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Research on thermoplastic elastomers by nano-mechanical properties mapping

Research Project

Project/Area Number 21350120
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

NISHI Toshio  東北大学, 原子分子材料科学高等研究機構, 教授 (70134484)

Co-Investigator(Kenkyū-buntansha) NAKAJIMA Ken  東北大学, 原子分子材料科学高等研究機構, 准教授 (90301770)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Keywordsゴム材料 / 熱可塑性エラストマー / 原子間力顕微鏡 / ナノ力学物性マッピング / ブロックコポリマー / 熱可塑性エーストマー / プロックコポリマー
Research Abstract

Thermoplastic elastomers (TPEs)are the future-promising elastomeric materials. They have rubber elasticity and at the same time have melt processability such as injection molding. Thus, they offer the rationalization of molding processes and recyclability of processed products, which contribute the today's needs such as energy saving and environmental protection. The purpose of this study is the understanding of industry-processed TPEs in terms of structural and mechanical-properties' evaluations, where the basic research on TPEs will be bridged to R & D stage of practical TPE products. The key to realize this purpose is the evaluation of TPEs' mechanical properties at nano-scale. Nano-mechanical mapping based on atomic force microscopy was employed to perform the actual experiments. It was confirmed that the TPEs experienced the high-shear process showed totally different mechanical properties and that this difference was attributed to the different nano-scale morphology.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (24 results)

All 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 9 results) Presentation (11 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Character-ization of morphology and mechanical properties of block copolymers using atomic force microscopy : Effects of processing conditions2012

    • Author(s)
      D. Wang, K. Nakajima, S. Fujinami, Y. Shibasaki, J.-Q. Wang, T. Nishi
    • Journal Title

      Polymer

      Volume: Vol.53 Pages: 1960-1965

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of morphology and mechanical properties of block copolymers using atomic force microscopy : Effects of processing conditions2012

    • Author(s)
      D.Wang, K.Nakajima, S.Fujinami, Y.Shibasaki, J.-Q.Wang, T.Nishi
    • Journal Title

      Polymer

      Volume: 53 Issue: 9 Pages: 1960-1965

    • DOI

      10.1016/j.polymer.2012.02.046

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Surface Viscoelasticity and Energy Dissipation in a Polymer Film by Atomic Force Microscopy2011

    • Author(s)
      D. Wang, X.-B. Liang, Y.-H. Liu, S. Fujinami, T. Nishi, and K. Nakajima
    • Journal Title

      Macromolecules

      Volume: Vol.44 Pages: 8693-8697

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Dynamics of Polymeric Materials in Nano-scale Chinese2011

    • Author(s)
      T. Nishi, S. Fujinami, D. Wang, H. Liu and K. Nakajima
    • Journal Title

      J. Polym. Sci.

      Volume: Vol.29 Pages: 43-52

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structure and Dynamics of Polymeric Materials in Nano-scale2011

    • Author(s)
      T.Nishi, S.Fujinami, D.Wang, H.Liu, K.Nakajima
    • Journal Title

      Chinese J.Polym.Sci.

      Volume: 29 Issue: 1 Pages: 43-52

    • DOI

      10.1007/s10118-010-1023-5

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Characterization of Surface Viscoelasticity and Energy Dissipation in a Polymer Film by Atomic Force Microscopy2011

    • Author(s)
      D.Wang, X.-B.Liang, Y.-H.Liu, S.Fujinami, T.Nishi, K.Nakajima
    • Journal Title

      Macromolecules

      Volume: 44 Issue: 21 Pages: 8693-8697

    • DOI

      10.1021/ma201148f

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of True Surface Morphology and Nano-mechanical Properties of Poly(styrene-b-ethylene-co-butylene-b-styrene)Using Nanomechanical Mapping : Effects of Composition2010

    • Author(s)
      D. Wang, S. Fujinami, H. Liu, K. Nakajima, T. Nishi
    • Journal Title

      Macromolecules

      Volume: Vol.43 Pages: 9049-9055

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] True Surface Topography and Nanomechanical Mapping Measurements on Block Copolymers with Atomic Force Microscopy2010

    • Author(s)
      D. Wang, S. Fujinami, K. Nakajima, T. Nishi
    • Journal Title

      Macromolecules

      Volume: Vol.43 Pages: 3169-3172

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of True Surface Morphology and Nanomechanical Properties of Poly (styrene-b-ethylene-co-butylene-b-styrene) Using Nanomechanical Mapping : Effects of Comnosition2010

    • Author(s)
      Dong Wang, So Fujinami, Hao Liu, Ken Nakajima, Toshio Nishi
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 9049-9055

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] True Surface Topography and Nanomechanical Mapping Measurements on Block Copolymers with Atomic Force Microscopy2010

    • Author(s)
      Dong Wang, So Fujinami, Ken Nakajima, Toshio Nishi
    • Journal Title

      Macromolecules 43

      Pages: 3169-3172

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Characterization of Surface Mechanical Properties of Block Copolymers Using Atomic Force Microscopy2011

    • Author(s)
      D. Wang, S. Fujinami, K. Nakajima, and T. Nishi
    • Organizer
      The Chinese Symposium on Polymers
    • Place of Presentation
      Dalian, China
    • Year and Date
      2011-09-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Nano Based Mega-technology of Soft Materials2011

    • Author(s)
      T. Nishi and K. Nakajima
    • Organizer
      第9回日中先進高分子材料研究討論会(招待講演)
    • Place of Presentation
      Dalian, China
    • Year and Date
      2011-09-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Nano Based Mega-technology of Soft Materials2011

    • Author(s)
      T.Nishi, K.Nakajima
    • Organizer
      第9回日中先進高分子材料研究討論会
    • Place of Presentation
      Dalian, China(招待講演)
    • Year and Date
      2011-09-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] Measurements of Surface Properties of Block Copolymers with Atomic Force Microscopy2010

    • Author(s)
      D. Wang, S. Fujinami, H. Liu, K. Nakajima, T. Nishi
    • Organizer
      18th International Colloquium on Scanning Probe Microscopy (ICSPM18)
    • Place of Presentation
      Atagawa, Japan
    • Year and Date
      2010-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Measurements of Surface Properties of Block Copolymers with Atomic Force Microscopy2010

    • Author(s)
      Dong Wang, So Fujinami, Hao Liu, Ken Nakajima, Toshio Nishi
    • Organizer
      18th International Colloquium on Scanning Probe Microscopy (ICSPM18)
    • Place of Presentation
      Atagawa, Shizuoka
    • Year and Date
      2010-12-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Nanotechnology for Environment and Energy Related Problems2010

    • Author(s)
      Toshio Nishi, Ken Nakajima
    • Organizer
      International Rubber Conference 2010 (IRC2010)
    • Place of Presentation
      Mumbai, India
    • Year and Date
      2010-11-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Recent Progress on Nanomechanical Mapping of Polymer Nanocomposites(Invited)(招待講演)2010

    • Author(s)
      Toshio Nishi, So Fujinami, Dong Wang, Ken Nakajima
    • Organizer
      NRF-JSPS Core University Program : Advanced Polymeric Materials and Technology Symposium(APMT 2010)
    • Place of Presentation
      韓国・済州
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rubber Nanotechnology for the Future High Performance Materials(Plenary Lecture)(招待講演)2010

    • Author(s)
      Toshio Nishi, Ken Nakajima, Hiroshi Jinnai
    • Organizer
      12^<th> International Seminar on Elastomers(ISE 2010)& 2^<nd> Thailand-Japan Rubber Symposium
    • Place of Presentation
      タイ・チャアム
    • Related Report
      2009 Annual Research Report
  • [Presentation] Polymer Nanotechnology for Future Economic Growth & Development(Keynote Lecture)(招待講演)2010

    • Author(s)
      Toshio Nishi, Ken Nakajima, Hiroshi Jinnai
    • Organizer
      Plastics and Rubber Institute of Malaysia(PRIM)Golden Jubilee International Polymer Conference(GJIPC)
    • Place of Presentation
      マレーシア・クアラルンプール
    • Related Report
      2009 Annual Research Report
  • [Presentation] Nanomechanical Mapping of Block Copolymers with Atomic Force Microscopy Force Measurement2009

    • Author(s)
      D. Wang, S. Fujinami, K. Nakajima, T. Nishi
    • Organizer
      17th International Colloquium on Scanning Probe Microscopy (ICSPM17)
    • Place of Presentation
      Atagawa, Japan
    • Year and Date
      2009-12-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Nanomechanical Mapping of Block Copolymers with Atomic Force Microscopy Force Measurement2009

    • Author(s)
      Dong Wang, So Fujinami, Ken Nakajima, Toshio Nishi
    • Organizer
      17th International Colloquium on Scanning Probe Microscopy(ICSPM17)
    • Place of Presentation
      静岡県熱川
    • Year and Date
      2009-12-11
    • Related Report
      2009 Annual Research Report
  • [Book] Polymer Physics : From Suspensions to Nano-composites and Beyond2010

    • Author(s)
      K. Nakajima, T. Nishi
    • Publisher
      Wiley
    • Related Report
      2011 Final Research Report
  • [Book] Polymer Physics : From Suspensions to Nanocomposites and Beyond (Eds.Le szek A.Utracki, Alexander M.Jamieson)2010

    • Author(s)
      Ken Nakajima, Toshio Nishi
    • Publisher
      Wiley
    • Related Report
      2010 Annual Research Report
  • [Remarks] H24年度より特定非営利活動法人ナノ構造ポリマー研究協会内に設置されているTPE技術研究会の会長を再び務めることとなった。今後もTPE技術進展に貢献していくつもりである。

    • URL

      http://ransp.org/blog/tpe/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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