弘, 吉江尚子
    • Organizer
      第60回高分子学会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] 動的結合を利用した修復性ポリマー材料の設計2011

    • Author(s)
      吉江尚子
    • Organizer
      第60回高分子学会
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 動的結合を利用した修復性ポリマー材料の設計2011

    • Author(s)
      吉江尚子
    • Organizer
      第60回高分子学会
    • Place of Presentation
      大阪(招待講演)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] 両末端を水素結合部位で修飾した結晶性ポリマーの自己修復性2011

    • Author(s)
      大矢延弘, 吉江尚子
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Aliphatic polyesters cross-linked by reversible bonds : remendability and thermo-responsibility2010

    • Author(s)
      Naoko Yoshie
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-18
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Network polymer formed by photodimerization of cinnamate as a photo-induced mendable material2010

    • Author(s)
      Nobuhiro Oya,Naoko Yoshie
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 可逆反応を利用したネットワークポリマーの機能化2010

    • Author(s)
      吉江尚子
    • Organizer
      日本接着学会関西支部第6回若手研究者の会
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 可逆反応を利用したネットワークポリマーの機能化2010

    • Author(s)
      吉江尚子
    • Organizer
      第60回ネットワークポリマー講演討論会
    • Place of Presentation
      東京
    • Year and Date
      2010-10-15
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Diels-Alder反応による自己修復材料の開発とその物性2010

    • Author(s)
      齋藤俊介・大矢延弘, 吉江尚子
    • Organizer
      第60回ネットワークポリマー講演討論会
    • Place of Presentation
      東京
    • Year and Date
      2010-10-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Remending of Polymers Crosslinked by Reversible Bond2010

    • Author(s)
      Naoko Yoshie
    • Organizer
      IUPAC 6th International Symposium on Novel Materials and Their Synthesis(NMS-VI) & 20th International Symposium on Fine Chemistry and Functional Polymers(FCFP-XX)
    • Place of Presentation
      Wuhan(China)
    • Year and Date
      2010-10-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Remending of Polymers Crosslinked by Reversible Bond2010

    • Author(s)
      Naoko Yoshie
    • Organizer
      IUPAC 6th International Symposium on Novel Materials and Their Synthesis (NMS-VI), 20th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XX)
    • Place of Presentation
      Wuhan(China)
    • Year and Date
      2010-10-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 両末端に水素結合性部位を持つ直鎖ポリマーを用いた修復材料2010

    • Author(s)
      大矢延弘, 吉江尚子
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Functional ization of Network Polymers with Reversible Bonds2010

    • Author(s)
      Naoko Yoshie
    • Organizer
      2010 Japan-Taiwan Bilateral Polymer Symposium
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-07-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光二量化反応を用いた修復材料構築2010

    • Author(s)
      大矢延弘, P.Sukarsaatmadja, 吉江尚子
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可逆反応を利用した自己修復性架橋高分子2010

    • Author(s)
      吉江尚子
    • Organizer
      第10回表面力セミナー
    • Place of Presentation
      東北大学(仙台)
    • Year and Date
      2010-03-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] 桂皮酸エステルの光二量化を用いた修復性高分子材料2010

    • Author(s)
      大矢延弘, P.Sukarsaatmadja, 吉江尚子
    • Organizer
      第10回GSCシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2010-03-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可逆反応により構築したネットワークポリマー材料の機能2010

    • Author(s)
      吉江尚子
    • Organizer
      解体性接着技術研究会第2回研究会&シンポジウム
    • Place of Presentation
      東京工業大学(大岡山・東京)
    • Year and Date
      2010-02-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Functions of Bio-based Polymers with Dynamic Bonds2010

    • Author(s)
      Naoko Yoshie
    • Organizer
      2010 RIKEN Conference ; Soft Materials and Interface
    • Place of Presentation
      播磨
    • Year and Date
      2010-01-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Functions of Bio-based Polymers with Dynamic Bonds2010

    • Author(s)
      Naoko Yoshie
    • Organizer
      2010 RIKEN Conference ; Soft Materials and Interface
    • Place of Presentation
      Spring8(播磨)
    • Year and Date
      2010-01-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可逆反応性ネットワークポリマーの機能2009

    • Author(s)
      吉江尚子
    • Organizer
      第19回日本MRS学術シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2009-12-08
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Functionalization of Biobased Polymers by Reversible Reactions2009

    • Author(s)
      Naoko Yoshie
    • Organizer
      1st FAPS Polymer Congress
    • Place of Presentation
      名古屋
    • Year and Date
      2009-10-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] 動的結合を利用した自己修復性材料2009

    • Author(s)
      吉江尚子、石田一樹、荒木ひとみ、渡邉真里子
    • Organizer
      第59回ネットワークポリマー講演討論会
    • Place of Presentation
      関西大学
    • Year and Date
      2009-10-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可逆反応を利用したバイオベースポリマーの高機能化2009

    • Author(s)
      吉江尚子
    • Organizer
      高分子学会
    • Place of Presentation
      九州工業大学
    • Year and Date
      2009-10-02
    • Related Report
      2011 Final Research Report
  • [Presentation] 可逆反応を利用したバイオベースポリマーの高機能化2009

    • Author(s)
      吉江尚子
    • Organizer
      高分子学会09-2エコマテリアル研究会
    • Place of Presentation
      九州工業大学(北九州市)
    • Year and Date
      2009-10-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 熱可逆反応を利用した自己修復性高分子材料2009

    • Author(s)
      吉江尚子, 石田一樹, 荒木ひとみ, 渡邉真里子
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 光可逆性反応によるネットワークポリマーの機能化2009

    • Author(s)
      吉江尚子, スカルサトゥマジャペティ, 石田一樹
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Book] 高分子の架橋と分解III,第7章2.動的架橋を利用したネットワークポリマーの機能化-硬軟物性変換性と修復性2012

    • Author(s)
      吉江尚子
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Final Research Report
  • [Book] 高分子の架橋と分解III 第7章2.動的架橋を利用したネットワークポリマーの機能化-硬軟物性変換性と修復性2012

    • Author(s)
      吉江尚子
    • Total Pages
      8
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Annual Research Report
  • [Book] 自己修復(キズ復元)材料の最新技術,メーカー採用のトレンド(技術情報協会編)第2章2節高分子の主鎖結合に可逆反応を導入した自己修復ポリマー2011

    • Author(s)
      大矢延弘、吉江尚子
    • Publisher
      技術情報協会
    • Related Report
      2011 Final Research Report
  • [Book] 自己修復(キズ復元)材料の最新技術,メーカー採用のトレンド(技術情報協会編)第2章 2節 高分子の主鎖結合に可逆反応を導入した自己修復ポリマー2011

    • Author(s)
      大矢延弘、吉江尚子
    • Total Pages
      4
    • Publisher
      技術情報協会
    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://yoshielab.iis.u-tokyo.ac.jp/

    • Related Report
      2011 Final Research Report
  • [Remarks] 自己修復できる樹脂硬軟自在、ゴムの代替に,日経産業新聞, 2012年2月24日

    • Related Report
      2011 Final Research Report
  • [Remarks] Naoko Yoshie, Molecular Design for Repairing Polymer by Using Dynamic Bonds,高分子, Hot Topics欄, 2012, 61(5), 323.

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://yoshielab.iis.u-tokyo.ac.jp/

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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