Development of Novel Organic Solid-state Luminescent Compounds Based on Control of the Excited State
Project/Area Number |
21350109
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic industrial materials
|
Research Institution | The University of Tokyo |
Principal Investigator |
ARAKI Koji 東京大学, 生産技術研究所, 教授 (40134639)
|
Co-Investigator(Renkei-kenkyūsha) |
MUTAI Toshiki 東京大学, 生産技術研究所, 助教 (80313112)
YOSHIKAWA Isao 東京大学, 生産技術研究所, 技術専門職員 (10401283)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2011: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2010: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
|
Keywords | 色素・色材 / 有機発光材料 / 光物性 / 超分子化学 / 結晶多形 / プロトン移動 / イミダゾピリジン / ピレン / 励起状態 / 有機固体発光材料 / 蛍光 / ESIPT / 結晶構造解析 / 置換基効果 / 分子軌道計算 / 結晶 |
Research Abstract |
The compounds that can undergo excited state proton transfer were studied in order for development of the novel organic solid-state luminescent materials, and following results and novel photofunctional materials are obtained.(1) Suppressing the radiationless decay process by fixation of the conformation is the effective design concept for strongly luminescent solid materials.(2) A series of compounds showing a wide variety of luminescence color are newly synthesized by tuning electronic effect of the substituent(s).(3) Luminescence switches by alteration of molecular packing with external stimuli are developed.(4) Colorless white emitting materials are obtained.
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Report
(4 results)
Research Products
(86 results)